Oligocene emplacement of the Eclogite Zone of the central Tauern Window, Eastern Alps, Austria

The EZ is an approximately 20km long and 2–3km wide coherent unit of the Tauern Window in the Eastern Alps. It is sandwiched between the Venedigerand the Glockner Nappe. While rocks in the EZ experienced HP metamorphic conditions (24 kbar/650°C), rocks from the underlying Venediger Nappe and the overlying Glockner Nappe only record lower alpine metamorphic conditions with peak pressures not exceeding 10 and 8 kbar, respectively. While metamorphism in the EZ is well dated with an average age of 31.5±0.7Ma (Glodny et al. 2005) the final emplacement of these different nappes is still under debate. Our Rb-Sr-data indicate that top-N thrusting at the base and large-scale folding of the EZ was coeval with sinistral strike-slip faulting at its upper boundary and eclogite-facies metamorphism in the EZ. The data also indicate that today’s nappe architecture must have been established in less than 2Ma after the eclogite facies metamorphism in the EZ. Very fast exhumation of the EZ was accomplished in a transpressional setting, which might explain why the exposed EZ is such a small unit.conferenc

Petrochronology of polygenetic white micas (Naxos, Greece)

Naxos in the Greek Cyclades preserves a type example of polymetamorphism. The southern and northern parts of the island record different Tertiary P–T histories between Eocene and Miocene times, including a blueschist facies event, one or more amphibolite/greenschist facies overprint(s) and contact metamorphism. Age attributions for these events are inconsistent in the literature. Here, we propose a new approach that combines electron probe microanalyzer (EPMA) characterization of the white mica (WM) with $^{39}$Ar-$^{40}$Ar–Rb-Sr multichronometry. Textural–petrographic–compositional observations reveal that the polygenetic WM consists of five different generations: pre-Eocene relicts, paragonite, high-Si phengite, low-Si phengite and muscovite. EPMA mapping of four WM samples, previously analysed by Rb-Sr, reveals major element compositions heterogeneous down to the μm scale. Each WM consists of chemically distinct generations, documenting submicron-scale retrogression of high-pressure (HP) phengite grains to muscovite. Four WM samples from a N-S traverse across the island were analysed by $^{39}$Ar-$^{40}$Ar stepheating, comparing coarse and fine sieve size fractions to obtain overdetermined K-Ar systematics. Fine sieve fractions are richer in Cl than coarse ones. Linear arrays in Cl/K-age isotope correlation diagrams show two predominant WM generations (one Cl-poor at ca. 38 Ma and one Cl-rich at <20 Ma). A lower-grade sample from southern Naxos was less pervasively recrystallized, provides older ages and preserves at least three WM generations, including a relict WM with a pre-Palaeocene K-Ar age, consistent with the high Ar retentivity of WM in the absence of complete recrystallization. The age of the Cl-poor end-member WM approximates the age of the HP event, 38 Ma. Ar inheritance in Cretaceous mica relicts is heterogeneous at the single-grain scale. Comparing the degassing rates of the WM fractions rules out ‘multidomain’ diffusion. As no sample is monomineralic, the degassing rate of each polygenetic mica is instead controlled by the mass balanced sum of the unrelated rate constants of its constituent minerals. Given the commonness of zoned and composite micas, the approach detailed here is potentially useful for reconstructing polyphase metamorphic histories worldwide

Methodische Untersuchungen am Kreta-Detachment (Kreta, Griechenland): Anzeichen für eine alpidische Metamorphose der Hangendscholle

