67 research outputs found
Atomistic mechanisms for the ordered growth of Co nano-dots on Au(788): comparison of VT-STM experiments and multi-scaled calculations
Hetero-epitaxial growth on a strain-relief vicinal patterned substrate has
revealed unprecedented 2D long range ordered growth of uniform cobalt
nanostructures. The morphology of a Co sub-monolayer deposit on a Au(111)
reconstructed vicinal surface is analyzed by Variable Temperature Scanning
Tunneling Microscopy (VT-STM) experiments. A rectangular array of nano-dots
(3.8 nm x 7.2 nm) is found for a particularly large deposit temperature range
lying from 60 K to 300 K. Although the nanodot lattice is stable at room
temperature, this paper focus on the early stage of ordered nucleation and
growth at temperatures between 35 K and 480 K. The atomistic mechanisms leading
to the nanodots array are elucidated by comparing statistical analysis of
VT-STM images with multi-scaled numerical calculations combining both Molecular
Dynamics for the quantitative determination of the activation energies for the
atomic motion and the Kinetic Monte Carlo method for the simulations of the
mesoscopic time and scale evolution of the Co submonolayer
Structure of self-organized Fe clusters grown on Au(111) analyzed by Grazing Incidence X-Ray Diffraction
We report a detailed investigation of the first stages of the growth of
self-organized Fe clusters on the reconstructed Au(111) surface by grazing
incidence X-ray diffraction. Below one monolayer coverage, the Fe clusters are
in "local epitaxy" whereas the subsequent layers adopt first a strained fcc
lattice and then a partly relaxed bcc(110) phase in a Kurdjumov-Sachs epitaxial
relationship. The structural evolution is discussed in relation with the
magnetic properties of the Fe clusters.Comment: 7 pages, 6 figures, submitted to Physical Review B September 200
Universal scaling in sports ranking
Ranking is a ubiquitous phenomenon in the human society. By clicking the web
pages of Forbes, you may find all kinds of rankings, such as world's most
powerful people, world's richest people, top-paid tennis stars, and so on and
so forth. Herewith, we study a specific kind, sports ranking systems in which
players' scores and prize money are calculated based on their performances in
attending various tournaments. A typical example is tennis. It is found that
the distributions of both scores and prize money follow universal power laws,
with exponents nearly identical for most sports fields. In order to understand
the origin of this universal scaling we focus on the tennis ranking systems. By
checking the data we find that, for any pair of players, the probability that
the higher-ranked player will top the lower-ranked opponent is proportional to
the rank difference between the pair. Such a dependence can be well fitted to a
sigmoidal function. By using this feature, we propose a simple toy model which
can simulate the competition of players in different tournaments. The
simulations yield results consistent with the empirical findings. Extensive
studies indicate the model is robust with respect to the modifications of the
minor parts.Comment: 8 pages, 7 figure
Relaxation and reconstruction on (111) surfaces of Au, Pt, and Cu
We have theoretically studied the stability and reconstruction of (111)
surfaces of Au, Pt, and Cu. We have calculated the surface energy, surface
stress, interatomic force constants, and other relevant quantities by ab initio
electronic structure calculations using the density functional theory (DFT), in
a slab geometry with periodic boundary conditions. We have estimated the
stability towards a quasi-one-dimensional reconstruction by using the
calculated quantities as parameters in a one-dimensional Frenkel-Kontorova
model. On all surfaces we have found an intrinsic tensile stress. This stress
is large enough on Au and Pt surfaces to lead to a reconstruction in which a
denser surface layer is formed, in agreement with experiment. The
experimentally observed differences between the dense reconstruction pattern on
Au(111) and a sparse structure of stripes on Pt(111) are attributed to the
details of the interaction potential between the first layer of atoms and the
substrate.Comment: 8 pages, 3 figures, submitted to Physical Review
Non-thermal transport of energy driven by photoexcited carriers in switchable solid states of GeTe
Phase change alloys have seen widespread use from rewritable optical discs to
the present day interest in their use in emerging neuromorphic computing
architectures. In spite of this enormous commercial interest, the physics of
carriers in these materials is still not fully understood. Here, we describe
the time and space dependence of the coupling between photoexcited carriers and
the lattice in both the amorphous and crystalline states of one phase change
material, GeTe. We study this using a time-resolved optical technique called
picosecond acoustic method to investigate the \textit{in situ} thermally
assisted amorphous to crystalline phase transformation in GeTe. Our work
reveals a clear evolution of the electron-phonon coupling during the phase
transformation as the spectra of photoexcited acoustic phonons in the amorphous
(-GeTe) and crystalline (-GeTe) phases are different. In particular
and surprisingly, our analysis of the photoinduced acoustic pulse duration in
crystalline GeTe suggests that a part of the energy deposited during the
photoexcitation process takes place over a distance that clearly exceeds that
defined by the pump light skin depth. In the opposite, the lattice
photoexcitation process remains localized within that skin depth in the
amorphous state. We then demonstrate that this is due to supersonic diffusion
of photoexcited electron-hole plasma in the crystalline state. Consequently
these findings prove the existence of a non-thermal transport of energy which
is much faster than lattice heat diffusion
Kondo screening of the spin and orbital magnetic moments of Fe impurities in Cu
We use x-ray magnetic circular dichroism to evidence the effect of correlations on the local impurity magnetic moment in an archetypal Kondo system, namely, a dilute Cu:Fe alloy. Applying the sum rules on the Fe L2,3 absorption edges, the evolution of the spin and orbital moments across the Kondo temperature are determined separately. The spin moment presents a crossover from a nearly temperature-independent regime below the Kondo temperature to a paramagneticlike regime above. Conversely, the weak orbital moment shows a temperature-independent behavior in the whole temperature range, suggesting different Kondo screening temperature scales for the spin and orbital moments
Evidence for Modification of the Electronic Density-of-States by Zero-Point Lattice Motion in One-Dimension - Luminescence and Resonance Raman Studies of An Mx Solid
Luminescence spectra, both emission and excitation, and the excitation dependence of the resonance Raman spectra, have been measured for the quasi-one-dimensional charge-density-wave material [Pt(en)2][Pt(en)2Cl2](ClO4)4, en = 1,2-diaminoethane. While the luminescence experiments show the existence of tail states at low temperature in the band gap region, the Raman measurements conclusively demonstrate that this tail does not arise from ordinary static structural disorder. These results can be explained by considering the zero-point motion of the lattice
Polarization state studies in second harmonic generation signals to trace atherosclerosis lesions
We have performed multi-photon image reconstructions as well as polarization state analyses inside an artery wall affected by atherosclerosis to investigate the changes in collagen structure. Mice, either healthy or affected by spontaneous atherosclerosis, have been used for this purpose. A two-photon imaging system has been used to investigate atherosclerotic lesions in the ascending aorta of mice. Second harmonic imaging has been performed alternatively on healthy samples and on affected region. The reconstructed images show that the spatial distribution of the collagen network seems disorganized by the disease. The polarization state studies reveal however that the apparent disorganization of the collagen is related to its spatially diffuse distribution and that the internal structure of the collagen fibers is not affected by the disease. In addition, a theoretical simulation of the second harmonic polarization states shows that they are consistent with the known 3D structure of the collagen network
Modern microwave methods in solid state inorganic materials chemistry: from fundamentals to manufacturing
No abstract available
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