23 research outputs found
A New Approach to Energy Calculation of Road Accidents against Fixed Small Section Elements Based on Close-Range Photogrammetry
[EN] This paper presents a new approach for energetic analyses of traffic accidents against fixed road elements using close-range photogrammetry. The main contributions of the developed approach are related to the quality of the 3D photogrammetric models, which enable objective and accurate energetic analyses through the in-house tool CRASHMAP. As a result, security forces can reconstruct the accident in a simple and comprehensive way without requiring spreadsheets or external tools, and thus avoid the subjectivity and imprecisions of the traditional protocol. The tool has already been validated, and is being used by the Local Police of Salamanca (Salamanca, Spain) for the resolution of numerous accidents. In this paper, a real accident of a car against a fixed metallic pole is analysed, and significant discrepancies are obtained between the new approach and the traditional protocol of data acquisition regarding collision speed and absorbed energy.S
Fe(II) complexes of pyridine-substituted thiosemicarbazone ligands as catalysts for oxidations with hydrogen peroxide
La reacción de tres complejos [FeII(TSC)2], donde TSC es una ligando de tipo tiosemicarbazona sustituido por piridina, con H2O2 en acetonitrilo no permitía acumular los correspondientes complejos de Fe(III), [FeIII(TSC)2]+. En su lugar, se generaba una mezcla de especies de Fe(II) diamagnéticas de bajo espín. Según los espectros obtenidos por espectrometría de masas, estas especies eran el resultado de la adición secuencial de hasta cinco átomos de oxígeno al complejo. Esta capacidad para la adición de átomos de oxígeno sugirió que dichas especies podrían ser activas para la transferencia de átomos de oxígeno a sustratos externos. Por ello, se evaluó la capacidad de estos complejos para la oxidación de tioanisol y estireno empleando H2O2 como oxidante inicial. Los complejos fueron activos tanto en la oxidación de tioanisol a su sulfóxido como en la de estireno a benzaldehído, con escalas temporales que indicaban la participación de las especies intermedias que contenían los átomos de oxígeno añadidos. Curiosamente, los ligandos libres y el complejo [Zn(Dp44mT)2] también catalizaban la sulfoxidación selectiva del tioanisol, pero eran ineficaces para catalizar la oxidación del estireno a benzaldehído. Estos hallazgos abren nuevas vías para el desarrollo de catalizadores metálicos basados en tiosemicarbazonas en procesos de oxidación de gran interés
Percutaneous iliosacral fixation in external rotational pelvic fractures. A biomechanical analysis
Although the gold standard in open book pelvic fractures remains the pubic symphysis (PS) plate fixation, the clinical outcomes are not satisfactory, despite the excellent anatomical reduction assessed radiologically. Some authors suggest that residual instability of the posterior pelvic elements may be responsible for the chronic pain and the early osteoarthritic changes in the sacroiliac joint (SIJ). Objective To evaluate whether the isolated posterior fixation with one or two iliosacral screws (ISSs) is sufficient to provide adequate stability for the treatment of Burgess Young APC-II (YB APC-II) type of pelvic ring injuries. Methods: Biomechanical experimental study using 7 fresh human pelvises, where an YB APC-II pelvic injury was previously implemented. The isolated posterior fixation of the pelvic ring with 1 or 2 ISSs directed in the S1 vertebra body was analysed in each specimen following an axial load of 300 N. The different displacement of the SIJ and of the PS were analysed in all three spatial axes, using the validated optical measurement system 3D PONTOS 5 M. A multivariate version of Friedman test (non-parametric ANOVA for repeated measures) was performed. Results: The isolated fixation of the SIJ with 1 ISS did not show any differences with respect to the intact pelvis (p = 0.851). Regarding the PS, both type of fixations (with 1 or 2 ISSs) confirmed an acceptable correction and adequate control of the PS even though with some differences compared to the intact pelvis (p = 0.01). The presence of the second ISS found not to offer any significant additional benefit. The three-dimensional analysis of the behaviour of the pelvic elements, in these two different types of fixation, did not show any statistical significant differences (p = 0.645). Conclusion: The posterior fixation with ISS can represent an alternative option for treatment of pelvic injuries associated with rotational instability. Further prospective clinical studies are necessary to determine, the influence of the residual pubic symphysis mobility in the every day life, when the above-mentioned technique is applied
