Comprehensive platform for distribution transactiveenergy markets

Reducing the cost of distributed energy resources (DERs) such as renewables, storage,electric vehicles and smart loads is driving their increased connection to distributionsystems. Extracting maximum benefits from DERs require liberalising distribution sys-tems by allowing: (1) a distribution transactive energy market (DTEM) operated by alocal distribution operator (LDO) and (2) peer-to-peer (P2P), peer-to-LDO (P2LDO) andTransmission-to-LDO (T2LDO) type transactions. A DTEM will bring several benefitssuch as: (1) enhanced economic opportunity for DERs, making them more profitable and(2) increased social welfare benefiting both buyers and sellers. To achieve this objective, wedevelop a comprehensive three-phase DTEM platform that provides maximum economicopportunities for DERs and maximises social welfare that benefits all market participants,while considering P2P, P2LDO and T2LDO transactions, for both energy and ancillaryservices. Interaction between bulk electricity market independent system operator (ISO)and LDO controlled DTEM is presented. The DTEM model is implemented as a practi-cal mixed-integer linear programming formulation that includes a network reconfigurationfeature. The DTEM model is studied on three-phase 5-bus and 34-bus systems, demon-strating its effectiveness to settle energy and ancillary service transactions, while obtainingdistribution locational marginal prices. Results show that P2P transactions, when allowed,increase social welfare and increases profitability of DER

Capacity Market for Distribution System Operator – with Reliability Transactions – Considering Critical Loads and Microgrids

Conventional distribution system (DS) asset planning methods consider energy only from transmission systems (TS) and not from distributed energy resources (DER), leading to expensive plans. Newer transactive energy DS (TEDS) asset planning models, built on capacity market mechanisms, consider energy from both TS and DERs, leading to lower-cost plans and maximizing social welfare. However, in both methods the cost of higher reliability requirements for some users are socialized across all users, leading to lower social welfare. In this paper, a novel transactive energy capacity market (TECM) model is proposed for DS asset planning. It builds on TEDS incremental capacity auction models by provisioning for critical loads to bid and receive superior reliability as a service. The TECM model considers these reliability transactions, in addition, to selling energy transactions from TS and DERs, buying energy transactions from loads, and asset upgrade transactions from the network operator. The TECM model allows for islanded microgrids and network reconfiguration to maximize social welfare. The TECM model is assessed on several case studies, demonstrating that it achieves higher social welfare and a lower plan cost

Antibacterial Strategies from the Sea: Polymer-Bound Cl-Catechols for Prevention of Biofilm Formation

Inspired by the amino acid 2-chloro-4,5-dihydroxyphenylalanine (Cl-DOPA), present in the composition of the proteinaceous glue of the sandcastle worm Phragmatopoma californica, a simple strategy is presented to confer antifouling properties to polymer surfaces using (but not releasing) a bioinspired biocide. Cl-Dopamine is used to functionalize polymer materials and hydrogel films easily, to prevent biofilm formation on themThe authors thank Uwe Rietzler from the Max-Planck-Institut für Polymerforschung for the SFM-based thickness measurements

Redox Active Polymer Brushes with Phenothiazine Moieties

We have investigated two different concepts to synthesize redox active polymer brushes using surface initiated atomic transfer radical polymerization (SI-ATRP). This polymerization technique allows the synthesis of well-defined grafted polymer brushes. In the initial step the surface was functionalized with a self-assembling monolayer of the SI-ATRP starter. Then, polymer brushes carrying phenothiazine moieties were grafted from the surface via SI-ATRP. The first concept consists of polymerizing monomers with phenothiazine pendant moieties to directly incorporate the redox functionality as side group in the growing polymer brush. The second concept consists of using grafted activated ester brushes which are functionalized with phenothiazine redox moieties in a successive reaction step. The electrochemical properties of the grafted redox active brushes were examined by cyclic voltammetry. Furthermore, the surface morphology and the chemical composition of the polymer brushes were characterized using scanning force microscopy (SFM), X-ray techniques, and UV/vis spectroscopy. Apart from their redox behavior, the synthesized brushes revealed increased mechanical stability on the nanoscale

