The pH value in bioethanol is a quality control parameter related to its
acidity and to the corrosiveness of vehicle engines when it is used as fuel. In
order to verify the comparability and reliability of the measurement of pH in
bioethanol matrix among some experienced chemical laboratories, reference
material (RM) of bioethanol developed by Inmetro - the Brazilian National
Metrology Institute - was used in a proficiency testing (PT) scheme. There was
a difference of more than one unit in the value of the pH measured due to the
type of internal filling electrolytic solutions (potassium chloride, KCl or
lithium chloride, LiCl) from the commercial pH combination electrodes used by
the participant laboratories. Therefore, bimodal distribution has occurred from
the data of this PT scheme. This work aims to present the possibilities that a
PT scheme provider can use to overcome the bimodality problem. Data from the PT
of pH in bioethanol were treated by two different statistical approaches:
kernel density model and the mixture of distributions. Application of these
statistical treatments improved the initial diagnoses of PT provider, by
solving bimodality problem and contributing for a better performance evaluation
in measuring pH of bioethanol.Comment: 20 pages, 6 figures, Accepted for publication in Accreditation and
Quality Assurance (ACQUAL