A new approach to energy calculation of road accidents against fixed small section elements based on close-range Photogrammetry
This paper presents a new approach for energetic analyses of traffic accidents against fixed road elements using close-range photogrammetry. The main contributions of the developed approach are related to the quality of the 3D photogrammetric models, which enable objective and accurate energetic analyses through the in-house tool CRASHMAP. As a result, security forces can reconstruct the accident in a simple and comprehensive way without requiring spreadsheets or external tools,
and thus avoid the subjectivity and imprecisions of the traditional protocol. The tool has already been validated, and is being used by the Local Police of Salamanca (Salamanca, Spain) for the resolution of numerous accidents. In this paper, a real accident of a car against a fixed metallic pole is analysed, and significant discrepancies are obtained between the new approach and the traditional protocol of data acquisition regarding collision speed and absorbed energ
Catálogo y distribución geográfica de los Odonatos en la Región de Murcia (SE España).
Se actualiza el catálogo y la distribución del orden Odonata en la Región de Murcia, comparándolo a uno anterior realizado en los años 50 del siglo XX. Los resultados indican que a mitad del siglo pasado se localizaron 40 especies en 17 localidades, mientras
que las 2.087 citas recopiladas entre 1991-2017 confirman la presencia de 47 especies en 191 localidades. Se han identificado 11 nuevas especies para la Región de Murcia, que se pueden haber visto favorecidas por la construcción de charcas, embalses y otras infraestructuras para abastecer a las 225.000 ha de regadíos. De ellas, 9 especies se están expandiendo su área de distribución hacia el norte de Europa y/o Asia, efecto que podría estar relacionado con el proceso de cambio climático actual. Por el contrario, en la revisión actual no han sido detectadas 4 especies citadas en el estudio realizado a mediados del siglo XX
Tratamientos psicológicos empíricamente apoyados para adultos: Una revisión selectiva
Antecedentes: los tratamientos psicológicos han mostrado su eficacia, efectividad y eficiencia para el abordaje de los trastornos mentales; no obstante, considerando el conocimiento científico generado en los últimos años, no se dispone de trabajos de actualización en español sobre cuáles son los tratamientos psicológicos con respaldo empírico. El objetivo fue realizar una revisión selectiva de los principales tratamientos psicológicos empíricamente apoyados para el abordaje de trastornos mentales en personas adultas. Método: se recogen niveles de evidencia y grados de recomendación en función de los criterios propuestos por el Sistema Nacional de Salud de España (en las Guías de Práctica Clínica) para diferentes trastornos psicológicos. Resultados: los resultados sugieren que los tratamientos psicológicos disponen de apoyo empírico para el abordaje de un amplio elenco de trastornos psicológicos. El grado de apoyo empírico oscila de bajo a alto en función del trastorno psicológico analizado. La revisión sugiere que ciertos campos de intervención necesitan una mayor investigación. Conclusiones: a partir de esta revisión selectiva, los profesionales de la psicología podrán disponer de información rigurosa y actualizada que les permita tomar decisiones informadas a la hora de implementar aquellos procedimientos psicoterapéuticos empíricamente fundamentados en función de las características de las personas que demandan ayuda.
