738 research outputs found
Pressure-induced structural transitions in MgH
The stability of MgH has been studied up to 20~GPa using
density-functional total-energy calculations. At ambient pressure
-MgH takes a TiO-rutile-type structure. -MgH is
predicted to transform into -MgH at 0.39~GPa. The calculated
structural data for - and -MgH are in very good agreement
with experimental values. At equilibrium the energy difference between these
modifications is very small, and as a result both phases coexist in a certain
volume and pressure field. Above 3.84~GPa -MgH transforms into
-MgH; consistent with experimental findings. Two further
transformations have been identified at still higher pressure: i) - to
-MgH at 6.73 GPa and (ii) - to -MgH at
10.26~GPa.Comment: 4 pages, 4 figure
Structure and Thermodynamics of the Mixed Alkali Alanates
The thermodynamics and structural properties of the hexahydride alanates
(M2M'AlH6) with the elpasolite structure have been investigated. A series of
mixed alkali alanates (Na2LiAlH6, K2LiAlH6 and K2NaAlH6) were synthesized and
found to reversibly absorb and desorb hydrogen without the need for a catalyst.
Pressure-composition isotherms were measured to investigate the thermodynamics
of the absorption and desorption reactions with hydrogen. Isotherms for
catalyzed (4 mol% TiCl3) and uncatalyzed Na2LiAlH6 exhibited an increase in
kinetics, but no change in the bulk thermodynamics with the addition of a
dopant. A structural analysis using synchrotron x-ray diffraction showed that
these compounds favor the Fm-3m space group with the smaller ion (M') occupying
an octahedral site. These results demonstrate that appropriate cation
substitutions can be used to stabilize or destabilize the material and may
provide an avenue to improving the unfavorable thermodynamics of a number of
materials with promising gravimetric hydrogen densities.Comment: 6 pages, 7 figures,3 tables, submitted to PR
Perception of Nuclear Energy and Coal in France and the Netherlands
This study focuses on the perception of large scale application of nuclear energy and coal in the Netherlands and France. The application of these energy-sources and the risks and benefits are judged differently by various group in society. In Europe, France has the highest density of nuclear power plants and the Netherlands has one of the lowest. In both countries scientists and social scientists completed a questionnaire assessing the perception of the large scale application of both energy sources. Furthermore, a number of variables relating to the socio cultural and political circumstances were measured. The results indicate that the French had a higher risk perception and a more negative attitude toward nuclear power than the Dutch. But they also assess the benefits of the use of nuclear power to be higher. Explanations for these differences are discussed
Facile synthesis of nanosized sodium magnesium hydride, NaMgH<sub>3</sub>
The ternary magnesium hydride NaMgH3 has been synthesised via reactive milling techniques. The method employed neither a reactive H2 atmosphere nor high pressure sintering or other post-treatment processes. The formation of the ternary hydride was studied as a function of milling time and ball:powder ratio. High purity NaMgH3 powder (orthorhombic space group Pnma, a=5.437(2) Å, b=7.705(5) Å, c=5.477(2) Å; Z=4) was prepared in 5 h at high ball:powder ratios and characterised by powder X-ray diffraction (PXD), Raman spectroscopy and scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDX). The products formed sub-micron scale (typically 200–400 nm in size) crystallites that were approximately isotropic in shape. The dehydrogenation behaviour of the ternary hydride was investigated by temperature programmed desorption (TPD). The nanostructured hydride releases hydrogen in two steps with an onset temperature for the first step of 513 K
Phase Diagram of the 1D Anderson Lattice
We map out the phase diagram of the one--dimensional Anderson lattice by
studying the ground state magnetization as a function of band--filling using
the density matrix renormalization group technique. For strong coupling, we
find that the quarter--filled system has an S=0 ground state with strong
antiferromagnetic correlations. As additional electrons are put in, we find
first a ferromagnetic phase, as reported by M\"{o}ller and W\"{o}lfle, and then
a phase in which the ground state has total spin . Within this
phase, we find RKKY oscillations in the spin--spin correlation functions.Comment: REVTEX manuscript with 5 Postcript figures included in uu file.
Submitted to Phys. Rev.