Die Insel Kreta bildet den südlichen Rand der externen Helleniden, welche üblicherweise in zwei Deckenstapel untergliedert werden: Die unteren Decken (Plattenkalk und Phyllit-Quarzit- Einheit) sind durch eine alpidische HP-Metamorphose (Oligozän/Miozän) gekennzeichnet (Seidel et al. 1982, Jolivet et al. 1996), welche im Hangenden bislang nicht nachgewiesen wurde. Die Oberen Decken (i.w. Tripolitza- und Pindos-Einheit) bestehen aus karbonatischen Gesteinen und sind für eine petrologische PT-Abschätzung ungeeignet. Aufgrund des Gesteinshabitus wurden sie als unmetamorph eingestuft. Schlußfolgernd wird der Kontakt der beiden Stapel seit etwa zwanzig Jahren als krustales Megadetachment (‚Kreta- Detachment‘) aufgefaßt (Jolivet et al. 1996, Fassoulas et al. 1994, Kilias et al. 1994), wobei Versatzbeträge von über 100km angenommen werden (Ring et al. 2001, 2001). Ziel dieser Arbeit ist es Gemeinsamkeiten und Unterschiede der unmittelbar an das Detachment angrenzenden Einheiten herauszuarbeiten, um Rückschlüsse auf die tatsächliche Signifikanz der Störungszone zu ziehen.conferenc

Plume–lithosphere interactions and LIP-triggered climate crises constrained by the origin of Karoo lamproites

We identified a ca. 180 Ma diamondiferous lamproite event in Zambia, establishing a link between ultrapotassic volcanism and the early Jurassic Karoo flood basalt province of sub-Saharan Africa. The cratonic lamproites erupted through the Permo–Triassic Luangwa Rift structure, but MgO-rich ultrapotassic magma formation was unrelated to rifting and triggered by plume–lithosphere interactions during the Karoo LIP event. Elevated Li–Zn–Ti concentrations in magmatic olivine (up to 18.5 ppm Li at 86–90 mol.% forsterite) and strong Sr–Nd–Hf–Pb isotopic enrichment of the host lamproites ( 87Sr/86Sr = 0.70701–0.70855, εNd = − 10.8 to − 10, εHf = − 20.3 to − 19.1, 206Pb/204Pb = 16.8–17.5) suggest partial melting of phlogopite-metasomatized lithospheric mantle domains, at approximately 180–200 km depth. The mantle-like δ7 Li values (+2.8 to +5.7‰) of the most pristine lamproite samples are compatible with source enrichment by asthenosphere-derived melts, without significant involvement of recycled sedimentary components. This geochemical fingerprint stands in sharp contrast to the negative δ7 Li compositions of primitive K-rich volcanic rocks from collision zone settings, where the shallow mantle sources contain recycled sediment. Isotope modelling demonstrates that the sub-Saharan lamproites originate from a MARID-style metasomatized peridotitic mantle source that underwent incompatible element enrichment at ca. 1 Ga, during tectonic activity associated with Rodinia supercontinent formation. Plume-sourced basaltic and picritic magmas of the 180 Ma Karoo LIP interacted with such K-rich hydrous lithospheric mantle domains, thereby attaining enriched incompatible element and radiogenic isotope compositions. Nd–Hf isotope mass balance suggests that up to 25% of MARID-sourced lamproite melt component contributed to some of the high-Ti flood volcanic units. Although large quantities of volatiles can be transferred from Earth’s mantle to the atmosphere via plume–lithosphere interactions, it is unlikely that outgassing of mantle-sourced sulphur can exceed the climatic impact caused by the release of much more abundant carbon from thick continental roots. Thus, the excess SO2 required to account for transient atmospheric cooling during the early Jurassic, coincident with the Karoo LIP event, must have had a thermogenic origin near the surface of Earth

The occurrence of dental caries is associated with atherosclerosis

OBJECTIVE: Previous studies have suggested that marginal periodontitis is a risk factor for developing atherosclerosis. The objective of this study was to determine whether caries may also be associated with atherosclerosis. METHODS: The computed tomography data sets of 292 consecutive patients, 137 women and 155 men with a mean age of 54.1±17.3 years, were analyzed. Caries were quantified based on the number of decayed surfaces of all the teeth, and periodontitis was quantified on the basis of the horizontal bone loss in the jaw. The presence of chronic apical periodontitis (CAP) was assessed, and the aortic atherosclerotic burden was quantified using a calcium scoring method. RESULTS: The patients wit

