701 research outputs found
Ultralong Copper Phthalocyanine Nanowires with New Crystal Structure and Broad Optical Absorption
The development of molecular nanostructures plays a major role in emerging
organic electronic applications, as it leads to improved performance and is
compatible with our increasing need for miniaturisation. In particular,
nanowires have been obtained from solution or vapour phase and have displayed
high conductivity, or large interfacial areas in solar cells. In all cases
however, the crystal structure remains as in films or bulk, and the
exploitation of wires requires extensive post-growth manipulation as their
orientations are random. Here we report copper phthalocyanine (CuPc) nanowires
with diameters of 10-100 nm, high directionality and unprecedented aspect
ratios. We demonstrate that they adopt a new crystal phase, designated
eta-CuPc, where the molecules stack along the long axis. The resulting high
electronic overlap along the centimetre length stacks achieved in our wires
mediates antiferromagnetic couplings and broadens the optical absorption
spectrum. The ability to fabricate ultralong, flexible metal phthalocyanine
nanowires opens new possibilities for applications of these simple molecules
Conceptualizing the adventure-sports coach
As a comparatively recent development, the adventure-sports coach struggles for a clear and distinct identity. The generic term ‘instructor’ no longer characterizes the role and function of this subgroup of outdoor professionals. Indeed, although the fields of adventure/outdoor education and leadership are comparatively well researched, the arrival of this ‘new kid on the block’ appears to challenge both the adventure-sports old guard and traditional views of sports coaching. In an attempt to offer clarity and stimulate debate, this paper attempts to conceptualize the adventure-sports coach in the context of the existing roles in the field and current motivations for activity in the outdoors. We identify issues that are specific to the adventure-sports coach while also recognizing those skills and competencies shared with other professionals, both in the adventure sports profession and traditional sports coaching fields. Based on this review, we offer a conceptual model which may be used to focus debate, stimulate research and, at a possible later stage, to underpin accreditation, training and professional development
Resolving the compact HII regions in N160A with HST
Using high-resolution imaging with the Hubble Space Telescope, we study the
Large Magellanic Cloud HII region N160A and uncover several striking features
of this complex massive star-forming site. The two compact high excitation HII
blobs (HEBs) A1 and A2 are for the first time resolved and their stellar
content and morphology is revealed. A1, being of higher excitation, is powered
by a single massive star whose strong wind has created a surrounding bubble. A2
harbors several exciting stars enshrouded inside large quantities of dust. The
whole N160A nebula is energized by three star clusters for which we obtain
photometry and study their color-magnitude diagram. The HII region is
particularly dusty, with extinction values reaching an A_v~2.5 mag in the
visible, and it is separated from the molecular cloud by an outstanding
ionization front. A previously detected infrared young stellar object is also
accurately located with respect to the HII region.Comment: 11 pages, 5 figures. Accepted for publication in Astronomy &
Astrophysics. A version of the paper with higher quality images is available
at http://wwwusr.obspm.fr/~heydari/projects/N16
Personality characteristics are independently associated with prospective memory in the laboratory, and in daily life, among older adults
Prospective memory (PM) can deteriorate with age and adversely influence health behaviours. Research suggests that personality is related to PM in healthy young adults, but we know little about the role of personality in the PM amongst older adults. Community-dwelling older adults (N = 152) completed the NEO Five-Factor Inventory-3 and PM measures. After adjusting for demographics and general cognition, higher neuroticism and lower levels of openness were independently associated with lower objectively-measured time- and event-based PM. Lower conscientiousness was the only personality predictor of self-reported everyday PM failures. Findings indicate that personality plays a role in PM functioning in the laboratory and daily life
Adherence to a Mediterranean diet and Alzheimer's disease risk in an Australian population
