943 research outputs found
Using a Flow Through device to reconstruct the thermal gradient in the water column based on G. inflata Mg/Ca
We present Mg/Ca analyses performed via a Flow Through sequential dissolution device connected to an ICP-OES on the planktonic foraminifer Globorotalia inflata. The aim of the study is to explore the possibility to reconstruct the thermal gradient in the water column by separating non-crusted and crusted calcite phases in the tests of G. inflata using the difference between their Mg/Ca ratios as a measure of the thermal gradient. An important assumption is that the non-crusted part of the tests is calcified in shallow, warmer water than the crusted part. For analyses a range of different preparation steps were used to determine the ideal way of separating the phases. Foraminifer tests were (not) cleaned, (not) crushed, and (not) pulverized before online analysis with the FT device.
To analyze samples with a FT device the foraminifer tests are placed on a filter with a mesh of 0.45 μm preventing clay minerals to wash through. A sequential dissolution protocol first rinses the samples with buffered Seralpur water before QD HNO3 is added in small steps to create a ramp of increasing acid strength. As acid is kept constant at each concentration for several minutes, dissolution of a specific calcite phase can take place. Initial results show that it is most effective to slightly crush the tests without applying standard cleaning procedures, but rather analyze them without cleaning.
Samples were selected from the South Atlantic (core tops and specific downcore samples) and the Mediteterranean (plankton tows). All samples were chosen based on previous work on them to provide comparison with routinely analysed Mg/Ca ratios. The South Atlantic samples have been analyzed extensively as bulk samples separated in difference size fractions and crusted vs. non-crusted (Groeneveld and Chiessi). The Mediterranean samples were not only analyzed as bulk samples but also by Laser Ablation ICP-MS (von Raden et al.).
Results show that bulk analyses are reliably reproduced by the FT method, especially for samples which are dominated by crusted calcite. Samples which were uncrusted often gave much higher Mg/Ca ratios than the bulk analyses. These higher Mg/Ca ratios mainly occur in the plankton tow samples and were also identified with Laser Ablation ICP-MS. A possible reason for this could be the presence of a high Mg amorphous calcite layer on the outside of foraminifer tests which have not completed their calcification yet as was recently also pointed out in several other studies. Identification of the crusted and uncrusted phases, and therewith a thermal gradient, seems to give the expected differences but a more rigorous statistical treatment is needed to pinpoint singular dissolution phases
Cluster expansion for abstract polymer models. New bounds from an old approach
We revisit the classical approach to cluster expansions, based on tree
graphs, and establish a new convergence condition that improves those by
Kotecky-Preiss and Dobrushin, as we show in some examples. The two ingredients
of our approach are: (i) a careful consideration of the Penrose identity for
truncated functions, and (ii) the use of iterated transformations to bound
tree-graph expansions.Comment: 16 pages. This new version, written en reponse to the suggestions of
the referees, includes more detailed introductory sections, a proof of the
generalized Penrose identity and some additional results that follow from our
treatmen
Ultrafast dynamics of coherent optical phonons and nonequilibrium electrons in transition metals
The femtosecond optical pump-probe technique was used to study dynamics of
photoexcited electrons and coherent optical phonons in transition metals Zn and
Cd as a function of temperature and excitation level. The optical response in
time domain is well fitted by linear combination of a damped harmonic
oscillation because of excitation of coherent phonon and a
subpicosecond transient response due to electron-phonon thermalization. The
electron-phonon thermalization time monotonically increases with temperature,
consistent with the thermomodulation scenario, where at high temperatures the
system can be well explained by the two-temperature model, while below
50 K the nonthermal electron model needs to be applied. As the
lattice temperature increases, the damping of the coherent phonon
increases, while the amplitudes of both fast electronic response and the
coherent phonon decrease. The temperature dependence of the damping of
the phonon indicates that population decay of the coherent optical
phonon due to anharmonic phonon-phonon coupling dominates the decay process. We
present a model that accounts for the observed temperature dependence of the
amplitude assuming the photoinduced absorption mechanism, where the signal
amplitude is proportional to the photoinduced change in the quasiparticle
density. The result that the amplitude of the phonon follows the
temperature dependence of the amplitude of the fast electronic transient
indicates that under the resonant condition both electronic and phononic
responses are proportional to the change in the dielectric function.Comment: 10 pages, 9 figures, to appear in Physical Review
Relaxation Dynamics of Photoinduced Changes in the Superfluid Weight of High-Tc Superconductors
In the transient state of d-wave superconductors, we investigate the temporal
variation of photoinduced changes in the superfluid weight. We derive the
formula that relates the nonlinear response function to the nonequilibrium
distribution function. The latter qunatity is obtained by solving the kinetic
equation with the electron-electron and the electron-phonon interaction
included. By numerical calculations, a nonexponential decay is found at low
temperatures in contrast to the usual exponential decay at high temperatures.