Constraining Andean Propagation of Exhumation at the Limit of the Eastern Cordillera, NW Argentina, Using Low-Temperature Thermochronology in a Structural Context

Within the Central Andes of NW Argentina, the spatiotemporal distribution and style of deformation is strongly influenced by pre-Cenozoic heterogeneities, mostly related to the Salta rift extension in the Cretaceous. At the enigmatic junction of the thin-skinned Subandean belt and the thick-skinned Santa Barbara System, the Tilcara Range and adjacent San Lucas block, located within the Eastern Cordillera, show thermochronological and field evidence of multiple exhumation events. Mesozoic (140-115 Ma), pre-Andean exhumation of basement highs is constrained by unconformities between basement and syn-rift strata, as well as zircon (U-Th-Sm)/He cooling ages. Cenozoic Andean exhumation is quantified by apatite (U-Th-Sm)/He and fission track cooling ages, which were reset between the Late Cretaceous and Miocene. These data show that the westernmost Tilcara Range began exhuming in the late Oligocene-early Miocene (26-16 Ma), after which exhumation propagated to the border of the Eastern Cordillera in the middle Miocene (22-10 Ma). The onset of rapid exhumation in the San Lucas block, which is located east of the Tilcara Range, occurred in the late Miocene (10-8 Ma) in its western part, and in the late Miocene-early Pliocene (6-4 Ma) in its eastern part. Internal deformation of the San Lucas block, disturbing zircon (U-Th-Sm)/He and apatite fission track age patterns, predates propagation of rapid exhumation. The here presented low-temperature thermochronology data set thus quantifies the multi-phase exhumation history of the Eastern Cordillera of NW Argentina and constrains the timing of Andean propagation of exhumation within the Eastern Cordillera and the adjacent structural transition zone.Fil: van Kooten, Willemijn S. M. T.. Universitat Potsdam; AlemaniaFil: Sobel, Edward Robert. Universitat Potsdam; AlemaniaFil: del Papa, Cecilia Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Payrola Bosio, Patricio Augusto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta-Jujuy. Instituto de Bio y Geociencias del Noroeste Argentino. Universidad Nacional de Salta. Facultad de Ciencias Naturales. Instituto de Bio y Geociencias del Noroeste Argentino; ArgentinaFil: Glodny, Johannes. German Research Centre for Geosciences; Alemani

New thermocronological data of the Cretaceous-Cenozoic clastic sequences from the VINCHINA basin: Linkage between burial, exhumation and thermal flow variations

New apatite fission track (AFT) and (U–Th)/He (AHe) data from two sections recording Cretaceous-Cenozoic clastic successions (La Flecha - La Troya Sur creeks) in the northern sector of the Central Precordillera of Argentina are presented. The results show that the Ciénaga del Río Huaco, Puesto la Flecha and Vallecito Fms. would have crossed the 60 °C isotherm during burial, while the middle sector of the Vinchina Fm. would not have reached temperatures higher than 55 °C. Multimethod inverse thermal modeling suggests that the AFT ages of all the studied levels would not have been completely reset and allow inferring that the partial retention zone for the AHe system (AHe-PRZ) would have been reached during the Miocene in levels between the Vallecito and Vinchina Fms. Our 1D-modeling results for the Ciénaga del Río Huaco, Puesto la Flecha and Vallecito Fms. show that the maximum temperature would have been reached at ~15 Ma, with a sedimentary thickness of ~2750 m and a heat flow of 65 mW/m2. From these data, a geothermal gradient of ~27 °C/km at this time could be inferred. In turn, the Vinchina and Zapallar Fms. would have reached their maximum temperature at ~2 Ma, under a cooler thermal regime (20 mW/m2) and with an estimated geothermal gradient of <15 °C/km. Thus, a complex time-temperature trajectory is proposed. Maximum and cooling temperatures reached by each unit do not correspond in all cases to the maximum burial and exhumation times. Comparison of the thermal modelling from this work with those carried out by other authors for sections immediately to the north allows us to infer that the thermal regime within the Vinchina basin has important lateral variations. Finally, AFT and AHe analyzes carried out in this work constitute a baseline database of the thermal regime, which is necessary for future multiproxies studies that are being done to evaluate the preservation of primary thermal signals, and thus check their reliability for pealeoclimatic and paleoenvironmental interpretations.Fil: Wunderlin, Cecilia Ayelén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Collo, Gilda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Parra, Mauricio. Universidade de Sao Paulo; BrasilFil: Ezpeleta, Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Sánchez Nassif, Francisco Gabriel Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Flores, Marlene. Universidade de Sao Paulo; BrasilFil: Sobel, Edward Robert. Universitat Potsdam; AlemaniaFil: Glodny, Johannes. Universitat Potsdam; Alemani

