Kinetic study of the reaction of leuco methylene blue with 2,6-dimethyl-p-benzoquinone in a reverse micellar system

The kinetics of the reaction of leuco methylene blue (MBH) with 2,6-dimethyl-p-benzoquinone (DMBQ) were studied in a heptane/bis(2-ethylhexyl)-sulfosuccinate (AOT)/water reverse micellar system. The pseudo-first-order rate constant (k (obsd)) obtained in the presence of excess of DMBQ was found to be proportional to the initial concentration of DMBQ for W (0)=3, 5, 10, 15 and 20 (W (0)=[H2O]/[AOT]). The second-order rate constant (k (2)=k (obsd)/[DMBQ](0)) increased with an increase in the W (0) value, but was almost independent of the concentration of the water pool. A mechanism involving the distribution of DMBQ between the reverse micellar interface and bulk organic solvent was proposed to explain these findings.</p

Hydrochemical characterization of a mine water geothermal energy resource in NW Spain

Abandoned and flooded mine networks provide underground reservoirs of mine water that can be used as a renewable geothermal energy source. A complete hydrochemical characterization of mine water is required to optimally design the geothermal installation, understand the hydraulic behavior of the water in the reservoir and prevent undesired effects such as pipe clogging via mineral precipitation. Water pumped from the Barredo-Figaredo mining reservoir (Asturias, NW Spain), which is currently exploited for geothermal use, has been studied and compared to water from a separate, nearby mountain mine and a river that receives mine water discharge and partially infiltrates into the mine workings. Although the hydrochemistry was altered during the flooding process, the deep mine waters are currently near neutral, net alkaline, high metal waters of Na-HCO3 type. Isotopic values suggest that mine waters are closely related to modern meteoric water, and likely correspond to rapid infiltration. Suspended and dissolved solids, and particularly iron content, of mine water results in some scaling and partial clogging of heat exchangers, but water temperature is stable (22 °C) and increases with depth, so, considering the available flow (> 100 L s− 1), the Barredo-Figaredo mining reservoir represents a sustainable, long-term resource for geothermal use

República: Año III Número 387 - (14/11/33)

PURPOSE OF REVIEW: The purpose of this study was to investigate the association of 26 inflammatory biomarkers (acute phase proteins, cytokines, chemokines) and renal markers with coronary lipid core burden index (LCBI) assessed by near-infrared spectroscopy (NIRS) imaging, as well as the association of these biomarkers with long-term cardiovascular outcome. RECENT FINDINGS: NIRS-derived LCBI has recently been shown to be an independent predictor of major adverse cardiac events (MACE). However, studies on the association between circulating biomarkers and NIRS-derived characteristics have not yet been performed. Between 2008 and 2011, 581 patients underwent diagnostic coronary angiography or percutaneous coronary intervention for stable angina pectoris or acute coronary syndrome (ACS). NIRS of a non-culprit vessel was performed in a subset of 203 patients. In multivariable analyses, TNF-alpha tended to be associated with higher LCBI (beta 0.088 ln (pg/ml) increase per unit LCBI; 95% CI 0.000-0.177, p = 0.05) after adjustment for clinical characteristics. However, this association did not persist after Bonferroni correction (statistical threshold 0.0019). Major adverse cardiac events (MACE) were registered in 581 patients during a median follow-up time of 4.7 years (IQR: [4.2-5.6] years). After adjustment for clinical characteristics and Bonferroni correction, IL-8 (HR 1.60; 95% CI [1.18-2.17] per ln (pg/ml), p = 0.002) was borderline associated with MACE and significantly associated with all-cause mortality or ACS (HR 1.75; 95% CI [1.24-2.48] per ln (pg/ml), p = 0.0015). In conclusion, we found that IL-8 was independently associated with clinical outcome, but altogether, the multiplex panel we investigated here did not render a useful blood biomarker of high LCBI

Wormhole Geometries In f(R,T)f(R,T) Gravity

We study wormhole solutions in the framework of f (R,T) gravity where R is the scalar curvature, and T is the trace of the stress-energy tensor of the matter. We have obtained the shape function of the wormhole by specifying an equation of state for the matter field and imposing the flaring out condition at the throat. We show that in this modified gravity scenario, the matter threading the wormhole may satisfy the energy conditions, so it is the effective stress-energy that is responsible for violation of the null energy condition.Comment: 9 pages, 4 figures, published version, references adde

Explorar e Investigar em Matemática: Uma Actividade Fundamental no Ensino e na Aprendizagem