Phase separation in a lattice model of a superconductor with pair hopping
We have studied the extended Hubbard model with pair hopping in the atomic
limit for arbitrary electron density and chemical potential. The Hamiltonian
considered consists of (i) the effective on-site interaction U and (ii) the
intersite charge exchange interactions I, determining the hopping of electron
pairs between nearest-neighbour sites. The model can be treated as a simple
effective model of a superconductor with very short coherence length in which
electrons are localized and only electron pairs have possibility of
transferring. The phase diagrams and thermodynamic properties of this model
have been determined within the variational approach, which treats the on-site
interaction term exactly and the intersite interactions within the mean-field
approximation. We have also obtained rigorous results for a linear chain (d=1)
in the ground state. Moreover, at T=0 some results derived within the random
phase approximation (and the spin-wave approximation) for d=2 and d=3 lattices
and within the low density expansions for d=3 lattices are presented. Our
investigation of the general case (as a function of the electron concentration
and as a function of the chemical potential) shows that, depending on the
values of interaction parameters, the system can exhibit not only the
homogeneous phases: superconducting (SS) and nonordered (NO), but also the
phase separated states (PS: SS-NO). The system considered exhibits interesting
multicritical behaviour including tricritical points.Comment: 15 pages, 9 figures; pdf-ReVTeX, final version, corrected typos;
submitted to Journal of Physics: Condensed Matte
Soft and non-soft structural transitions in disordered nematic networks
Properties of disordered nematic elastomers and gels are theoretically
investigated with emphasis on the roles of non-local elastic interactions and
crosslinking conditions. Networks originally crosslinked in the isotropic phase
lose their long-range orientational order by the action of quenched random
stresses, which we incorporate into the affine-deformation model of nematic
rubber elasticity. We present a detailed picture of mechanical quasi-Goldstone
modes, which accounts for an almost completely soft polydomain-monodomain (P-M)
transition under strain as well as a ``four-leaf clover'' pattern in
depolarized light scattering intensity. Dynamical relaxation of the domain
structure is studied using a simple model. The peak wavenumber of the structure
factor obeys a power-law-type slow kinetics and goes to zero in true mechanical
equilibrium. The effect of quenched disorder on director fluctuation in the
monodomain state is analyzed. The random frozen contribution to the fluctuation
amplitude dominates the thermal one, at long wavelengths and near the P-M
transition threshold. We also study networks obtained by crosslinking
polydomain nematic polymer melts. The memory of initial director configuration
acts as correlated and strong quenched disorder, which renders the P-M
transition non-soft. The spatial distribution of the elastic free energy is
strongly dehomogenized by external strain, in contrast to the case of
isotropically crosslinked networks.Comment: 19 pages, 15 EPS figure
An automatic critical care urine meter
Nowadays patients admitted to critical care units have most of their physiological parameters measured automatically by sophisticated commercial monitoring devices. More often than not, these devices supervise whether the values of the parameters they measure lie within a pre-established range, and issue warning of deviations from this range by triggering alarms. The automation of measuring and supervising tasks not only discharges the healthcare staff of a considerable workload but also avoids human errors in these repetitive and monotonous tasks. Arguably, the most relevant physiological parameter that is still measured and supervised manually by critical care unit staff is urine output (UO). In this paper we present a patent-pending device that provides continuous and accurate measurements of patient’s UO. The device uses capacitive sensors to take continuous measurements of the height of the column of liquid accumulated in two chambers that make up a plastic container. The first chamber, where the urine inputs, has a small volume. Once it has been filled it overflows into a second bigger chamber. The first chamber provides accurate UO measures of patients whose UO has to be closely supervised, while the second one avoids the need for frequent interventions by the nursing staff to empty the containe
Asthma in 9-year-old children of subfertile couples is not associated with in vitro fertilization procedures
Asthma is a chronic reversible obstructive airway disease, which is common among children and leads to respiratory impairment. Studies showed that asthma is more common among children born after in vitro fertilization (IVF) than among spontaneously conceived children. However, it is unknown which component of the IVF procedure contributes to this putative link. Therefore, the aim of this prospective follow-up study was to differentiate the possible effect of ovarian hyperstimulation from that of the in vitro culture procedure on asthma and rhinitis in 9-year-old children conceived with IVF. The study comprised three groups of singletons: (I) conceived with ovarian hyperstimulation-IVF (COH-IVF, n = 95); (II) conceived with modified natural cycle-IVF (MNC-IVF, n = 48); and (III) naturally conceived to subfertile couples (Sub-NC, n = 68). Parents filled out the validated Dutch version of the asthma questionnaire of the International Study of Asthma and Allergies. Asthma prevalence in the groups did not differ: COH-IVF n = 8 (8%); MNC-IVF n = 0 (0%); and Sub-NC n = 4 (6%). Adjustment for confounders did not alter the results.Conclusion: Neither ovarian hyperstimulation nor the in vitro culture procedure was associated with asthma and rhinitis at 9 years. IVF children had a similar prevalence of asthma compared with children conceived naturally by subfertile couples.Trial registration: ISRCTN76355836 What is Known: • An increased risk for asthma has been observed in children born after in vitro fertilization at preschool and school age. • The association between IVF and asthma may be partly explained by parental subfertility. What is New: • IVF children do not have a higher prevalence of asthma than children of subfertile couples conceived naturally. • Ovarian hyperstimulation used in IVF is not associated with asthma in 9-year-old children of subfertile couples.</p
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