Chandra HETGS Multiphase Spectroscopy Of The Young Magnetic O Star Theta(1) Orionis C

We report on four Chandra grating observations of the oblique magnetic rotator theta(1) Ori C (O5.5 V), covering a wide range of viewing angles with respect to the star\u27s 1060 G dipole magnetic field. We employ line-width and centroid analyses to study the dynamics of the X-ray - emitting plasma in the circumstellar environment, as well as line-ratio diagnostics to constrain the spatial location, and global spectral modeling to constrain the temperature distribution and abundances of the very hot plasma. We investigate these diagnostics as a function of viewing angle and analyze them in conjunction with new MHD simulations of the magnetically channeled wind shock mechanism on theta(1) Ori C. This model fits all the data surprisingly well, predicting the temperature, luminosity, and occultation of the X-ray - emitting plasma with rotation phase

Optimizing the Optoelectronic Properties of Conjugated Polymers Through Metal-Ligand Coordination

From the phones at our fingertips to the solar panels on our roofs, humans are becoming increasingly dependent on electronics for information, entertainment, and to power their daily lives. Further advancements are paving the way for a new age of high-performance, flexible devices. Organic electronics made from conjugated semiconducting polymers are showing great potential as a softer and more processable material than brittle silicon used in today’s devices, while exhibiting comparable charge transport to silicon. However, one key challenge with these organic polymers is the difficulty to control their optical properties and charge transport in devices. Electronics must interact with and alter their lighting while efficiently conducting electricity. Therefore, the desired material must be tuneable to precisely control these important properties. In this research, a novel organic diketopyrrolopyrrole-based conjugated polymer is presented as a leading candidate for optoelectronics. This polymer uses noncovalent metal-ligand interactions, enabled by using specific terpyridine ligands, to fine-tune its ability to emit light and transport electrons. Various transition metal ions, including Fe2+, Co2+, Zn2+, and Mn2+, were introduced into the polymer to determine which species would coordinate most efficiently with the ligand, altering its optical nature. Results from fluorescence and absorption spectroscopies showed that the manganese ion coordinated the weakest to the ligand, while iron and cobalt ions bound the most efficiently and optimally altered emission intensity. Thus, iron and cobalt were identified as great candidates for metal-ligand coordination within the polymer for optimal optoelectronic capabilities. These findings contribute to the continued pursuit of creating efficient organic optoelectronics through the promising technique of metal-ligand interactions. Keywords: organic electronics, conjugated polymer, optoelectronics, metal-ligand interaction

X-ray emission from the giant magnetosphere of the magnetic O-type star NGC 1624-2

We observed NGC 1624-2, the O-type star with the largest known magnetic field Bp~20 kG), in X-rays with the ACIS-S camera onboard the Chandra X-ray Observatory. Our two observations were obtained at the minimum and maximum of the periodic Halpha emission cycle, corresponding to the rotational phases where the magnetic field is the closest to equator-on and pole-on, respectively. With these observations, we aim to characterise the star's magnetosphere via the X-ray emission produced by magnetically confined wind shocks. Our main findings are: (i) The observed spectrum of NGC 1624-2 is hard, similar to the magnetic O-type star Theta 1 Ori C, with only a few photons detected below 0.8 keV. The emergent X-ray flux is 30% lower at the Halpha minimum phase. (ii) Our modelling indicated that this seemingly hard spectrum is in fact a consequence of relatively soft intrinsic emission, similar to other magnetic Of?p stars, combined with a large amount of local absorption (~1-3 x 10^22 cm^-2). This combination is necessary to reproduce both the prominent Mg and Si spectral features, and the lack of flux at low energies. NGC 1624-2 is intrinsically luminous in X-rays (log LX emission ~ 33.4) but 70-95% of the X-ray emission produced by magnetically confined wind shocks is absorbed before it escapes the magnetosphere (log LX ISM corrected ~ 32.5). (iii) The high X-ray luminosity, its variation with stellar rotation, and its large attenuation are all consistent with a large dynamical magnetosphere with magnetically confined wind shocks.Comment: Accepted in MNRAS 13 pages, 10 figures, 4 table

