122 research outputs found
Structure and magnetic order in Fe2+xV1-xAl
We present a detailed structural investigation via neutron diffraction of
differently heat treated samples Fe2VAl and Fe2+xV1-xAl. Moreover, the magnetic
behaviour of these materials is studied by means of mSR and
Mossbauer-experiments. Our structural investigation indicates that quenched
Fe2VAl, exhibiting the previously reported "Kondo insulating like" behaviour,
is off-stoichiometric (6%) in its Al content. Slowly cooled Fe2VAl is
structurally better ordered and stoichiometric, and the microscopic magnetic
probes establish long range ferromagnetic order below TC = 13K, consistent with
results from bulk experiments. The magnetic state can be modelled as being
generated by diluted magnetic ions in a non-magnetic matrix. Quantitatively,
the required number of magnetic ions is too large as to be explained by a model
of Fe/V site exchange. We discuss the implications of our findings for the
ground state properties of Fe2VAl, in particular with respect to the role of
crystallographic disorder.Comment: accepted for publication in J. Phys.: Condens. Matte
BioConcens: Biomass and bioenergy production agriculture – consequences for soil fertility, environment, spread of animal parasites and socio-economy
The research programme called “international research cooperation and organic integrity” was commenced for a period 2006-2010. It is coordinated by DARCOF (The Danish Research Centre for Organic Farming). The whole programme, with acronym DARCOF III, consists of 15 projects (http://www.darcof.dk/research/darcofiii/index.html). One of them is BIOCONCENS - Biomass and bioenergy production in organic farming – consequences for soil fertility, environment, spread of animal parasites and socio-economy (http://www.bioconcens.elr.dk/uk/). The production of bioenergy in organic agriculture (OA) can reduce its dependency of fossil fuels and decrease green house gasses emission; consequently it will increase sustainability of organic farms. Biorefinery concept based on co-production of biogas, bioethanol and protein fodder in organic farming will be developed within the BIOCONCENS project and the background for the project and the different work packages will be presented in this paper
Invariant higher-order variational problems II
Motivated by applications in computational anatomy, we consider a
second-order problem in the calculus of variations on object manifolds that are
acted upon by Lie groups of smooth invertible transformations. This problem
leads to solution curves known as Riemannian cubics on object manifolds that
are endowed with normal metrics. The prime examples of such object manifolds
are the symmetric spaces. We characterize the class of cubics on object
manifolds that can be lifted horizontally to cubics on the group of
transformations. Conversely, we show that certain types of non-horizontal
geodesics on the group of transformations project to cubics. Finally, we apply
second-order Lagrange--Poincar\'e reduction to the problem of Riemannian cubics
on the group of transformations. This leads to a reduced form of the equations
that reveals the obstruction for the projection of a cubic on a transformation
group to again be a cubic on its object manifold.Comment: 40 pages, 1 figure. First version -- comments welcome
NMR and Mossbauer study of spin dynamics and electronic structure of Fe{2+x}V{1-x}Al and Fe2VGa
In order to assess the magnetic ordering process in Fe2VAl and the related
material Fe2VGa, we have carried out nuclear magnetic resonance (NMR) and
Mossbauer studies. 27Al NMR relaxation measurements covered the temperature
range 4 -- 500 K in Fe(2+x)V(1-x)Al samples. We found a peak in the NMR
spin-lattice relaxation rate, 27T1^-1, corresponding to the magnetic
transitions in each of these samples. These peaks appear at 125 K, 17 K, and
165 K for x = 0.10, 0, and - 0.05 respectively, and we connect these features
with critical slowing down of the localized antisite defects. Mossbauer
measurements for Fe2VAl and Fe2VGa showed lines with no hyperfine splitting,
and isomer shifts nearly identical to those of the corresponding sites in Fe3Al
and Fe3Ga, respectively. We show that a model in which local band filling leads
to magnetic regions in the samples, in addition to the localized antisite
defects, can account for the observed magnetic ordering behavior.Comment: 5 pages, 3 figure
Room Temperature Optically and Magnetically Active Edges in Phosphorene Nanoribbons
Nanoribbons - nanometer wide strips of a two-dimensional material - are a
unique system in condensed matter physics. They combine the exotic electronic
structures of low-dimensional materials with an enhanced number of exposed
edges, where phenomena including ultralong spin coherence times, quantum
confinement and topologically protected states can emerge. An exciting prospect
for this new material concept is the potential for both a tunable
semiconducting electronic structure and magnetism along the nanoribbon edge.
This combination of magnetism and semiconducting properties is the first step
in unlocking spin-based electronics such as non-volatile transistors, a route
to low-energy computing, and has thus far typically only been observed in doped
semiconductor systems and/or at low temperatures. Here, we report the magnetic
and semiconducting properties of phosphorene nanoribbons (PNRs). Static (SQUID)
and dynamic (EPR) magnetization probes demonstrate that at room temperature,
films of PNRs exhibit macroscopic magnetic properties, arising from their edge,
with internal fields of ~ 250 to 800 mT. In solution, a giant magnetic
anisotropy enables the alignment of PNRs at modest sub-1T fields. By leveraging
this alignment effect, we discover that upon photoexcitation, energy is rapidly
funneled to a dark-exciton state that is localized to the magnetic edge and
coupled to a symmetry-forbidden edge phonon mode. Our results establish PNRs as
a unique candidate system for studying the interplay of magnetism and
semiconducting ground states at room temperature and provide a stepping-stone
towards using low-dimensional nanomaterials in quantum electronics.Comment: 18 pages, 4 figure
Lack of observational evidence for quantum structure of space-time at Plank scales
It has been noted (Lieu & Hillmann, 2002) that the cumulative affect of
Planck-scale phenomenology, or the structure of space-time at extremely small
scales, can be lead to the loss of phase of radiation emitted at large
distances from the observer. We elaborate on such an approach and demonstrate
that such an effect would lead to an apparent blurring of distant
point-sources. Evidence of the diffraction pattern from the HST observations of
SN 1994D and the unresolved appearance of a Hubble Deep Field galaxy at z=5.34
lead us to put stringent limits on the effects of Planck-scale phenomenology.Comment: 12 pages, 3 figures, accepter for ApJ
Common Features at the Start of the Neurodegeneration Cascade
A single-molecule study reveals that neurotoxic proteins share common structural features that may trigger neurodegeneration, thus identifying new targets for therapy and diagnosis
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