Investigar, ensinar e aprender são actividades que podem estar presentes, de forma articulada, no ensino-aprendizagem da Matemática e na actividade profissional do professor. Para isso, é necessário conceber tarefas que possam ser o ponto de partida para investigações e explorações matemáticas dos alunos e discutir o modo como podem ser trabalhadas na sala de aula. Recorrendo a exemplos de actividades realizadas por professores de Matemática portugueses, analiso a actividade de aprendizagem suscitada por tarefas deste tipo e discuto as respectivas potencialidades. Finalmente, refiro as condições respeitantes à cultura profissional dos professores que podem favorecer uma actividade de investigação sobre a sua própria profissional, com relevo para a colaboração e a dimensão associativa.Researching, teaching and learning are activities that may be present, in coordination, teaching and learning of mathematics in the work of the teacher. Therefore, it is necessary to design tasks that may be the starting point for mathematical investigations and explorations of the students and discuss how they can be worked in the classroom. Drawing on examples of activities carried out by Portuguese teachers of mathematics by examining the activity of learning raised by such tasks and discuss their potencial. Finally, I refer to conditions relating to the professional culture of teachers who can promote the research activity on their own training, with an emphasis on collaboration and associative dimension

On some congruence properties of elliptic curves

In this paper, as a result of a theorem of Serre on congruence properties, a complete solution is given for an open question (see the text) presented recently by Kim, Koo and Park. Some further questions and results on similar types of congruence properties of elliptic curves are also presented and discussed.Comment: 11 pages, The title is changed. Thanks to a result of J.-P. Serre from his letter on June 15, 2009 to the author, a complete solution for an open question of Kim, Koo and Park is obtained in this fifth revised version. Some related questions and results are also presented and discusse

Temperatuurintegratie bij Anthurium andreanum

Met meerdaagse temperatuurintegratie is het mogelijk energie te besparen. Anthurium is een gewas dat relatief warm wordt geteeld en dat mogelijk schade ondervindt van lage temperaturen. Daarom is in dit onderzoek gekeken naar de invloed van temperatuurintegratie op productie en kwaliteit van Anthurium. Daarnaast is ook gekeken of energie besparing mogelijk is en waar temperatuur ondergrenzen liggen. Begin april 2002 zijn de Anthurium andreanum cultivars ‘Acropolis’, ‘Midori’ en ‘Tropical’ geplant in oasis verdeeld over twee kassen. In de rand rijen was als vierde ras ‘Fantasia’ geplant (dit ras staat bekend als gevoelig voor kou en als gevolg daarvan zou het snel van de wortel gaan)

Spectral properties of a generalized chGUE

We consider a generalized chiral Gaussian Unitary Ensemble (chGUE) based on a weak confining potential. We study the spectral correlations close to the origin in the thermodynamic limit. We show that for eigenvalues separated up to the mean level spacing the spectral correlations coincide with those of chGUE. Beyond this point, the spectrum is described by an oscillating number variance centered around a constant value. We argue that the origin of such a rigid spectrum is due to the breakdown of the translational invariance of the spectral kernel in the bulk of the spectrum. Finally, we compare our results with the ones obtained from a critical chGUE recently reported in the literature. We conclude that our generalized chGUE does not belong to the same class of universality as the above mentioned model.Comment: 12 pages, 3 figure

3D electrical resistivity of Gran Canaria island using magnetotelluric data

Gran Canaria, one of the two main islands of the Canary Archipelago off NW Africa, has been volcanically active for at least 15 million years. The island went through several volcanic cycles that varied greatly in composition and extrusive and intrusive activity. The complex orography of the island has excluded extensive land geophysical surveys on the island. A review of the available geophysical information on the island shows that it has been obtained mainly through marine and airborne geophysical surveys. A new dataset comprising 100 magnetotelluric soundings acquired on land has been used to obtain the first 3D electrical resistivity model of the island at crustal scale. The model shows high resistivity values close to the surface in the exposed Tejeda Caldera that extends at depth to the SE cutting the islands in half. Outside the inferred limits of the Tejeda Caldera the 3D model shows low resistivity values that could be explained by hydrothermal alteration at deeper levels and the presence of marine saltwater intrusion at shallower levels near the coast. The presence of unconnected vertical-like structures, with very low resistivity (<10 ohm m) could be associated to small convective cells is confirmed by the sensitivity analysis carried out in the present study. Those structures are the most likely candidates for a detailed analysis in order to determine their geothermal economic potential. A comprehensive review of existing geophysical data and models of Gran Canaria island and their comparison with the new 3D electrical resistivity model is presented.</p