Atomic and Molecular Gas in the Starburst Galaxy NGC4945

Spatial and kinematical correlations between HI and CO (2-1) emission of the southern spiral galaxy NGC4945 are studied with a common angular (23 arcsec) and velocity resolution (7 km/s). The 21cm continuum emission is also observed. The HI kinematics yield a galaxy mass of 1.4x10^{11} Mo within a radius of 380 arcsec, with molecular and neutral atomic gas each contributing 2%. Nuclear HI absorption at velocities 80 km/s higher than systemic indicates gas flowing towards the centre. HI features at each end of the major axis (R ~ 600 arcsec) are interpreted as spiral arms that are viewed tangentially and that also cause prominent emission features in the radio continuum, HI, and CO further inside the galaxy. A central elongated region showing non-circular motions is interpreted as a bar which fuels the nuclear starburst. HI and CO position-velocity data have been analysed using linear resonance theory and possible locations of resonances are identified.Comment: 16 pages, Latex file, 9 Postscript Figures, aa.cls and psfig.sty included. Accepted by Astronomy and Astrophysic

VLA observations of 6-cm excited OH

The VLA was used to determine precise positions for 4765-MHz OH maser emission sources toward star-forming regions which had been observed about seven months earlier with the Effelsberg 100-meter telescope. The observations were successful for K3-50, DR21EX, W75N, and W49A. No line was detected toward S255: this line had decreased to less than 5 per cent of the flux density observed only seven months earlier. The time-variability of the observed features during the past 30 years is summarised. In addition, to compare with the Effelsberg observations, the 4750-MHz and 4660-MHz lines were observed in W49A. These lines were found to originate primarily from an extended region which is distinguished as an exceptional collection of compact continuum components as well as by being the dynamical centre of the very powerful H_2 O outflow.Comment: 11 pages, will require MN style file to process. MNRAS, accepted Oct 15, 200

Herschel/HIFI Observations of Hydrogen Fluoride Toward Sagittarius B2(M)

Herschel/HIFI observations have revealed the presence of widespread absorption by hydrogen fluoride (HF) J = 1-0 rotational transition, toward a number of Galactic sources. We present observations of HF J = 1-0 toward the high-mass star-forming region Sagittarius B2(M). The spectrum obtained shows a complex pattern of absorption, with numerous features covering a wide range of local standard of rest velocities (-130 to 100 km -1). An analysis of this absorption yields HF abundances relative to H2 of ~1.3 {\times}10-8, in most velocity intervals. This result is in good agreement with estimates from chemical models, which predict that HF should be the main reservoir of gas-phase fluorine under a wide variety of interstellar conditions. Interestingly, we also find velocity intervals in which the HF spectrum shows strong absorption features that are not present, or are very weak, in spectra of other molecules, such as 13CO (1-0) and CS (2-1). HF absorption reveals components of diffuse clouds with small extinction that can be studied for the first time. Another interesting observation is that water is significantly more abundant than hydrogen fluoride over a wide range of velocities toward Sagittarius B2(M), in contrast to the remarkably constant H2O/HF abundance ratio with average value close to unity measured toward other Galactic sources

Recent advances using [Cp*Co(CO)I2] catalysts as a powerful tool for C-H functionalisation

Expansion of the synthetic chemists' toolbox is currently a topic of great interest, with successes providing access to novel compounds and more efficient routes towards new and known pharmaceuticals and agrochemicals. In this context, the development and application of first-row transition metal-catalysed C-H functionalisation protocols is seen as a key opportunity. This perspective provides a brief background of the discovery and application of high-valent cobalt-catalysis in C-H functionalisation, before detailing examples of recent advances in this field using the powerful [Cp*Co(CO)I2] catalysts for both terminal couplings and heterocycle formation. Finally, a discussion on the detection and isolation of elusive reactive intermediates in high-valent cobalt-catalysed C-H functionalisation, shedding light on how these catalyst systems operate, will be provided

Synthesis Imaging of Dense Molecular Gas in the N113 HII Region of the Large Magellanic Cloud

We present aperture synthesis imaging of dense molecular gas in the Large Magellanic Cloud, taken with the prototype millimeter receivers of the Australia Telescope Compact Array (ATCA). Our observations of the N113 HII region reveal a condensation with a size of ~6" (1.5 pc) FWHM, detected strongly in the 1-0 lines of HCO+, HCN and HNC, and weakly in C_2H. Comparison of the ATCA observations with single-dish maps from the Mopra Telescope and sensitive spectra from the Swedish-ESO Submillimetre Telescope indicates that the condensation is a massive clump of ~10^4 solar masses within a larger ~10^5 solar mass molecular cloud. The clump is centered adjacent to a compact, obscured HII region which is part of a linear structure of radio continuum sources extending across the molecular cloud. We suggest that the clump represents a possible site for triggered star formation. Examining the integrated line intensities as a function of interferometer baseline length, we find evidence for decreasing HCO+/HCN and HCN/HNC ratios on longer baselines. These trends are consistent with a significant component of the HCO+ emission arising in an extended clump envelope and a lower HCN/HNC abundance ratio in dense cores.Comment: 10 pages, 6 figures, to appear in Ap

H110alpha recombination-line emission and 4.8-GHz continuum emission in the Carina Nebula

We present results from observations of H110alpha recombination-line emission at 4.874 GHz and the related 4.8-GHz continuum emission towards the Carina Nebula using the Australia Telescope Compact Array. These data provide information on the velocity, morphology and excitation parameters of the ionized gas associated with the two bright HII regions within the nebula, Car I and Car II. They are consistent with both Car I and Car II being expanding ionization fronts arising from the massive star clusters Trumpler 14 and Trumpler 16, respectively. The overall continuum emission distribution at 4.8 GHz is similar to that at lower frequencies. For Car I, two compact sources are revealed that are likely to be young HII regions associated with triggered star formation. These results provide the first evidence of ongoing star formation in the northern region of the nebula. A close association between Car I and the molecular gas is consistent with a scenario in which Car I is currently carving out a cavity within the northern molecular cloud. The complicated kinematics associated with Car II point to expansion from at least two different centres. All that is left of the molecular cloud in this region are clumps of dense gas and dust which are likely to be responsible for shaping the striking morphology of the Car II components.Comment: 10 pages, 7 figures, accepted for publication in MNRA