15 research outputs found
Effect of pore formers on properties of tape cast porous sheets for electrochemical flue gas purification
A novel rapid alloy development method towards powder bed additive manufacturing, demonstrated for binary Al-Ti, -Zr and -Nb alloys
Powder bed fusion (PBF) methods offer the best material properties among metal additive manufacturing (AM) processes. Yet, alloy development for PBF is only at its infancy and has a great untapped potential. This originates from the high solidification rate within the melt pool and to exploit the full potential of materials produced by PBF methods, a diligent work lies ahead. This paper presents a high-throughput method to rapidly screen large compositional alloy intervals experimentally for their PBF feasibility, which can drastically reduce the time needed for alloy development and provide valuable data for modelling. Our method consists of two steps; co-sputtering and electron beam re-melting. First step produces an alloy gradient film on a sheet substrate. The film is then re-molted to produce a PBF mimicked microstructure. The method is successfully demonstrated on binary systems; Al-Ti,-Zr and-Nb and produced gradients in compositional ranges of 3-50 wt%Ti, 1-15 wt%Zr and 2-15 wt%Nb over a length of 200 mm. From the produced materials, the alloying efficiency could be investigated and determined regarding hardness and grain refinement. Zr shows the highest strength contribution per at% and the best grain refinement at low levels. However, at higher levels grain refinement efficiency decreases for Zr. (c) 2021 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http:// creativecommons.org/licenses/by/4.0/).Funding Agencies|Norsk Hydro ASA; Carl Tryggers Foundation for Scientific Research [CTS 15:219, CTS 14:431]</p
High entropy alloy thin films on SS304 substrates: Evolution of microstructure and interface modulated by energetic condensation in nanoscale
High entropy alloys (HEAs), as a novel material in the 21st century, possess several advantages, such as excellent corrosion & oxidation resistance and high mechanical properties. HEA thin films show these favourable properties with lower material costs than their bulk counterparts. Studying the HEA film-substrate interface represents challenges but is of extreme importance for the understanding of growth mechanisms with important implications for film adhesion. However, most HEA films were deposited on monocrystalline silicon substrates with limited practical applicability. Further, where commercial stainless steel, aluminium or titanium alloy substrates were used, the microstructure and chemistry at the interface were neglected. Here, we deposited AlCrFeCoNiCu0.5 HEA thin films on stainless steel 304 (SS304) substrates using cathodic arc deposition with different substrate biases. The crystallography and microstructure were investigated using an X-ray and electron-microscopy based chatacterization. A transition of an incoherent to semi-coherent interface was observed from 0 V to -50 V of the substrate bias. Energy dispersive spectroscopy demonstrated a transition of Cr2O3 to aluminum oxide across the interface. The nanoindentation tests revealed the significant improvement of mechanical properties of SS304 with HEA coatings. High-strength HEA (8.0 ± 0.2 GPa) thin films with semi-coherent interfaces were manufactured on SS304
Periodic Open Cellular Raney‐Copper Catalysts Fabricated via Selective Electron Beam Melting
Herein, the possibility of generating Raney‐Copper catalysts with high geometric complexity is demonstrated. For this, periodic open cellular structures (POCS) composed of a highly brittle Al–Cu alloy containing 29.4 at% copper are fabricated by selective electron beam melting (SEBM) for application in chemical reaction engineering. After selective leaching of aluminum in an NaOH solution, the POCS show a core–shell structure with a nanoporous copper surface layer and a solid core. The fabrication and dealloying processes as well as the microstructure are studied. Moreover, the SEBM‐processed Raney‐type copper catalysts show a high catalytic activity in methanol synthesis
No Structure-Switching Required: A Generalizable Exonuclease-Mediated Aptamer-Based Assay for Small-Molecule Detection
The
binding of small molecules to double-stranded DNA can modulate
its susceptibility to digestion by exonucleases. Here, we show that
the digestion of aptamers by exonuclease III can likewise be inhibited
upon binding of small-molecule targets and exploit this finding for
the first time to achieve sensitive, label-free small-molecule detection.
This approach does not require any sequence engineering and employs
prefolded aptamers which have higher target-binding affinities than
structure-switching aptamers widely used in current small-molecule
detecting assays. We first use a dehydroisoandrosterone-3-sulfate-binding
aptamer to show that target binding halts exonuclease III digestion
four bases prior to the binding site. This leaves behind a double-stranded
product that retains strong target affinity, whereas digestion of
nontarget-bound aptamer produces a single-stranded product incapable
of target binding. Exonuclease I efficiently eliminates these single-stranded
products but is unable to digest the target-bound double-stranded
product. The remaining products can be fluorescently quantified with
SYBR Gold to determine target concentrations. We demonstrate that
this dual-exonuclease-mediated approach can be broadly applied to
other aptamers with differing secondary structures to achieve sensitive
detection of various targets, even in biological matrices. Importantly,
each aptamer digestion product has a unique sequence, enabling the
creation of multiplex assays, and we successfully demonstrate simultaneous
detection of cocaine and ATP in a single microliter volume sample
in 25 min via sequence-specific molecular beacons. Due to the generality
and simplicity of this assay, we believe that different DNA signal-reporting
or amplification strategies can be adopted into our assay for target
detection in diverse analytical contexts
Practically applicable water oxidation electrodes from 3D-printed Ti6Al4V scaffolds with surface nanostructuration and iridium catalyst coating
Bundesministerium für Bildung und Forschun