1,925 research outputs found
Inter- and intra-layer excitons in MoS/WS and MoSe/WSe heterobilayers
Accurately described excitonic properties of transition metal dichalcogenide
heterobilayers (HBLs) are crucial to comprehend the optical response and the
charge carrier dynamics of them. Excitons in multilayer systems posses inter or
intralayer character whose spectral positions depend on their binding energy
and the band alignment of the constituent single-layers. In this study, we
report the electronic structure and the absorption spectra of MoS/WS
and MoSe/WSe HBLs from first-principles calculations. We explore the
spectral positions, binding energies and the origins of inter and intralayer
excitons and compare our results with experimental observations. The absorption
spectra of the systems are obtained by solving the Bethe-Salpeter equation on
top of a GW calculation which corrects the independent particle
eigenvalues obtained from density functional theory calculations. Our
calculations reveal that the lowest energy exciton in both HBLs possesses
interlayer character which is decisive regarding their possible device
applications. Due to the spatially separated nature of the charge carriers, the
binding energy of inter-layer excitons might be expected to be considerably
smaller than that of intra-layer ones. However, according to our calculations
the binding energy of lowest energy interlayer excitons is only 20\%
lower due to the weaker screening of the Coulomb interaction between layers of
the HBLs. Therefore, it can be deduced that the spectral positions of the
interlayer excitons with respect to intralayer ones are mostly determined by
the band offset of the constituent single-layers. By comparing oscillator
strengths and thermal occupation factors, we show that in luminescence at low
temperature, the interlayer exciton peak becomes dominant, while in absorption
it is almost invisible.Comment: 17 pages, 4 figure
3.13 Tank mixtures of insecticides and fungicides, adjuvants, additives, fertilizers and their effects on honey bees after contact exposure in a spray chamber
In agriculture honey bees may be exposed to multiple pesticides. In contrast to single applications of plant protection products (PPP), the effects of tank mixtures of two or more PPP on honey bees are not routinely assessed in the risk assessment of plant protection products. However, tank mixes are often common practice by farmers. Mixtures of practically non-toxic substances can lead to synergistic increase of toxic effects on honey bees, observed for the first time in 19921 in combinations of pyrethroids and azole fungicides. 2004 Iwasa et al. already reported that ergosterol-biosynthesis-inhibiting (EBI) fungicides strongly increase the toxicity of neonicotinoids in laboratory for the contact exposure route. Furthermore, in agricultural practice additives, adjuvants and fertilizers may be added to the spray solution. For these additives usually no informations on potential side effects on bees are available when mixed with plant protection products. Therefore, it is considered necessary to investigate possible additive or synergistic impacts and evaluate potentially critical combinations to ensure protection of bees. Here, we investigated the effects on bees of combinations of insecticides, fungicides and fertilizers under controlled laboratory conditions. A spray chamber was used to evaluate effects following contact exposure by typical field application rates. Subsequently, mortality and behaviour of bees were monitored for at least 48 h following the OECD acute contact toxicity test 2143. Dependencies of synergistic effects and the time intervals between the applications of the mixing partners were evaluated.In agriculture honey bees may be exposed to multiple pesticides. In contrast to single applications of plant protection products (PPP), the effects of tank mixtures of two or more PPP on honey bees are not routinely assessed in the risk assessment of plant protection products. However, tank mixes are often common practice by farmers. Mixtures of practically non-toxic substances can lead to synergistic increase of toxic effects on honey bees, observed for the first time in 19921 in combinations of pyrethroids and azole fungicides. 2004 Iwasa et al. already reported that ergosterol-biosynthesis-inhibiting (EBI) fungicides strongly increase the toxicity of neonicotinoids in laboratory for the contact exposure route. Furthermore, in agricultural practice additives, adjuvants and fertilizers may be added to the spray solution. For these additives usually no informations on potential side effects on bees are available when mixed with plant protection products. Therefore, it is considered necessary to investigate possible additive or synergistic impacts and evaluate potentially critical combinations to ensure protection of bees. Here, we investigated the effects on bees of combinations of insecticides, fungicides and fertilizers under controlled laboratory conditions. A spray chamber was used to evaluate effects following contact exposure by typical field application rates. Subsequently, mortality and behaviour of bees were monitored for at least 48 h following the OECD acute contact toxicity test 2143. Dependencies of synergistic effects and the time intervals between the applications of the mixing partners were evaluated
Raman imaging and electronic properties of graphene
Graphite is a well-studied material with known electronic and optical
properties. Graphene, on the other hand, which is just one layer of carbon
atoms arranged in a hexagonal lattice, has been studied theoretically for quite
some time but has only recently become accessible for experiments. Here we
demonstrate how single- and multi-layer graphene can be unambiguously
identified using Raman scattering. Furthermore, we use a scanning Raman set-up
to image few-layer graphene flakes of various heights. In transport experiments