The Mediterranean diet (MeDi), due to its correlation with a low morbidity and mortality for many chronic diseases, has been widely recognised as a healthy eating model. We aimed to investigate, in a cross-sectional study, the association between adherence to a MeDi and risk for Alzheimer's disease (AD) and mild cognitive impairment (MCI) in a large, elderly, Australian cohort. Subjects in the Australian Imaging, Biomarkers and Lifestyle Study of Ageing cohort (723 healthy controls (HC), 98 MCI and 149 AD participants) completed the Cancer Council of Victoria Food Frequency Questionnaire. Adherence to the MeDi (0- to 9-point scale with higher scores indicating higher adherence) was the main predictor of AD and MCI status in multinominal logistic regression models that were adjusted for cohort age, sex, country of birth, education, apolipoprotein E genotype, total caloric intake, current smoking status, body mass index, history of diabetes, hypertension, angina, heart attack and stroke. There was a significant difference in adherence to the MeDi between HC and AD subjects (P < 0.001), and in adherence between HC and MCI subjects (P < 0.05). MeDi is associated with change in Mini-Mental State Examination score over an 18-month time period (P < 0.05) in HCs. We conclude that in this Australian cohort, AD and MCI participants had a lower adherence to the MeDi than HC participants.S Gardener, Y Gu, S R Rainey-Smith, J B Keogh, P M Clifton, S L Mathieson, K Taddei, A Mondal, V K Ward, N Scarmeas, M Barnes, K A Ellis, R Head, C L Masters, D Ames, S L Macaulay, C C Rowe, C Szoeke and R N Martins for the AIBL Research Grou
Planned Cesarean or planned vaginal delivery for twins : secondary analysis of randomized controlled trial
ACKNOWLEDGMENTS We thank all the participants in the Twin Birth Study and the staff at the Centre for Mother, Infant, and Child Research for their hard work and dedication. The Twin Birth Study was supported by a grant (63164) from the Canadian Institute of Health Research. P.T. and M.H.Z. were supported by a grant from The Netherlands Organization for Scientific Research (NWO ‐ grant number 401.16.080). The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript.Peer reviewedPublisher PD
Adherence to a Mediterranean diet and Alzheimer\u27s disease risk in an Australian population
The Mediterranean diet (MeDi), due to its correlation with a low morbidity and mortality for many chronic diseases, has been widely recognised as a healthy eating model. We aimed to investigate, in a cross-sectional study, the association between adherence to a MeDi and risk for Alzheimer’s disease (AD) and mild cognitive impairment (MCI) in a large, elderly, Australian cohort. Subjects in the Australian Imaging, Biomarkers and Lifestyle Study of Ageing cohort (723 healthy controls (HC), 98 MCI and 149 AD participants) completed the Cancer Council of Victoria Food Frequency Questionnaire. Adherence to the MeDi (0- to 9-point scale with higher scores indicating higher adherence) was the main predictor of AD and MCI status in multinominal logistic regression models that were adjusted for cohort age, sex, country of birth, education, apolipoprotein E genotype, total caloric intake, current smoking status, body mass index, history of diabetes, hypertension, angina, heart attack and stroke. There was a significant difference in adherence to the MeDi between HC and AD subjects (P\u3c0.001), and in adherence between HC and MCI subjects (P\u3c0.05). MeDi is associated with change in Mini-Mental State Examination score over an 18-month time period (P\u3c0.05) in HCs. We conclude that in this Australian cohort, AD and MCI participants had a lower adherence to the MeDi than HC participants
Greed, recklessness and/or dishonesty? An investigation into the micro-regulation and culture of five UK banks between 2004-2009
The author uses a multiple case study approach to examine five UK banks in her paper. The banks are Northern Rock, the Royal Bank of Scotland, Barclays, Lloyds Banking Group and HSBC. The author feels that it is appropriate to use a multiple case study here because it will be interesting to study the micro aspects of regulation and corporate governance of five UK banks. The banks have to comply with the same regulations and laws on a macro level, so it is essential to examine the differences between these banks on a micro level through reviewing annual reports and financial ratios. The case study is longitudinal, spanning across 2004-2009. In accordance to the aims of a case study, the author will describe, understand and explain the effects of the financial crisis 2007 on five UK banks. This case study provides an opportunity to examine the weaknesses and failures of corporate governance of five UK banks at a micro level. The author has two hypotheses at the beginning of the study. First, banks moved from a customer driven culture to sales driven one. Secondly, the banking culture during between 2004-2009 is one of greed, recklessness and dishonesty. With the caveat that one should not make generalisations, there is evidence from the case study that both hypotheses are correct to a certain extent
- …