Adsorption, Aggregation, and Desorption of Proteins on Smectite Particles

We report on adsorption of lysozyme (LYS), ovalbumin (OVA), or ovotransferrin (OVT) on particles of a synthetic smectite (synthetic layered aluminosilicate). In our approach we used atomic force microscopy (AFM) and quartz crystal microbalance (QCM) to study the protein–smectite systems in water solutions at pH ranging from 4 to 9. The AFM provided insights into the adhesion forces of protein molecules to the smectite particles, while the QCM measurements yielded information about the amounts of the adsorbed proteins, changes in their structure, and conditions of desorption. The binding of the proteins to the smectite surface was driven mainly by electrostatic interactions, and hence properties of the adsorbed layers were controlled by pH. At high pH values a change in orientation of the adsorbed LYS molecules and a collapse or desorption of OVA layer were observed. Lowering pH to the value ≤4 caused LYS to desorb and swelling the adsorbed OVA. The stability of OVT–smectite complexes was found the lowest. OVT revealed a tendency to desorb from the smectite surface at all investigated pH. The minimum desorption rate was observed at pH close to the isoelectric point of the protein, which suggests that nonspecific interactions between OVT and smectite particles significantly contribute to the stability of these complexes

Stress–Structure Correlation in PS–PMMA Mixed Polymer Brushes

The ability to alter surface properties such as morphology and surface energy upon external stimuli makes switchable polymer surfaces a promising field of research. Mixed polymer brushes consisting of two different homopolymers covalently attached to a surface are one system in which surface properties can be switched. In this work the correlation between the change in structure and the resulting surface stress in thin poly­(methyl methacrylate)–polystyrene mixed polymer brush film upon exposure to selective solvents is investigated. By measuring the forces acting inside the film, we are able to achieve a deeper understanding of the observed structural changes. To obtain a thorough understanding of the film’s morphology, the structure is analyzed by scanning probe microscopy, X-ray reflectivity, and grazing incidence small-angle X-ray scattering (GISAXS). Upon exposure to acetic acid, a selective solvent for PMMA, the film showed a dimple-like structure. This is linked to collapsed domains of polystyrene covered by PMMA chains. Bending experiments resulted in tensile stress, pointing to attractive forces acting inside the polymer film. After exposure to dichloromethane, a good solvent for both polymers, bending experiments revealed a decreased but still high tensile stress, indicating that the microdomains are still present. The results of the experiments enable us to further explain the domain memory effect typically found in these kinds of mixed polymer brush systems

BJS commission on surgery and perioperative care post-COVID-19

Background: Coronavirus disease 2019 (COVID-19) was declared a pandemic by the WHO on 11 March 2020 and global surgical practice was compromised. This Commission aimed to document and reflect on the changes seen in the surgical environment during the pandemic, by reviewing colleagues experiences and published evidence. Methods: In late 2020, BJS contacted colleagues across the global surgical community and asked them to describe how severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) had affected their practice. In addition to this, the Commission undertook a literature review on the impact of COVID-19 on surgery and perioperative care. A thematic analysis was performed to identify the issues most frequently encountered by the correspondents, as well as the solutions and ideas suggested to address them. Results: BJS received communications for this Commission from leading clinicians and academics across a variety of surgical specialties in every inhabited continent. The responses from all over the world provided insights into multiple facets of surgical practice from a governmental level to individual clinical practice and training. Conclusion: The COVID-19 pandemic has uncovered a variety of problems in healthcare systems, including negative impacts on surgical practice. Global surgical multidisciplinary teams are working collaboratively to address research questions about the future of surgery in the post-COVID-19 era. The COVID-19 pandemic is severely damaging surgical training. The establishment of a multidisciplinary ethics committee should be encouraged at all surgical oncology centres. Innovative leadership and collaboration is vital in the post-COVID-19 era

BJS commission on surgery and perioperative care post-COVID-19

Coronavirus disease 2019 (COVID-19) was declared a pandemic by the WHO on 11 March 2020 and global surgical practice was compromised. This Commission aimed to document and reflect on the changes seen in the surgical environment during the pandemic, by reviewing colleagues' experiences and published evidence