we measure weak localization and conductance fluctuations in a graphene flake
of about 7 monolayer thickness. We obtain a phase-coherence length of about 2
m at a temperature of 2 K. Furthermore we investigate the conductivity
through single-layer graphene flakes and the tuning of electron and hole
densities via a back gate
The prevalence of naturally acquired multiple infections of Wuchereria bancrofti and human malarias in anophelines
Malaria and filaria infection rates were determined for anopheline mosquitoes collected whilst biting and resting in village houses in Papua New Guinea. The number of anophelines infected with both parasites was greater than expected from the infection rates of each parasite and this difference was significant in resting collections. The excess of multiply infected mosquitoes is probably a result of a vector population composed of individuals with differing numbers of opportunities to become infected. Malaria-positive, Anopheles punctulatus from resting catches had a significantly greater number of Stage 3 Wuchereria bancroftilarvae than malaria-negative mosquitoes. However, multiply infected mosquitoes appear to suffer greater mortality than non-infected or singly infected mosquitoes when the filarial worm reaches the third stage. Any potential increase in transmission resulting from multiple infections is thereby offset by a greater mortality rate in these mosquitoe
Conductance of Open Quantum Billiards and Classical Trajectories
We analyse the transport phenomena of 2D quantum billiards with convex
boundary of different shape. The quantum mechanical analysis is performed by
means of the poles of the S-matrix while the classical analysis is based on the
motion of a free particle inside the cavity along trajectories with a different
number of bounces at the boundary. The value of the conductance depends on the
manner the leads are attached to the cavity. The Fourier transform of the
transmission amplitudes is compared with the length of the classical paths.
There is good agreement between classical and quantum mechanical results when
the conductance is achieved mainly by special short-lived states such as
whispering gallery modes (WGM) and bouncing ball modes (BBM). In these cases,
also the localization of the wave functions agrees with the picture of the
classical paths. The S-matrix is calculated classically and compared with the
transmission coefficients of the quantum mechanical calculations for five modes
in each lead. The number of modes coupled to the special states is effectively
reduced.Comment: 19 pages, 6 figures (jpg), 2 table
Increased Sensitivity to Possible Muonium to Antimuonium Conversion
A new experimental search for muonium-antimuonium conversion was conducted at
the Paul Scherrer Institute, Villigen, Switzerland. The preliminary analysis
yielded one event fulfilling all required criteria at an expected background of
1.7(2) events due to accidental coincidences. An upper limit for the conversion
probability in 0.1 T magnetic field is extracted as (90%
CL).Comment: 2 figure
Negative length orbits in normal-superconductor billiard systems
The Path-Length Spectra of mesoscopic systems including diffractive
scatterers and connected to superconductor is studied theoretically. We show
that the spectra differs fundamentally from that of normal systems due to the
presence of Andreev reflection. It is shown that negative path-lengths should
arise in the spectra as opposed to normal system. To highlight this effect we
carried out both quantum mechanical and semiclassical calculations for the
simplest possible diffractive scatterer. The most pronounced peaks in the
Path-Length Spectra of the reflection amplitude are identified by the routes
that the electron and/or hole travels.Comment: 4 pages, 4 figures include
Geometry-dependent scattering through quantum billiards: Experiment and theory
We present experimental studies of the geometry-specific quantum scattering
in microwave billiards of a given shape. We perform full quantum mechanical
scattering calculations and find an excellent agreement with the experimental
results. We also carry out the semiclassical calculations where the conductance
is given as a sum of all classical trajectories between the leads, each of them
carrying the quantum-mechanical phase. We unambiguously demonstrate that the
characteristic frequencies of the oscillations in the transmission and
reflection amplitudes are related to the length distribution of the classical
trajectories between the leads, whereas the frequencies of the probabilities
can be understood in terms of the length difference distribution in the pairs
of classical trajectories. We also discuss the effect of non-classical "ghost"
trajectories that include classically forbidden reflection off the lead mouths.Comment: 4 pages, 4 figure
Особливості управлінння персоналом в сучасних організаціях
Головним ресурсом підприємства є люди. Саме від персоналу залежить якість продукції, рівень обслуговування, загальний ріст і розвиток компанії. Система управління персоналом підприємства представляє собою сукупність прийомів, методів, управлінських дій спрямованих на організації роботи з персоналом. При формуванні системи управління персоналом організації необхідно враховувати такі моменти: організація є відкритою системою і на її діяльність впливають фактори зовнішнього середовища, такі, як ринкова кон’юнктура, ринок праці, правові норми, потреби споживачів, конкуренти; внутрішнє середовище організації характеризується такими складовими, як: місія організації, ціль діяльності, задачі, люди, організаційна структура та корпоративна культура; результат діяльності організації залежить від кваліфікації, досвіду, компетенцій персоналу організації; конкурентоздатність організації залежить не лише від конкурентоздатності продукції чи послуг, а і від конкурентоздатності персоналу організації
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