146 research outputs found

    Simultaneous measurement of the maximum oscillation amplitude and the transient decay time constant of the QCM reveals stiffness changes of the adlayer

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    Interpretation of adsorption kinetics measured with a quartz crystal microbalance (QCM) can be difficult for adlayers undergoing modification of their mechanical properties. We have studied the behavior of the oscillation amplitude, A 0, and the decay time constant, Ď„, of quartz during adsorption of proteins and cells, by use of a home-made QCM. We are able to measure simultaneously the frequency, f, the dissipation factor, D, the maximum amplitude, A 0, and the transient decay time constant, Ď„, every 300ms in liquid, gaseous, or vacuum environments. This analysis enables adsorption and modification of liquid/mass properties to be distinguished. Moreover the surface coverage and the stiffness of the adlayer can be estimated. These improvements promise to increase the appeal of QCM methodology for any applications measuring intimate contact of a dynamic material with a solid surfac

    Unsupervised Incremental Online Learning and Prediction of Musical Audio Signals

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    Guided by the idea that musical human-computer interaction may become more effective, intuitive, and creative when basing its computer part on cognitively more plausible learning principles, we employ unsupervised incremental online learning (i.e. clustering) to build a system that predicts the next event in a musical sequence, given as audio input. The flow of the system is as follows: 1) segmentation by onset detection, 2) timbre representation of each segment by Mel frequency cepstrum coefficients, 3) discretization by incremental clustering, yielding a tree of different sound classes (e.g. timbre categories/instruments) that can grow or shrink on the fly driven by the instantaneous sound events, resulting in a discrete symbol sequence, 4) extraction of statistical regularities of the symbol sequence, using hierarchical N-grams and the newly introduced conceptual Boltzmann machine that adapt to the dynamically changing clustering tree in 3) , and 5) prediction of the next sound event in the sequence, given the last n previous events. The system's robustness is assessed with respect to complexity and noisiness of the signal. Clustering in isolation yields an adjusted Rand index (ARI) of 82.7%/85.7% for data sets of singing voice and drums. Onset detection jointly with clustering achieve an ARI of 81.3%/76.3% and the prediction of the entire system yields an ARI of 27.2%/39.2%

    Multiple shutters for a stereoscopic camera

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    Focal plane shutter assembly composed of three mechanically separate rotary shutters permits exposure of three separated photographic films simultaneously with exposure time of 0.08 second. Exposure time is repeatable within 2 percent, uniformity of exposure over all three films is within 5 percent

    An innovative speech-based user interface for smarthomes and IoT solutions to help people with speech and motor disabilities

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    A better use of the increasing functional capabilities of home automation systems and Internet of Things (IoT) devices to support the needs of users with disability, is the subject of a research project currently conducted by Area Ausili (Assistive Technology Area), a department of Polo Tecnologico Regionale Corte Roncati of the Local Health Trust of Bologna (Italy), in collaboration with AIAS Ausilioteca Assistive Technology (AT) Team. The main aim of the project is to develop experimental low cost systems for environmental control through simplified and accessible user interfaces. Many of the activities are focused on automatic speech recognition and are developed in the framework of the CloudCAST project. In this paper we report on the first technical achievements of the project and discuss future possible developments and applications within and outside CloudCAST

    A new clinopyroxene thermobarometer for mafic to intermediate magmatic systems

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    Clinopyroxene-only thermobarometry is one of the most practical tools to reconstruct crystallization pressures and temperatures of clinopyroxenes. Because it does not require any information of coexisting silicate melt or other co-crystallized mineral phases, it has been widely used to elucidate the physiochemical conditions of crystallizing magmas. However, previously calibrated clinopyroxene-only thermobarometers display low accuracy when being applied to mafic and intermediate magmatic systems. Hence, in this study, we present new empirical nonlinear barometric and thermometric models, which were formulated to improve the performance of clinopyroxene-only thermobarometry. Particularly, a total of 559 experimental runs conducted in the pressure range of 1gbar to 12gkbar have been used for calibration and validation of the new barometric and thermometric formulation. The superiority of our new models with respect to previous ones was confirmed by comparing their performance on 100 replications of calibration and validation, and the standard error of estimate (SEE) of the new barometer and thermometer are 1.66gkbar and 36.6gg C, respectively. Although our new barometer and thermometer fail to reproduce the entire test dataset, which has not been used for calibration and validation, they still perform well on clinopyroxenes crystallized from subalkaline basic to intermediate magmas (i.e., basaltic, basalt-andesitic, dacitic magma systems). Thus, their applicability should be limited to basaltic, basalt-andesitic and dacitic magma systems. In a last step, we applied our new thermobarometer to several tholeiitic Icelandic eruptions and established magma storage conditions exhibiting a general consistency with phase equilibria experiments. Therefore, we propose that our new thermobarometer represents a powerful tool to reveal the crystallization conditions of clinopyroxene in mafic to intermediate magmas. © Copyright

    When who and how matter: explaining the success of referendums in Europe

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    This article aims to identify the institutional factors that make a referendum successful. This comparative analysis seeks to explain the success of top-down referendums organized in Europe between 2001 and 2013. It argues and tests for the main effect of three institutional factors (popularity of the initiator, size of parliamentary majority, and political cues during referendum campaigns) and controls for the type of referendum and voter turnout. The analysis uses data collected from referendums and electoral databases, public opinion surveys, and newspaper articles. Results show that referendums proposed by a large parliamentary majority or with clear messages from political parties during campaign are likely to be successful

    Classical approach in quantum physics

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    The application of a classical approach to various quantum problems - the secular perturbation approach to quantization of a hydrogen atom in external fields and a helium atom, the adiabatic switching method for calculation of a semiclassical spectrum of hydrogen atom in crossed electric and magnetic fields, a spontaneous decay of excited states of a hydrogen atom, Gutzwiller's approach to Stark problem, long-lived excited states of a helium atom recently discovered with the help of PoincareËŠ\acute{\mathrm{e}} section, inelastic transitions in slow and fast electron-atom and ion-atom collisions - is reviewed. Further, a classical representation in quantum theory is discussed. In this representation the quantum states are treating as an ensemble of classical states. This approach opens the way to an accurate description of the initial and final states in classical trajectory Monte Carlo (CTMC) method and a purely classical explanation of tunneling phenomenon. The general aspects of the structure of the semiclassical series such as renormgroup symmetry, criterion of accuracy and so on are reviewed as well. In conclusion, the relation between quantum theory, classical physics and measurement is discussed.Comment: This review paper was rejected from J.Phys.A with referee's comment "The author has made many worthwhile contributions to semiclassical physics, but this article does not meet the standard for a topical review"
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