Orientation and symmetry control of inverse sphere magnetic nanoarrays by guided self-assembly

Inverse sphere shaped Ni arrays were fabricated by electrodeposition on Si through the guided self-assembly of polystyrene latex spheres in Si/SiO2 patterns. It is shown that the size commensurability of the etched tracks is critical for the long range ordering of the spheres. Moreover, noncommensurate guiding results in the reproducible periodic triangular distortion of the close packed self-assembly. Magnetoresistance measurements on the Ni arrays were performed showing room temperature anisotropic magnetoresistance of 0.85%. These results are promising for self-assembled patterned storage media and magnetoresistance devices

Surface Enhanced Second Harmonic Generation from Macrocycle, Catenane, and Rotaxane Thin Films: Experiments and Theory

Surface enhanced second harmonic generation (SE SHG) experiments on molecular structures, macrocycles, catenanes, and rotaxanes, deposited as monolayers and multilayers by vacuum sublimation on silver, are reported. The measurements show that the molecules form ordered thin films, where the highest degree of order is observed in the case of macrocycle monolayers and the lowest in the case of rotaxane multilayers. The second harmonic generation activity is interpreted in terms of electric field induced second harmonic (EFISH) generation where the electric field is created by the substrate silver atoms. The measured second order nonlinear optical susceptibility for a rotaxane thin film is compared with that obtained by considering only EFISH contribution to SHG intensity. The electric field on the surface of a silver layer is calculated by using the Delphi4 program for structures obtained with TINKER molecular mechanics/dynamics simulations. An excellent agreement is observed between the calculated and the measured SHG susceptibilities.

First Dark Matter Limits from the COUPP 4kg Bubble Chamber at a Deep Underground Site

The COUPP 4 kg bubble chamber employs 4.0 kg of CF$_3$I as a WIMP scattering target for use as a dark matter direct detection search. This thesis reports the first experimental results from operating this bubble chamber at the deep underground site (6000 m.w.e.) of SNOLAB, near Sudbury, Ontario. Twenty dark matter candidate events were observed during an effective exposure of 553.0 kg-days, when operating the bubble chamber at three different bubble nucleation thresholds. These data are consistent with a neutron background internal to the detector. Characterization of this neutron background has led to the recommendation to replace two detector components to maximize dark matter signal sensitivity in a future run with this bubble chamber. A measurement of the gamma-ray flux has confirmed that this detector should not be sensitive to a gamma-induced background for more than three orders of magnitude below current sensitivity. The dark matter search data presented here set a new world-leading limit on the spin-dependent WIMP-proton scattering cross section and demonstrate significant sensitivity to spin-independent WIMP-nucleon scattering.Comment: University of Chicago PhD thesis. 224 pages, 18 tables, 71 figure

Improved Limits on Spin-Dependent WIMP-Proton Interactions from a Two Liter CF3_3I Bubble Chamber

Data from the operation of a bubble chamber filled with 3.5 kg of CF$_{3}$I in a shallow underground site are reported. An analysis of ultrasound signals accompanying bubble nucleations confirms that alpha decays generate a significantly louder acoustic emission than single nuclear recoils, leading to an efficient background discrimination. Three dark matter candidate events were observed during an effective exposure of 28.1 kg-day, consistent with a neutron background. This observation provides the strongest direct detection constraint to date on WIMP-proton spin-dependent scattering for WIMP masses $>20$ GeV/c$^{2}$.Comment: 4 pages, 4 figures V2 submitted to match journal versio