Síntesis y eficacia de formulaciones de liberación lenta del herbicida Mesotriona

Ponencia presentada en el XV Congreso de la Sociedad Española de Malherbología SEMh 2015 “La Malherbología y la Transferencia Tecnológica” Sevilla, 19 al 22 de octubre de 2015[ES]: Se ha comprobado la eficacia de formulaciones desarrolladas mediante complejos surfactante-sepiolita en la reducción de la lixiviación del herbicida mesotriona. Entre las formulaciones desarrolladas se ha escogido aquella que presentaba un perfil de liberación más lento en ensayos in vitro. Al aplicarse en columnas de suelo se observó una lixiviación del herbicida y acumulación con la formulación comercial en los segmentos inferiores a diferencia de la formulación desarrollada, que se correlacionaba con un incremento de la bioeficacia en los segmentos superiores. En experimentos en parcelas de campo, a diferencia de la formulación comercial, no se observó un rebrote de las malas hierbas al usar la formulación desarrollada. [EN]: Synthesis and efficiency of slow release formulations of the herbicide mesotrione. The bioefficay of developed formulations based on surfactant-sepiolite complexes for reduced leaching of the herbicide mesotrione was tested. The formulation with a slower release pattern in in-vitro experiments was chosen for soil column and field experiments. In soil columns, the commercial formulation was leached and accumulated in the lower segments unlike the synthesized formulation, with a higher amount retained in the upper segments which was also correlated with a higher bioefficacy. In field experiments, a regrowth of weeds with the clay-based formulation was not observed, unlike the commercial formulation.Esta investigación ha recibido financiación a través de los proyectos CMT2009-07425 (MEC) cofinanciado por el Fondo Europeo de Desarrollo Regional (FEDER) y el Proyecto Bilateral Hispano-Argentino PRI-PIBAR-2011-1393 (MINECO-MINCYT). Carmen Galán agradece la beca Predoctoral disfrutada y asociada al Proyecto de Excelencia P09- RNM-4581.Peer Reviewe

Contribution in the foot health status in elderly people based on the results of biomechanics gait analysis

Purpose: To examine the correlation between the gait biomechanic analysis, foot dynamometry movements and different variables about the foot health status in elderly people. Relevance: Exact knowledge of the biomechanics of foot-print using this tool, as well as the relationship with the function and health status of the foot are important for planning the rehabilitation of the musculo skeletal pathology of the foot. Participants: 22 participants over 60 years old were recruited for a physical activity program. Methods: The variables were about anthropometric characteristics, about general and foot health status by FHSQ questionnaire scores ( foot pain, foot function, participant shoes, general health, physical activity, social capacity and vigour), about biomechanic gait analysis ( maximum pressures retro, mid and front foot, pressures times, times to initiate and end supports, maximum average pressures) and about analogue dynamometry variables in differente foot movements. Analysis: We used Pearson’s linear correlation with 95% Zr and a multivariant correlation. We looked for simple and multiple regression models. Results: the Pearson´s linear correlation showed relationships between foot pain variable with ending support in mid right foot variable (r = 0.562), maximum average pressure in mid right foot (r = 0.424), maximum average time pressure in front right foot (r = 0.588) and first right foot finger flexion (r = 0.434). A multivariant correlation was performed using the foots physical components of the FHSQ questionnaire scores how to dependent variable (foot pain) and the most relevant independents variables; ending support in mid right foot, maximum average time pressure in front right foot, first right foot finger flexion (r2 = 0.484; p < 0.007). Conclusions: We determined a significant quantitative relationship between biomechanics gait analysis, right foot dynamometry movements and the foot health status.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Alcohol-Based Adsorption Heat Pumps using Hydrophobic Metal-Organic Frameworks