Exhumation and structural evolution of the high-elevation Malcante Range, Eastern Cordillera, NW Argentina

As an integral part of the Eastern Cordillera, the fault-bounded Malcante mountain range (up to 5100 m) in the NW Argentine Andes (ca. 25°S) is located in the transition between the arid Puna Plateau to the west and the humid broken foreland to the east. At this latitude, the topographic gradient of the eastern Andean margin forms an efficient orographic barrier that causes pronounced east–west rainfall and surface-process gradients. In this setting, the Malcante Range is an important, yet poorly studied structural high formed during the Cenozoic topographic growth of the Central Andes. In this study, we combine (a) detailed field observations, (b) a two-dimensional structural reconstruction, (c) apatite fission track and (U–Th-Sm)/He thermochronology of bedrock samples from a vertical transect across the western flank of the Malcante Range, and (d) inverse thermal modelling using QTQt software with the aim of deciphering the exhumation history of this mountain range. Field data indicate the presence of an angular unconformity between Cenozoic foreland deposits and older sedimentary strata, suggesting an initial episode of deformation during the middle-late Eocene, while our thermal model constrains the onset of exhumation at ~10 Ma. We suggest that exhumation was related to the unroofing of the easily erodible sedimentary cover, which prevented significant initial surface uplift. This may have changed as more resilient bedrock was exposed at ~5 Ma according to the thermal model, promoting rapid rock uplift. In combination with published data, our thermochronology allows us to speculate on the existence of a zone of deformation concentrated in the area of the present-day Pasha (24.5°S), Malcante (25°S), and Agua de Castilla (25.4°S) mountain ranges by ca. 10 Ma.Fil: Payrola Bosio, Patricio Augusto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Bio y Geociencias del NOA. Universidad Nacional de Salta. Facultad de Ciencias Naturales. Museo de Ciencias Naturales. Instituto de Bio y Geociencias del NOA; ArgentinaFil: Zapata, Matias Sebastian. Smithsonian Tropical Research Institute; Panamá. University of Missouri; Estados UnidosFil: Sobel, Edward Robert. Universitat Potsdam. Mathematisch Nautrwissenschaften Fakultat. Institut für Geowissenschaften; AlemaniaFil: del Papa, Cecilia Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Pingel, Heiko. Universitat Potsdam. Mathematisch Nautrwissenschaften Fakultat. Institut für Geowissenschaften; AlemaniaFil: Glodny, Johannes. German Research Centre for Geosciences; AlemaniaFil: Ledesma, Jonathan Hernán. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentin

Inter-laboratory Characterisation of Apatite Reference Materials for Chlorine Isotope Analysis

Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca-10(PO4)(6)(F,Cl,OH)(2) solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for Cl-37/Cl-35 homogeneity using SIMS followed by delta Cl-37 characterisation by gas source mass spectrometry using both dual-inlet and continuous-flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than +/- 0.10% (1s) for the five samples with > 0.5% m/m Cl and +/- 0.19% (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38% between the mean Cl-37/Cl-35 ratios measured on three oriented apatite fragments. Furthermore, the results of GS-IRMS analyses show small but systematic offset of delta Cl-37(SMOC) values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 10(3)delta Cl-37(SMOC) values between +0.09 and +0.42 and in all cases with 1s <= +/- 0.25