Paper Session III-C - Corrosion Protection of Launch Infrastructure and Flight Hardware at the Kennedy Space Center

The Kennedy Space Center (KSC) is a major source of worldwide corrosion expertise. Corrosion studies began at KSC in 1966 during the Gemini/Apollo Programs with the evaluation of long-term protective coatings for the atmospheric protection of carbon steel. NASA’s KSC Beach Corrosion Test Site was established at that time. The site has provided over 30 years of technical information on the long-term performance of many materials and continues to be upgraded with state-of-the-art capabilities to meet the current and future needs of NASA, other government agencies, and industry for corrosion protection. With the introduction of the Space Shuttle in 1981, the already highly corrosive conditions at the launch pad were rendered even more severe by the acidic exhaust from the solid rocket boosters. In the years that followed, numerous studies have identified materials, coatings, and maintenance procedures for launch hardware and equipment exposed to the highly corrosive environment at the launch pad. KSC’s Materials Science Laboratories have conducted testing and research in the field of corrosion since 1968. The Corrosion Laboratory was established in 1985 and was outfitted with stateof- the-art equipment to conduct research and materials evaluation in many different corrosive environments. In 2000, the Corrosion Technology Testbed was created in order to achieve KSC’s goal of increased participation in research and development. The Corrosion Technology Testbed is staffed with scientists, corrosion engineers and technicians with extensive experience in the field of corrosion and is outfitted with state-of-the-art instrumentation and equipment to develop new corrosion control technologies and to investigate, evaluate, and determine materials behavior in many different corrosive environments. Its facilities include an Atmospheric Exposure Test Site, documented by the American Society of Materials (ASM) as one of the most corrosive naturally occurring environments in the world, an Electrochemistry Laboratory, a Seawater Immersion System, a Coatings Application Laboratory, and an Accelerated Corrosion Laboratory. The site has recently been outfitted with network connectivity for data acquisition through the Internet. A historical perspective highlighting the lessons learned in over thirty years of corrosion research, materials evaluation, and development work aimed at protecting and enhancing the safety and reliability of the nation’s launch infrastructure and hardware will be presented

Electrochemical Evaluation of Stainless Steels in Acidified Sodium Chloride Solutions

This paper presents the results of an investigation in which several 300-series stainless steels (SS): AISI S30403 SS (UNS S30403), AISI 316L SS (UNS S31603), and AISI 317L SS (LINS S31703), as well as highly-alloyed: SS 254-SMO (UNS S32154), AL-6XN (N08367) and AL29-4C (UNS S44735), were evaluated using DC electrochemical techniques in three different electrolyte solutions. The solutions consisted of neutral 3.55% NaCl, 3.55% NaCl in 0.1N HCl, and 3.55% NaCl in 1.0N HCl. These solutions were chosen to simulate environments that are less, similar, and more aggressive, respectively, than the conditions at the Space Shuttle launch pads. The electrochemical test results were compared to atmospheric exposure data and evaluated for their ability to predict the long-term corrosion performance of the subject alloys. The electrochemical measurements for the six alloys indicated that the higher-alloyed SS 254-SMO, AL29-4C, and AL-6XN exhibited significantly higher resistance to localized corrosion than the 300-series SS. There was a correlation between the corrosion performance of the alloys during a two-year atmospheric exposure and the corrosion rates calculated from electrochemical (polarization resistance) measurements

Nucleon-Nucleon interaction, charge symmetry breaking and renormalization

We study the interplay between charge symmetry breaking and renormalization in the NN system for s-waves. We find a set of universality relations which disentangle explicitly the known long distance dynamics from low energy parameters and extend them to the Coulomb case. We analyze within such an approach the One-Boson-Exchange potential and the theoretical conditions which allow to relate the proton-neutron, proton-proton and neutron-neutron scattering observables without the introduction of extra new parameters and providing good phenomenological success.Comment: 15 pages, 6 figure

Paper Session II-B - Performance Status of the Mars Environmental Compatibility Assessment Electrometer

The Mars Environmental Compatibility Assessment electrometer is an instrument intended to fly on a future Mars lander mission. The electrometer was designed primarily to investigate (1) the electrostatic interaction between the Martian soil and five different types of insulators attached to the electrometer, which are to be rubbed over the Martian soil. The MECA Electrometer is also capable of measuring (2) the presence of charged particles in the Martian atmosphere, (3) the local electric field strength, and (4) the local temperature. We have tested and evaluated the measurement capabilities of the MECA Electrometer under simulated Martian surface conditions using facilities located in the Electromagnetic Physics Testbed at KSC. The results of the study have demonstrated that rubbing an insulator over the Martian soil simulant does triboelectrically charge up the insulator\u27s surface. However, the charge buildup on an insulator was found to be as low as 1% of the current maximum range of the electrometer when it is rubbed through Martian soil. This indicates that the overall gain of the MECA Electrometer could be increased by a factor of 50, if measurements at the 50% level of full-range sensitivity are desired. The ion gauge, which detects the presence of charged particles, was also evaluated over the pressure range 13 - 533 mbar, and results will be presented

Paper Session I-A - Electrostatic Charging of Polymers by Particle Impact at Martian Atmospheric Pressurs

