Treatment of bimodality in proficiency test of pH in bioethanol matrix

The pH value in bioethanol is a quality control parameter related to its acidity and to the corrosiveness of vehicle engines when it is used as fuel. In order to verify the comparability and reliability of the measurement of pH in bioethanol matrix among some experienced chemical laboratories, reference material (RM) of bioethanol developed by Inmetro - the Brazilian National Metrology Institute - was used in a proficiency testing (PT) scheme. There was a difference of more than one unit in the value of the pH measured due to the type of internal filling electrolytic solutions (potassium chloride, KCl or lithium chloride, LiCl) from the commercial pH combination electrodes used by the participant laboratories. Therefore, bimodal distribution has occurred from the data of this PT scheme. This work aims to present the possibilities that a PT scheme provider can use to overcome the bimodality problem. Data from the PT of pH in bioethanol were treated by two different statistical approaches: kernel density model and the mixture of distributions. Application of these statistical treatments improved the initial diagnoses of PT provider, by solving bimodality problem and contributing for a better performance evaluation in measuring pH of bioethanol.Comment: 20 pages, 6 figures, Accepted for publication in Accreditation and Quality Assurance (ACQUAL

Phenomenology Tools on Cloud Infrastructures using OpenStack

We present a new environment for computations in particle physics phenomenology employing recent developments in cloud computing. On this environment users can create and manage "virtual" machines on which the phenomenology codes/tools can be deployed easily in an automated way. We analyze the performance of this environment based on "virtual" machines versus the utilization of "real" physical hardware. In this way we provide a qualitative result for the influence of the host operating system on the performance of a representative set of applications for phenomenology calculations.Comment: 25 pages, 12 figures; information on memory usage included, as well as minor modifications. Version to appear in EPJ

Generation of higher derivatives operators and electromagnetic wave propagation in a Lorentz-violation scenario

We study the perturbative generation of higher-derivative operators as corrections to the photon effective action, which are originated from a Lorentz violation background. Such corrections are obtained, at one-loop order, through the proper-time method, using the zeta function regularization. We focus over the lowest order corrections and investigate their influence in the propagation of electromagnetic waves through the vacuum, in the presence of a strong, constant magnetic field. This is a setting of experimental relevance, since it bases active efforts to measure non linear electromagnetic effects. After surprising cancellations of Lorentz violating corrections to the Maxwell's equation, we show that no effects of the kind of Lorentz violation we consider can be detected in such a context.Comment: v2: 13 pages, no figures, section IV considerably rewritten, main results unchanged and are now obtained in a simpler way. To appear in PL

Weak insensitivity to initial conditions at the edge of chaos in the logistic map

We extend existing studies of weakly sensitive points within the framework of Tsallis non-extensive thermodynamics to include weakly insensitive points at the edge of chaos. Analyzing tangent points of the logistic map we have verified that the generalized entropy with suitable entropic index q correctly describes the approach to the attractor.Comment: 6 pages, 3 figure

Experimental Observation of Quantum Correlations in Modular Variables

We experimentally detect entanglement in modular position and momentum variables of photon pairs which have passed through $D$-slit apertures. We first employ an entanglement criteria recently proposed in [Phys. Rev. Lett. {\bf 106}, 210501 (2011)], using variances of the modular variables. We then propose an entanglement witness for modular variables based on the Shannon entropy, and test it experimentally. Finally, we derive criteria for Einstein-Podolsky-Rosen-Steering correlations using variances and entropy functions. In both cases, the entropic criteria are more successful at identifying quantum correlations in our data.Comment: 7 pages, 4 figures, comments welcom

The determinants of risk reporting during the period of adoption of Basel II Accord: Evidence from the Portuguese commercial banks

The purpose of this paper to analyze the risk reporting practices and its determinants of commercial banks during the period of the adoption of the Basel II Accord in Portugal. The paper conducts a content analysis of the risk and risk management sections included in the management reports and the notes of the annual reports of Portuguese commercial banks, for the years 2007, 2010 and 2013. Findings show that theoretical frameworks underpinned in agency and legitimacy theories continue to provide valid explanations for risk reporting by Portuguese banks. More specifically, findings indicate that agency costs, public visibility and reputation are crucial drivers of risk reporting. Findings also indicate that younger banks with lower risk management skills use risk reporting either as an informational process or as a channel to manage organizational legitimacy. The content analysis does not allow readily for in-depth qualitative inquiry. The coding instrument is subject to coder bias. Information about risk can be provided in sources other than annual reports. Additionally, not all banks disclose information on corporate governance-related variables that could also influence risk reporting. The current research setting has never been studied hitherto. In this sense, this study seems to be of great relevance given the scarcity of literature on the subject in Portugal.info:eu-repo/semantics/publishedVersio

Cost-Effectiveness of the 13-Valent Pneumococcal Conjugate Vaccine in Children in Portugal

Pneumococcal infections are the leading cause of vaccine-preventable death in children. In June 2015, the 13-valent pneumococcal conjugate vaccine (PCV13) was introduced in the Portuguese Immunization Program. We evaluated the cost-effectiveness of children vaccinated with PCV13 versus no vaccination for preventing pneumococcal diseases.info:eu-repo/semantics/publishedVersio