Chandra X-Ray Spectroscopy Of The Very Early O Supergiant HD 93129A: Constraints On Wind Shocks And The Mass-Loss Rate

We present an analysis of both the resolved X-ray emission-line profiles and the broad-band X-ray spectrum of the O-2 If* star HD 93129A, measured with the Chandra High Energy Transmission Grating Spectrometer ( HETGS). This star is among the earliest and most massive stars in the Galaxy, and provides a test of the embedded wind-shock scenario in a very dense and powerful wind. A major new result is that continuum absorption by the dense wind is the primary cause of the hardness of the observed X-ray spectrum, while intrinsically hard emission from colliding wind shocks contributes less than 10 per cent of the X-ray flux. We find results consistent with the predictions of numerical simulations of the line-driving instability, including line broadening indicating an onset radius of X-ray emission of several tenths of R-*. Helium-like forbidden-to-intercombination line ratios are consistent with this onset radius, and inconsistent with being formed in a wind-collision interface with the star\u27s closest visual companion at a distance of 100 au. The broad-band X-ray spectrum is fitted with a dominant emission temperature of just kT = 0.6 keV along with significant wind absorption. The broad-band wind absorption and the line profiles provide two independent measurements of the wind mass-loss rate:. M = 5.2(-1.5)(+1.8) x 10(-6) and 6.8(-2.2)(+2.8) x 10(-6) M-circle dot yr(-1), respectively. This is the first consistent modelling of the X-ray line-profile shapes and broad-band X-ray spectral energy distribution in a massive star, and represents a reduction of a factor of 3-4 compared to the standard H alpha mass-loss rate that assumes a smooth wind

Relative Reactivity of the Metal-Amido versus Metal-Imido Bond in Linked Cp-Amido and Half-Sandwich Complexes of Vanadium

Treatment of (η5-C5H4C2H4NR)V(N-t-Bu)Me (R = Me, i-Pr) and CpV(N-p-Tol)(N-i-Pr2)Me (Cp = η5-C5H5) with B(C6F5)3 or [Ph3C][B(C6F5)4] results in formation of the corresponding cations, [(η5-C5H4C2H4NR)V(N-t-Bu)]+ and [CpV(N-p-Tol)(N-i-Pr2)]+. The latter could also be generated as its N,N-dimethylaniline adduct by treatment of the methyl complex with [PhNMe2H][BAr4] (Ar = Ph, C6F5). Instead, the analogous reaction with the linked Cp-amido precursor results in protonation of the imido-nitrogen atom. Sequential cyclometalation of the amide substituents gave cationic imine complexes [(η5-C5H4C2H4NCR'2)V(NH-t-Bu)]+ (R' = H, Me) and methane. Reaction of cationic [(η5-C5H4C2H4NR)V(N-t-Bu)]+ with olefins affords the corresponding olefin adducts, whereas treatment with 1 or 2 equiv of 2-butyne results in insertion of the alkyne into the vanadium-nitrogen single bond, affording the mono- and bis-insertion products [(η5-C5H4C2H4N(i-Pr)C2Me2)V(N-t-Bu)]+ and [(η5-C5H4C2H4N(i-Pr)C4Me4)V(N-t-Bu)]+. The same reaction with the half-sandwich compound [CpV(N-p-Tol)(N-i-Pr2)]+ results in a paramagnetic compound that, upon alcoholysis, affords sec-butylidene-p-tolylamine, suggesting an initial [2+2] cycloaddition reaction. The difference in reactivity between the V-N bond versus the V=N bond was further studied using computational methods. Results were compared to the isoelectronic titanium system CpTi(NH)(NH2). These studies indicate that the kinetic product in each system is derived from a [2+2] cycloaddition reaction. For titanium, this was found as the thermodynamic product as well, whereas the insertion reaction was found to be thermodynamically more favorable in the case of vanadium.

