Synthesis and application of zeolite and glass fiber supported zero valent iron nanoparticles as membrane component for removal nitrate and Cr (+6) ions

In the present paper the synthesis and characterization of zeolite and glass fiber supported zero valent iron nanoparticles (Ze-ZVI, GF-ZVI NPs) are reported.ZVI, Ze-ZVI and GF-ZVI NPs size, composition and morphology were characterized by Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), Energy Dispersive Spectroscopy (EDS). Synthesized nanostructures were tested as reducing agents of nitrate and hexavalent Chromium. Batch experiments were carried for revealing of efficacy of prepared nanomaterials (ZE-ZVI NPs and GF-ZVI NPs). Nitrate removal efficiency (at initial concentration 50 mg/mL) was rapidly increased from 26% to 76% for GF-ZVI NPs at 60-240 min time interval for and from 34% to 90% for ZE-ZVI NPs at the same time interval.Also was studied the efficacy of prepared nanostructures ZE-ZVI and ZE-ZVI NPs as membrane component with 5% of ZVI NPS weight contentfor the removal of nitrate from water solution that made 85% for ZE-ZVI NPs and 76% for GF-ZVI NPs, respectively. The results of this study indicate that the application of GF-ZVI and ZE-ZVI NPs as membrane component is advantageous because it allows to prevent the additional pollution of treated solution caused by unreacted ZVI NPs

Combined surgical treatment for missed rupture of triceps tendon associated with avulsion of the ulnar collateral ligament and flexor-pronator muscle mass

Triceps tendon ruptures are rare injuries. Coexistence of ipsilateral ulnar collateral ligament injury is even rarer. Here, we describe an unusual combination injury to elbow of a 39-year-old male construction worker consisting of triceps tendon rupture, avulsion of elbow ulnar collateral ligament and flexor pronator muscle origin ipsilaterally. A simultaneous repair and reconstruction of all damaged structures was proposed with individualized postoperative rehabilitation. Return to pre-injury level of activities obtained with this treatment protocol. High degree of suspicion and careful examination were needed to prevent missed diagnosis and prolonged instability which may be inevitable after inappropriate treatment of such injury

Tooth Whitening Effects on Bracket Bond Strength In Vivo

Objective: To test the hypothesis that there is no difference between the bracket survival rate of brackets bonded to bleached and unbleached teeth. Materials and Methods: Thirty-eight patients who required comprehensive orthodontic treatment were included in the study. A split mouth technique was used with one arch exposed to in-office whitening gel containing 38% hydrogen peroxide for 30 minutes, while the unbleached arch served as the control. Patients were divided into two groups: Brackets bonded within 24 hours after bleaching and brackets bonded 2–3 weeks after bleaching. The bracket survival rate was computed using the log-rank test (Kaplan-Meier Analysis). Results: A significantly higher rate of bracket failure was found with bleached teeth (16.6%) compared with unbleached teeth (1.8%) after 180 days. Brackets bonded within 24 hours of bleaching resulted in significantly higher clinical failure (14.5%) compared with those bonded after 3 weeks (2.1%). Adhesive Remnant Index scores of failed brackets revealed that the majority of failure in bleached teeth occurred in the enamel/resin interface. Conclusions: The hypothesis was rejected. Brackets bonded within 24 hours after bleaching have a significantly higher risk for bond failure. Orthodontic bonding should be delayed for 2–3 weeks if patients have a history of in-office bleaching with 38% hydrogen peroxide

rac-Diethyl 9-hy­droxy-9-methyl-7-phenyl-1,4-diaza­spiro­[4.5]decane-6,8-dicarboxyl­ate

The title mol­ecule, C21H30N2O5, is chiral with four stereogenic centres. The crystal is a racemate and consists of enanti­omeric pairs with the relative configuration rac-(6S*,7R*,8R*,9S*). The ethyl fragment of the eth­oxy­carbonyl group at position 6 is disordered in a 0.46 (3):0.54 (3) ratio. The crystal structure features inter­molecular N—H⋯O. Intra­molecular O—H⋯N and N—H⋯O hydrogen bonds also occur

The Influence of Aerosols on Forest Vegetation Cover in the South-West of Azerbaijan

Atmospheric pollution by anthropogenic emissions leads to an increase in the content of aerosols in the air. This causes distortions in the Earth remote sensing data in the visible ranges. Thus, the use of vegetation indices, in particular, the normalized differential vegetation index (NDVI), is difficult. In this regard, interest in the use of satellite images obtained in the short-wave infrared bands SWIR1 and SWIR2 has recently increased. Unlike NDVI, when calculating the AFRI-1600 and AFRI-2100 indices, the values of these bands are taken into account (instead of visible red). Therefore, these indices are called aerosol-free. The article addresses the issues of the NDVI and AFRI indices. The studies have been carried out in three regions located in the south-west of Azerbaijan. The initial data has been taken from 2000 and 2021 images obtained using the Landsat-5 and Landsat-8 satellites, respectively. The scanners of these satellites have ranges of 1600 and 2100 μm. The study has taken place in several stages. At the first stage, the AFRI-1600 indices have been calculated and the areas with high aerosol content for the indicated years have been identified. By studying the dynamics of the amount of aerosols, two types of sites have been identified. Type 1 sites are those where the aerosol content was high in 2000, but dropped in 2021. In type 2 sites, a high value of this indicator was not previously recorded, but was noted in 2021. The NDVI index value has been obtained for both categories, and the classification of the site coverage has been carried out. The results of superimposing index maps on each other have shown that an increase in aerosol content corresponds to a decrease in vegetation density, and vice versa, a decrease in aerosols corresponds to an increase in this indicator. Thus, the increased aerosol content has a negative effect on the condition of forest cover. This is confirmed by the VCI (vegetation condition index) maps