The building climate industry and its influence on energy consumption have consequences on the environment due to the emission of greenhouse gasses. Improving the efficiency of this sector is essential to reduce the effect on climate change. In recent years, the interest in porous materials in applications such as heat pumps has increased for their promising potential. To assess the performance of adsorption heat pumps and cooling systems, here we discuss a multistep approach based on the processing of adsorption data combined with a thermodynamic model. The process provides properties of interest, such as the coefficient of performance, the working capacity, the specific heat or cooling effect, or the released heat upon adsorption and desorption cycles, and it also has the advantage of identifying the optimal conditions for each adsorbent-fluid pair. To test this method, we select several metal-organic frameworks that differ in topology, chemical composition, and pore size, which we validate with available experiments. Adsorption equilibrium curves were calculated using molecular simulations to describe the adsorption mechanisms of methanol and ethanol as working fluids in the selected adsorbents. Then, using a thermodynamic model we calculate the energetic properties combined with iterative algorithms that simultaneously vary all the required working conditions. We discuss the strong influence of operating temperatures on the performance of heat pump devices. Our findings point to the highly hydrophobic metal azolate framework MAF-6 as a very good candidate for heating and cooling applications for its high working capacity and excellent energy efficiency

Funcionalidad familiar y estilos de vida saludable en pacientes con linfoma Hodgkin en Bogotá

Se realizó una investigación cuantitativa descriptiva y transversal en un grupo de pacientes con linfoma Hodgkin para determinar la relación entre funcionalidad familiar y los estilos de vida saludable. Se usaron los instrumentos Escala de Evaluación de la Funcionalidad Familiar y el Health Promoting Lifestyle Profile II, los dos en su versión en español. El informante familiar fue el paciente con diagnóstico de linfoma Hodgkin. Se encontró predominio de un nivel bajo de funcionalidad familiar y frecuencia de estilos de vida saludable A veces y Frecuentemente; se determinó que solo hubo correlación con significancia estadística entre la dimensión Relaciones interpersonales, perteneciente a los estilos de vida saludable, y la funcionalidad familiar. Se requiere profundizar en esta temática con otros grupos de pacientes para lograr un mejor conocimiento al respecto

Short communication: Application of site‐level assessment of governance and equity (sage) methodology to a candidate oecm: AndakÍ municipal natural park, caquetÁ, colombia.

Governance is a fundamental aspect and precondition for conservation strategies, such as protected areas or OECMs. A methodology for Site-level Assessment of Governance and Equity (SAGE) has been proposed by IUCN to explore different aspects of governance, based on ten principles. This article describes the application of SAGE to a candidate OECM for what we believe is the first time: the Andakí Municipal Natural Park in the Amazon region of Colombia. The application of SAGE generated useful insights into different aspects of governance, including the importance of good communication and recognising and respecting the rights and responsibilities of different actors. Based on this experience, we believe that the SAGE methodology could be a useful tool not only to identify priorities for improving governance, but also to assess governance and equity in order to evaluate if an area meets the criteria for an OECM that it is governed and managed to achieve sustained and effective contributions to in situ conservation of biodiversity, associated ecosystem functions and services, and cultural, spiritual, socio-economic and other locally relevant values. © 2021, IUCN - International Union for the Conservation of Nature. All rights reserved.This process was made possible with the support of: a) the Local Protected Areas Regional Project implemented by Deutsche Gesellschaft f?r Internationale Zusammenarbeit (GIZ) GmbH, ICLEI ? Local Governments for Sustainability and the International Union for Conservation of Nature (IUCN); Environment ministries in Brazil, Colombia, Ecuador and Peru; commissioned by the German Federal Ministry for the Environment, Nature Protection and Nuclear Safety; b) the project adaptation of the OECM criteria to the Colombian context supported by PPD-GEF-PNUD, and implemented by Resnatur, Instituto Humboldt, Fundaci?n Natura and the Local Protected Areas Project; and c) the EUROCLIMA+ programme supported by Expertise France, GIZ and the International Institute for the Environment and Development (IIED); and d) Thora Amend, Vice Chair, IUCN World Commission on Protected Areas (thematic area: Governance)