Studies of the electrostatic interaction between micrometer-sized particles and polymer surfaces are of great interest to NASA’s planetary exploration program. The unmanned landing missions to Mars planned for this decade as well as the possible manned missions that might take place during the second decade of this century require a better understanding of the electrostatic response of the materials used in landing crafts and equipment when exposed to wind-blown dust or to surface dust and sand particles. We report on preliminary experiments designed to measure the electrostatic charge developed on three polymer surfaces as they are impacted by Mars simulant particles less than 5 micrometers in diameter moving at 20 m/s. Experiments were performed in a CO2 atmosphere at 10 mbars of pressure using a particle delivery method that propels the particles without contact. The polymer surfaces, commonly used in space applications, were chosen so that they span the triboelectric series

Paper Session II-A - Results of a Wheel Electrometer for Measuring the Triboelectric Properties of Martian Regolith

The preliminary results of a prototype Wheel Electrometer System (WES) are presented that show that it is indeed possible to use the static electricity generated between polymers and soils after contact (triboelectricity) as a means of detecting property changes. Changes in the triboelectric signals offer information as to the mechanical properties of the soil such as grain size differences, texture, hardness and even moisture content. Initially, four polymers are chosen that span the triboelectric series such as Teflon, Lucite, Fiberglass and Lexan. It is shown that the average charge on Teflon is much higher when rolled over beach sand as compared to Martian simulant and limestone. Lucite was the most susceptible to particle size differences, while Lexan was able to detect underlying materials in the case of a soil lightly covered with a different soil type. All polymers responded differently when rolled over dry soil compared with moist soil. This information can be used as a type of triboelectric spectroscopy when a library of data is used to categorize the unique charging characteristics of individual polymers. This system is of great interest to planetary scientists and such measurements may be included in future Mars rover missions

Assessing availability and greenhouse gas emissions of lignocellulosic biomass feedstock supply – case study for a catchment in England

© 2019 Society of Chemical Industry and John Wiley & Sons, Ltd.Feedstocks from lignocellulosic biomass (LCB) include crop residues and dedicated per¬ennial biomass crops. The latter are often considered superior in terms of climate change mitigation potential. Uncertainty remains over their availability as feedstocks for biomass provision and the net greenhouse gas emissions (GHG) during crop production. Our objective was to assess the optimal land allocation to wheat and Miscanthus in a specific case study located in England, to increase bio¬mass availability, improve the carbon balance (and reduce the consequent GHG emissions), and mini¬mally constrain grain production losses from wheat. Using soil and climate variables for a catchment in east England, biomass yields and direct nitrogen emissions were simulated with validated process-based models. A ‘Field to up-stream factory gate’ life-cycle assessment was conducted to estimate indirect management-related GHG emissions. Results show that feedstock supply from wheat straw can be supplemented beneficially with LCB from Miscanthus grown on selected low-quality soils. In our study, 8% of the less productive arable land area was dedicated to Miscanthus, increasing total LCB provision by about 150%, with a 52% reduction in GHG emission per ton LCB delivered and only a minor effect on wheat grain production (−3%). In conclusion, even without considering the likely carbon sequestration in impoverished soils, agriculture should embrace the opportunities to provide the bioeconomy with LCB from dedicated, perennial crops.Peer reviewe

A Neural Circuit Arbitrates between Persistence and Withdrawal in Hungry Drosophila

In pursuit of food, hungry animals mobilize significant energy resources and overcome exhaustion and fear. How need and motivation control the decision to continue or change behavior is not understood. Using a single fly treadmill, we show that hungry flies persistently track a food odor and increase their effort over repeated trials in the absence of reward suggesting that need dominates negative experience. We further show that odor tracking is regulated by two mushroom body output neurons (MBONs) connecting the MB to the lateral horn. These MBONs, together with dopaminergic neurons and Dop1R2 signaling, control behavioral persistence. Conversely, an octopaminergic neuron, VPM4, which directly innervates one of the MBONs, acts as a brake on odor tracking by connecting feeding and olfaction. Together, our data suggest a function for the MB in internal state-dependent expression of behavior that can be suppressed by external inputs conveying a competing behavioral drive

Lab-on-a-chip platforms based on highly sensitive nanophotonic Si biosensors for single nucleotide DNA testing

In order to solve the drawbacks of sensitivity and portability in optical biosensors we have developed ultrasensitive and miniaturized photonic silicon sensors able to be integrated in a "lab-on-a-chip" microsystem platform. The sensors are integrated Mach-Zehnder interferometers based on TIR optical waveguides (Si/SiO2/Si3N4) of micro/nanodimensions. We have applied this biosensor for DNA testing and for detection of single nucleotide polymorphisms at BRCA-1 gene, involved in breast cancer development, without target labeling. The oligonucleotide probe is immobilized by covalent attachment to the sensor surface through silanization procedures. The hybridization was performed for different DNA target concentrations showing a lowest detection limit at 10 pM. Additionally, we have detected the hybridization of different concentrations of DNA target with two mismatching bases corresponding to a mutation of the BRCA-1 gene. Following the way of the lab-on-a-chip microsystem, integration with the microfluidics has been achieved by using a novel fabrication method of 3-D embedded microchannels using the polymer SU-8 as structural material. The optofluidic chip shows good performances for biosensing

Accuracy of a method based on atomic absorption spectrometry to determine inorganic arsenic in food : Outcome of the collaborative trial IMEP-41

Peer reviewedPublisher PD