Background: Psychological treatments have shown their efficacy, effectiveness, and efficiency in dealing with mental disorders. However, considering the scientific knowledge generated in recent years, in the Spanish context, there are no updating studies about empirically supported psychological treatments. The main goal was to carry out a selective review of the main empirically supported psychological treatments for mental disorders in adults. Method: Levels of evidence and degrees of recommendation were collected based on the criteria proposed by the Spanish National Health System (Clinical Practice Guidelines) for different psychological disorders. Results: The results indicate that psychological treatments have empirical support for the approach to a wide range of psychological disorders. These levels of empirical evidence gathered range from low to high depending on the psychological disorder analysed. The review indicates the existence of certain fields of intervention that need further investigation. Conclusions: Based on this selective review, psychology professionals will be able to have rigorous, up-to-date information that allows them to make informed decisions when implementing empirically based psychotherapeutic procedures based on the characteristics of the people who require help
Kinetico-mechanistic Study on the Oxidation of Biologically Active Iron(II) Bis(thiosemicarbazone) Complexes by Air. Importance of NH···O2 Interactions As Established by Activation Volumes
Air oxidation of methanolic solutions of biologically active tridentate pyridyl thiosemicarbazone (TSC) complexes of the general formula [Fe(II)(TSC)2] has been studied at varying dioxygen concentrations, temperatures, and pressures. The data collected indicate that the activation entropy of the reaction increases linearly with the redox potential of the complexes in a more definite way than the activation enthalpy. However, a very distinct behavior is observed for the values of the activation volumes, which do not follow the expected entropy-volume parallel trend for all of the systems studied. The involvement of important interactions between the terminal NH groups of the coordinated TSC ligand and molecular dioxygen has been found to be significant by measurements carried out at varying hydrostatic pressures. Kinetic experiments run on analogous N-deuterated complexes confirm the importance of these noncovalent interactions, which are weaker for the less acidic ND groups. These interactions show the existence of an ordering/expansion process upon going from the reactants to the transition state, whenever an interaction between the polar terminal amino groups and dioxygen can be established
Self-assembly and properties of a discrete water-soluble prussian blue analogue FeII/CoIII cube: confinement of a water molecule in aqueous solution
Novel types of water-soluble anionic cubic cages, K4[{CoIII(Me3-Tacn)}4{FeII(CN)6}4] and Na4[{CoIII(Me3-Tacn)}4{FeII(CN)6}4] (Me3-Tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane), were prepared by means of a mechanistically designed self-assembly process between [Co(Me3-Tacn)Cl3] and A4[FeII(CN)6] (M = Na or K), consisting of a rate-limiting outer-sphere redox step, followed by a fast substitution/inner-sphere redox reaction sequence. These compounds show remarkable stability in aqueous solution at different pH ranges, displaying neat protonation processes and reversible oxidation with peroxodisulfate to its neutral {FeIII4CoIII4} form. Furthermore, the cages behave as a robust and water-soluble molecular Prussian Blue analogue capable of encapsulating {Na-OH2}+ pairs and K+ cations in aqueous solution, with the cubic structure of the complex being preserved. Substitution of the {Na-OH2}+ pairs by K+ is easily accomplished, and the electrochemical properties of the sodium and potassium salts of the new cages have been found to be dramatically dependent on the encapsulated units
Social but not solitary bees reject dangerous flowers where a conspecific has recently been attacked
International audienceSocial bees are known to avoid inflorescences marked with dead conspecifics or their smell. The avoidance response could be triggered by alarm signals actively given by attacked bees or by substances passively released through injuries as a by-product of the attack. To discriminate between these two options we note that both social and solitary bees are expected to react to nonsignalling cues associated with predation risk, while only social bees are expected to give alarm signals. We simulated risky inflorescences by pinching a landing bee with forceps, and compared the rate at which bees visited these experimental inflorescences and unmanipulated control inflorescences. We conducted the experiment with four species of social bees, Apis mellifera, Apis dorsata, Apis florea and Bombus terrestris and with three species of solitary bees, Eucera sp., Panurgus sp. and Nomia strigata. We found that while the three species of solitary bees responded similarly to control and experimental inflorescences, all four species of social bees strongly rejected inflorescences where we simulated a predation attempt. The finding that only social species avoided landing on dangerous inflorescences strongly suggests that the release of the alarm cue has been selected for its signalling value in social bees