Artificial intelligence assisted Mid-infrared laser spectroscopy in situ detection of petroleum in soils

A simple, remote-sensed method of detection of traces of petroleum in soil combining artificial intelligence (AI) with mid-infrared (MIR) laser spectroscopy is presented. A portable MIR quantum cascade laser (QCL) was used as an excitation source, making the technique amenable to field applications. The MIR spectral region is more informative and useful than the near IR region for the detection of pollutants in soil. Remote sensing, coupled with a support vector machine (SVM) algorithm, was used to accurately identify the presence/absence of traces of petroleum in soil mixtures. Chemometrics tools such as principal component analysis (PCA), partial least square-discriminant analysis (PLS-DA), and SVM demonstrated the e ectiveness of rapidly di erentiating between di erent soil types and detecting the presence of petroleum traces in di erent soil matrices such as sea sand, red soil, and brown soil. Comparisons between results of PLS-DA and SVM were based on sensitivity, selectivity, and areas under receiver-operator curves (ROC). An innovative statistical analysis method of calculating limits of detection (LOD) and limits of decision (LD) from fits of the probability of detection was developed. Results for QCL/PLS-DA models achieved LOD and LD of 0.2% and 0.01% for petroleum/soil, respectively. The superior performance of QCL/SVM models improved these values to 0.04% and 0.003%, respectively, providing better identification probability of soils contaminated with petroleum

Clinical and epidemiological characterization of a lymphogranuloma venereum outbreak in Madrid, Spain: co-circulation of two variants

AbstractThe lymphogranuloma venereum (LGV) outbreak described in the Netherlands in 2003, increased the interest in the genotyping of Chlamydia trachomatis. Although international surveillance programmes were implemented, these studies slowly decreased in the following years. Now data have revealed a new accumulation of LGV cases in those European countries with extended surveillance programmes. Between March 2009 and November 2011, a study was carried out to detect LGV cases in Madrid. The study was based on screening of C. trachomatis using commercial kits, followed by real-time pmpH-PCR discriminating LGV strains, and finally ompA gene was sequenced for phylogenetic reconstruction. Ninety-four LGV infections were identified. The number of cases increased from 10 to 30 and then to 54 during 2009–2011. Incidence of LGV was strongly associated with men who have sex with men; but in 2011, LGV cases were described in women and heterosexual men. Sixty-nine patients were also human immunodeficiency virus (HIV) positive, with detectable viral loads at the moment of LGV diagnosis, suggesting a high-risk of co-transmission. In fact, in four patients the diagnosis of HIV was simultaneous with LGV infection. The conventional treatment with doxycycline was prescribed in 75 patients, although in three patients the treatment failed. The sequencing of the ompA gene permitted identification of two independent transmission nodes. One constituted by 25 sequences identical to the L2b variant, and a second node including 37 sequences identical to L2. This epidemiological situation characterized by the co-circulation of two LGV variants has not been previously described, reinforcing the need for screening and genotyping of LGV strains

X-ray detection with Micromegas with background levels below 10−6^{-6} keV−1^{-1}cm−2^{-2}s−1^{-1}

Micromegas detectors are an optimum technological choice for the detection of low energy x-rays. The low background techniques applied to these detectors yielded remarkable background reductions over the years, being the CAST experiment beneficiary of these developments. In this document we report on the latest upgrades towards further background reductions and better understanding of the detectors' response. The upgrades encompass the readout electronics, a new detector design and the implementation of a more efficient cosmic muon veto system. Background levels below 10$^{-6}$keV$^{-1}$cm$^{-2}$s$^{-1}$ have been obtained at sea level for the first time, demonstrating the feasibility of the expectations posed by IAXO, the next generation axion helioscope. Some results obtained with a set of measurements conducted in the x-ray beam of the CAST Detector Laboratory will be also presented and discussed