On the Accuracy of First-Order Numerical Derivatives in Multidimensional Digital Waveguide Mesh Topologies

Digital waveguide mesh (DWM) models are numerical solvers for the wave equation in N-dimensions. They are used for obtaining the traveling-wave solution in practical acoustical modeling applications. Although unstructured meshes can be used with DWMs, regular mesh topologies are traditionally used due to their implementation simplicity. This letter discusses the accuracy of first-order approximations to numerical derivatives on more general unstructured mesh topologies. The results are applied to structured, regular mesh topologies as used in DWM modeling. A comparison of 2-D and 3-D DWM topologies with respect to the accuracy of first-order approximations to numerical derivatives is presented

Missense mutation in the ATPase, aminophospholipid transporter protein ATP8A2 is associated with cerebellar atrophy and quadrupedal locomotion

Cataloged from PDF version of article.Cerebellar ataxia, mental retardation and dysequilibrium syndrome is a rare and heterogeneous condition. We investigated a consanguineous family from Turkey with four affected individuals exhibiting the condition. Homozygosity mapping revealed that several shared homozygous regions, including chromosome 13q12. Targeted next-generation sequencing of an affected individual followed by segregation analysis, population screening and prediction approaches revealed a novel missense variant, p.I376M, in ATP8A2. The mutation lies in a highly conserved C-terminal transmembrane region of E1 E2 ATPase domain. The ATP8A2 gene is mainly expressed in brain and development, in particular cerebellum. Interestingly, an unrelated individual has been identified, in whom mental retardation and severe hypotonia is associated with a de novo t(10;13) balanced translocation resulting with the disruption of ATP8A2. These findings suggest that ATP8A2 is involved in the development of the cerebro-cerebellar structures required for posture and gait in humans. © 2013 Macmillan Publishers Limited All rights reserved

VORTEX: Physics-Driven Data Augmentations Using Consistency Training for Robust Accelerated MRI Reconstruction

Deep neural networks have enabled improved image quality and fast inference times for various inverse problems, including accelerated magnetic resonance imaging (MRI) reconstruction. However, such models require a large number of fully-sampled ground truth datasets, which are difficult to curate, and are sensitive to distribution drifts. In this work, we propose applying physics-driven data augmentations for consistency training that leverage our domain knowledge of the forward MRI data acquisition process and MRI physics to achieve improved label efficiency and robustness to clinically-relevant distribution drifts. Our approach, termed VORTEX, (1) demonstrates strong improvements over supervised baselines with and without data augmentation in robustness to signal-to-noise ratio change and motion corruption in data-limited regimes; (2) considerably outperforms state-of-the-art purely image-based data augmentation techniques and self-supervised reconstruction methods on both in-distribution and out-of-distribution data; and (3) enables composing heterogeneous image-based and physics-driven data augmentations. Our code is available at https://github.com/ad12/meddlr.Comment: Accepted to MIDL 202

The influence of temperature (up to 120 °C) on the thermal conductivity of variably porous andesite

The thermal conductivity of volcanic rock is an essential input parameter in a wide range of models designed to better understand volcanic and geothermal processes. However, although volcanoes and geothermal reservoirs are often characterised by temperatures above ambient, laboratory thermal conductivity measurements are often performed at ambient temperature. In addition, there are currently few data on the temperature dependence of thermal conductivity for andesite, a common volcanic rock. Here, we provide elevated-temperature (up to 120 °C) laboratory measurements of thermal conductivity for variably porous (∼0.05 to ∼0.6) and variably glassy andesites from Mt. Ruapheu (New Zealand) using the transient hot-strip method. Our data show that (1) the thermal conductivity of these andesites has little to no temperature dependence and, therefore, (2) there is also no influence of porosity on the temperature dependence of thermal conductivity. We compare our new data with compiled published data to show that the thermal conductivity of volcanic rocks may decrease, remain constant, or increase as a function of temperature. We show that the thermal conductivity of amorphous glass and crystalline material increase and decrease, respectively, as temperature increases. We therefore interpret the temperature dependence of the thermal conductivity of volcanic rock to be dependent on glass content. The thermal conductivity of the studied andesites, the microstructure of which can be characterised by phenocrysts within a variably glassy groundmass, has little to no temperature dependence because the decrease in the thermal conductivity of the crystalline materials, due to decreases in lattice thermal conductivity, is offset by the increase in the thermal conductivity of the amorphous glass. A simple modelling approach, using the temperature dependence of the thermal conductivity of glass and crystalline material, provides a crystal content of 0.26 for a thermal conductivity independent of temperature, a common crystal content for andesite dome rock. Our findings imply that calculations of heat transfer through partially glassy volcanic rocks need not consider a temperature-dependent thermal conductivity, but that decreases and increases in thermal conductivity with temperature should be expected for fully crystallised or devitrified volcanic rocks and completely glassy volcanic rocks, respectively. We highlight that more experimental studies are now required to assess the evolution of thermal conductivity as a function of temperature in a wide range of volcanic rocks with different crystallinities