The nonexponential decay originates from the nonmonotonous temporal variation
of the nonequilibrium distribution function at low energies. The main physical
process that causes this behavior is not the recombination of quasiparticles as
previous phenomenological studies suggested, but the absorption of phonons.Comment: 18 pages, 12 figures; to be published in J. Phys. Soc. Jpn. Vol. 80,
No.
AN ECOSYSTEM APPROACH TO FISHERIES IN THE SOUTHERN BENGUELA CONTEXT
The 2001 Reykjavík Declaration on Responsible Fisheries in the Marine Ecosystem and the Plan of Implementation of the 2002 World Summit on Sustainable Development highlighted the need in fisheries to look beyond considering only the target species and to consider in fisheries management the impacts of fishing on the ecosystem as a whole, as well as the impacts of the ecosystem on fisheries. This paper examines the practical implications of progressing towards ecosystem approaches by reference, in particular, to the FAO technical guidelines on the topic. It goes on to examine the major fishery types in South Africa and the southern Benguela, and to consider the probable impacts of those fisheries on target species, bycatch species and the ecosystem, as well as the indirect impacts on other ffected species. The review reveals that all fisheries have impacts beyond the target species and that an ecosystem approach is required in order to ensure the long-term sustainability of the living marine resources of the southern Benguela and the ecosystem as a whole. Finally, the likely obstacles to successful implementation of an ecosystem approach to fisheries in the southern Benguela are discussed.Afr. J. mar. Sci. 26: 9–3
Free energy of an SU(2) monopole-antimonopole pair
We present a high-statistic numerical study of the free energy of a
monopole-antimonopole pair in pure SU(2) theory. We find that the
monopole-antimonopole interaction potential exhibits a screened behavior, as
one would expect in presence of a monopole condensate. Screening occurs both in
the low-temperature, confining phase of the theory, and in the high-temperature
deconfined phase, with no evidence of a discontinuity of the screening mass
across the transition. The mass of the object responsible for the screening at
low temperature is approximately twice the established value for the lightest
glueball, indicating a prevalent coupling to glueball excitations. At high
temperature, the screening mass increases. We contrast the behavior of the
quantum system with that of the corresponding classical system, where the
monopole-antimonopole potential is of the Coulomb type.Comment: Latex, 22 pages, 8 figures. A mistake in the computer program
implementing the multihistogram method has been corrected and all the
affected numerical data have been revised. The main conclusions of the paper
are unchanged, but the screening masses turn out somehow larger. (We thank
Philippe de Forcrand for correspondence which helped us find the error.
Identity of the universal repulsive-core singularity with Yang-Lee edge criticality
Lattice and continuum fluid models with repulsive-core interactions typically
display a dominant, critical-type singularity on the real, negative activity
axis. Lai and Fisher recently suggested, mainly on numerical grounds, that this
repulsive-core singularity is universal and in the same class as the Yang-Lee
edge singularities, which arise above criticality at complex activities with
positive real part. A general analytic demonstration of this identification is
presented here using a field-theory approach with separate representation of
the repulsive and attractive parts of the pair interactions.Comment: 6 pages, 3 figure
Domain walls and perturbation theory in high temperature gauge theory: SU(2) in 2+1 dimensions
We study the detailed properties of Z_2 domain walls in the deconfined high
temperature phase of the d=2+1 SU(2) gauge theory. These walls are studied both
by computer simulations of the lattice theory and by one-loop perturbative
calculations. The latter are carried out both in the continuum and on the
lattice. We find that leading order perturbation theory reproduces the detailed
properties of these domain walls remarkably accurately even at temperatures
where the effective dimensionless expansion parameter, g^2/T, is close to
unity. The quantities studied include the surface tension, the action density
profiles, roughening and the electric screening mass. It is only for the last
quantity that we find an exception to the precocious success of perturbation
theory. All this shows that, despite the presence of infrared divergences at
higher orders, high-T perturbation theory can be an accurate calculational
tool.Comment: 75 pages, LaTeX, 14 figure
Size-Dependent Surface Plasmon Dynamics in Metal Nanoparticles
We study the effect of Coulomb correlations on the ultrafast optical dynamics
of small metal particles. We demonstrate that a surface-induced dynamical
screening of the electron-electron interactions leads to quasiparticle
scattering with collective surface excitations. In noble-metal nanoparticles,
it results in an interband resonant scattering of d-holes with surface
plasmons. We show that this size-dependent many-body effect manifests itself in
the differential absorption dynamics for frequencies close to the surface
plasmon resonance. In particular, our self-consistent calculations reveal a
strong frequency dependence of the relaxation, in agreement with recent
femtosecond pump-probe experiments.Comment: 8 pages + 4 figures, final version accepted to PR
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