Rol de la concentración de Níquel en cátodos de óxidos Mn-Ni

Se estudió el comportamiento catódico de óxidos NixMn3 - xO4 (x=0,4; 0,5; 0,6; 0,7; 0,8) en medio ácido. Se muestra la influencia del níquel en la reactividad electroquímica de los cátodos. Los mejores resultados se obtienen con NiO,6Mn2,4O4 . La reactividad de los óxidos en la reducción catódica se explica a través de la concentración de los cationes en la estructura y de la ocurrencia del proceso redox entre Ni2+ y Mn3+ de los sitios octaédricos de la espinela

Grids of Stellar Models and Frequencies with CLES + LOSC

We present a grid of stellar models, obtained with the CLES evolution code, following the specification of ESTA-Task1, and the corresponfing seismic properties, computed with the LOSC code. We provide a complete description of the corresponding files that will be available on the ESTA web-pages.Comment: 8 pages, accepted for publication in Astrophys. Space Sci. (CoRoT/ESTA Volume

High-resolution infrared spectroscopy as a tool to detect false positives of transit search programs

Transit search programs such as CoRoT and Kepler now have the capability of detecting planets as small as the Earth. The detection of these planets however requires the removal of all false positives. Although many false positives can be identified by a detailed analysis of the LCs, the detections of others require additional observations. An important source of false positives are faint eclipsing binaries within the PSF of the target stars. We develop a new method that allows us to detect faint eclipsing binaries with a separation smaller than one arcsec from target stars. We thereby focus on binaries that mimic the transits of terrestrial planets. These binaries can be either at the same distance as the target star (triple stars), or at either larger, or smaller distances. A close inspection of the problem indicates that in all relevant cases the binaries are brighter in the infrared than in the optical regime. We show how high resolution IR spectroscopy can be used to remove these false positives. For the triple star case, we find that the brightness difference between a primary and an eclipsing secondary is about 9-10 mag in the visual but only about 4.5-5.9 magnitudes in the K-band. We demonstrate how the triple star hypothesis can be excluded by taking a high-resolution IR spectrum. Simulations of these systems show that the companions can be detected with a false-alarm probability of 2%, if the spectrum has a S/N-ratio > 100. We show that high-resolution IR spectra also allows to detect most of the false positives caused by foreground or background binaries. If high resolution IR spectroscopy is combined with photometric methods, virtually all false positives can be detected without RV measurements. It is thus possible to confirm transiting terrestrial planets with a modest investment of observing time.Comment: 6 pages, 7 figure

Big data in economics: evolution or revolution?

The Big Data Era creates a lot of exciting opportunities for new developments in economics and econometrics. At the same time, however, the analysis of large datasets poses difficult methodological problems that should be addressed appropriately and are the subject of the present chapter

Low temperature transition to a superconducting phase in boron-doped silicon films grown on (001)-oriented silicon wafers

We report on a detailed analysis of the superconducting properties of boron-doped silicon films grown along the 001 direction by Gas Immersion Laser Doping. The doping concentration cB has been varied up to approx. 10 at.% by increasing the number of laser shots to 500. No superconductivity could be observed down to 40mK for doping level below 2.5 at.%. The critical temperature Tc then increased steeply to reach 0.6K for cB = 8 at%. No hysteresis was found for the transitions in magnetic field, which is characteristic of a type II superconductor. The corresponding upper critical field Hc2(0) was on the order of 1000 G, much smaller than the value previously reported by Bustarret et al. in Nature (London) 444, 465 (2006).Comment: 4 pages including 4 figures, submitted to PRB-Rapid Communicatio

Supramolecular chemistry of helical foldamers at the solid-liquid interface: self-assembled monolayers and anion recognition

The synthesis of a redox-active helical foldamer and its immobilization onto a gold electrode are described. These large molecular architectures are grafted in a reproducible manner and provide foldamer-based self-assembled monolayers displaying recognition properties

Evidence of electrochemical transduction of cation recognition by TEMPO derivatives

This work reports the first example of electrochemical cation binding transduction via nitroxyl groups. It shows the possibility to transduce a complexation without a pi-conjugated bridge between the redox and the host moieties. As expected, we confirm that the host/redox probe distance is a key point for transduction