Perception of clear fricatives by normal-hearing and simulated hearing-impaired listeners

This is the publisher's version, also available electronically from http://scitation.aip.org/content/asa/journal/jasa/123/2/10.1121/1.2821966.Speakers may adapt the phonetic details of their productions when they anticipate perceptual difficulty or comprehension failure on the part of a listener. Previous research suggests that a speaking style known as clear speech is more intelligible overall than casual, conversational speech for a variety of listener populations. However, it is unknown whether clear speech improves the intelligibility of fricative consonants specifically, or how its effects on fricative perception might differ depending on listener population. The primary goal of this study was to determine whether clear speech enhances fricative intelligibility for normal-hearing listeners and listeners with simulated impairment. Two experiments measured babble signal-to-noise ratio thresholds for fricative minimal pair distinctions for 14 normal-hearing listeners and 14 listeners with simulated sloping, recruiting impairment. Results indicated that clear speech helped both groups overall. However, for impaired listeners, reliable clear speech intelligibility advantages were not found for non-sibilant pairs. Correlation analyses comparing acoustic and perceptual data indicated that a shift of energy concentration toward higher frequency regions and greater source strength contributed to the clear speecheffect for normal-hearing listeners. Correlations between acoustic and perceptual data were less consistent for listeners with simulated impairment, and suggested that lower-frequency information may play a role

Global X-ray properties of the O and B stars in Carina

The key empirical property of the X-ray emission from O stars is a strong correlation between the bolometric and X-ray luminosities. In the framework of the Chandra Carina Complex Project, 129 O and B stars have been detected as X-ray sources; 78 of those, all with spectral type earlier than B3, have enough counts for at least a rough X-ray spectral characterization. This leads to an estimate of the Lx/Lbol ratio for an exceptional number of 60 O stars belonging to the same region and triples the number of Carina massive stars studied spectroscopically in X-rays. The derived log(Lx/Lbol) is -7.26 for single objects, with a dispersion of only 0.21dex. Using the properties of hot massive stars listed in the literature, we compare the X-ray luminosities of different types of objects. In the case of O stars, the Lx/Lbol ratios are similar for bright and faint objects, as well as for stars of different luminosity classes or spectral types. Binaries appear only slightly harder and slightly more luminous in X-rays than single objects; the differences are not formally significant (at the 1% level), except for the Lx/Lbol ratio in the medium (1.0--2.5keV) energy band. Weak-wind objects have similar X-ray luminosities but they display slightly softer spectra compared to "normal" O stars with the same bolometric luminosity. Discarding three overluminous objects, we find a very shallow trend of harder emission in brighter objects. The properties of the few B stars bright enough to yield some spectral information appear to be different overall (constant X-ray luminosities, harder spectra), hinting that another mechanism for producing X-rays, besides wind shocks, might be at work. However, it must be stressed that the earliest and X-ray brightest amongst these few detected objects are similar to the latest O stars, suggesting a possibly smooth transition between the two processes.Comment: 30 pages, 9 figures. Accepted for the ApJS Special Issue on the Chandra Carina Complex Project (CCCP), scheduled for publication in May 2011. All 16 CCCP Special Issue papers are available at http://cochise.astro.psu.edu/Carina_public/special_issue.html through 2011 at leas

Modelling semantic transparency

We present models of semantic transparency in which the perceived trans- parency of English noun–noun compounds, and of their constituent words, is pre- dicted on the basis of the expectedness of their semantic structure. We show that such compounds are perceived as more transparent when the first noun is more frequent, hence more expected, in the language generally; when the compound semantic rela- tion is more frequent, hence more expected, in association with the first noun; and when the second noun is more productive, hence more expected, as the second ele- ment of a noun–noun compound. Taken together, our models of compound and con- stituent transparency lead us to two conclusions. Firstly, although compound trans- parency is a function of the transparencies of the constituents, the two constituents differ in the nature of their contribution. Secondly, since all the significant predictors in our models of compound transparency are also known predictors of processing speed, perceived transparency may itself be a reflex of ease of processing