963 research outputs found
Electromotive forces and the Meissner effect puzzle
In a voltaic cell, positive (negative) ions flow from the low (high)
potential electrode to the high (low) potential electrode, driven by an
`electromotive force' which points in opposite direction and overcomes the
electric force. Similarly in a superconductor charge flows in direction
opposite to that dictated by the Faraday electric field as the magnetic field
is expelled in the Meissner effect. The puzzle is the same in both cases: what
drives electric charges against electromagnetic forces? I propose that the
answer is also the same in both cases: kinetic energy lowering, or `quantum
pressure'
Neutrino masses, leptogenesis and dark matter in hybrid seesaw
We suggest a hybrid seesaw model where relatively ``light''right-handed
neutrinos give no contribution to the neutrino mass matrix due to a special
symmetry. This allows their Yukawa couplings to the standard model particles to
be relatively strong, so that the standard model Higgs boson can decay
dominantly to a left and a right-handed neutrino, leaving another stable
right-handed neutrino as cold dark matter. In our model neutrino masses arise
via the type-II seesaw mechanism, the Higgs triplet scalars being also
responsible for the generation of the matter-antimatter asymmetry via the
leptogenesis mechanism.Comment: 4 page
A simple model for magnetism in itinerant electron systems
A new lattice model of interacting electrons is presented. It can be viewed
as a classical Hubbard model in which the energy associated to electron
itinerance is proportional to the total number of possible electron jumps.
Symmetry properties of the Hubbard model are preserved. In the half-filled band
with strong interaction the model becomes the Ising model. The main features of
the magnetic behavior of the model in the one-dimensional and mean-field cases
are studied.Comment: 9 pages, 3 figures, to be published in Physica
A multinuclear solid state NMR, density functional theory and X-Ray diffraction study of hydrogen bonding in Group I hydrogen dibenzoates
An NMR crystallographic approach incorporating multinuclear solid state NMR (SSNMR), X-ray structure determinations and density functional theory (DFT) are used to characterise the H bonding arrangements in benzoic acid (BZA) and the corresponding Group I alkali metal hydrogen dibenzoates (HD) systems. Since the XRD data often cannot precisely confirm the proton position within the hydrogen bond, the relationship between the experimental SSNMR parameters and the ability of gauge included plane augmented wave (GIPAW) DFT to predict them becomes a powerful constraint that can assist with further structure refinement. Both the 1H and 13C MAS NMR methods provide primary descriptions of the H bonding via accurate measurements of the 1H and 13C isotropic chemical shifts, and the individual 13C chemical shift tensor elements; these are unequivocally corroborated by DFT calculations, which together accurately describe the trend of the H bonding strength as the size of the monovalent cation changes. In addition, 17O MAS and DOR NMR form a powerful combination to characterise the O environments, with the DOR technique providing highly resolved 17O NMR data which helps verify unequivocally the number of inequivalent O positions for the conventional 17O MAS NMR to process. Further multinuclear MAS and static NMR studies involving the quadrupolar 7Li, 39K, 87Rb and 133Cs nuclei, and the associated DFT calculations, provide trends and a corroboration of the H bond geometry which assist in the understanding of these arrangements. Even though the crystallographic H positions in each H bonding arrangement reported from the single crystal X-ray studies are prone to uncertainty, the good corroboration between the measured and DFT calculated chemical shift and quadrupole tensor parameters for the Group I alkali species suggest that these reported H positions are reliable
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