Extraordinary sensitivity of the electronic structure and properties of single-walled carbon nanotubes to molecular charge-transfer

Interaction of single-walled carbon nanotubes with electron donor and acceptor molecules causes significant changes in the electronic and Raman spectra, the relative proportion of the metallic species increasing on electron donation through molecular charge transfer, as also verified by electrical resistivity measurements.Comment: 15 pages, 5 figurre

Plasmas generated by ultra-violet light rather than electron impact

We analyze, in both plane and cylindrical geometries, a collisionless plasma consisting of an inner region where generation occurs by UV illumination, and an un-illuminated outer region with no generation. Ions generated in the inner region flow outwards through the outer region and into a wall. We solve for this system's steady state, first in the quasi-neutral regime (where the Debye length ${\lambda}_D$ vanishes and analytic solutions exist) and then in the general case, which we solve numerically. In the general case a double layer forms where the illuminated and un-illuminated regions meet, and an approximately quasi-neutral plasma connects the double layer to the wall sheath; in plane geometry the ions coast through the quasi-neutral section at slightly more than the Bohm speed $c_s$. The system, although simple, therefore has two novel features: a double layer that does not require counter-streaming ions and electrons, and a quasi-neutral plasma where ions travel in straight lines with at least the Bohm speed. We close with a pr\'{e}cis of our asymptotic solutions of this system, and suggest how our theoretical conclusions might be extended and tested in the laboratory.Comment: 10 pages, 3 figures, accepted by Physics of Plasma

Shortcuts to Spherically Symmetric Solutions: A Cautionary Note

Spherically symmetric solutions of generic gravitational models are optimally, and legitimately, obtained by expressing the action in terms of the two surviving metric components. This shortcut is not to be overdone, however: a one-function ansatz invalidates it, as illustrated by the incorrect solutions of [1].Comment: 2 pages. Amplified derivation, accepted for publication in Class Quant Gra

Photographic Assessment of Change in Trichotillomania: Psychometric Properties and Variables Influencing Interpretation

Although photographic assessment has been found to be reliable in assessing hair loss in Trichotillomania, the validity of this method is unclear, particularly for gauging progress in treatment. The current study evaluated the psychometric properties of photographic assessment of change in Trichotillomania. Photographs showing hair loss of adults with Trichotillomania were taken before and after participating in a clinical trial for the condition. Undergraduate college students (N = 211) rated treatment response according to the photos, and additional archival data on hair pulling severity and psychosocial health were retrieved from the clinical trial. Photographic assessment of change was found to possess fair reliability (ICC = 0.53), acceptable criterion validity (r = 0.51), good concurrent validity (r = 0.30–0.36), and excellent incremental validity (ΔR2 = 8.67, p \u3c 0.01). In addition, photographic measures were significantly correlated with change in quality of life (r = 0.42), and thus could be considered an index of the social validity of Trichotillomania treatment. Gender of the photo rater and pulling topography affected the criterion validity of photographic assessment (partial η2 = 0.05–0.11). Recommendations for improving photographic assessment and future directions for hair pulling research are discussed

A paediatric telecardiology service for district hospitals in south-east England: an observational study.

The attached article is a Publisher version of the final published version which may be accessed at the link below. Copyright © 2010 BMJ Publishing Group Ltd & Royal College of Paediatrics and Child Health. All rights reservedOBJECTIVES: To compare caseloads of new patients assessed by paediatric cardiologists face-to-face or during teleconferences, and assess NHS costs for the alternative referral arrangements. DESIGN: Prospective cohort study over 15 months. SETTING: Four district hospitals in south-east England and a London paediatric cardiology centre. PATIENTS: Babies and children. INTERVENTION: A telecardiology service introduced alongside outreach clinics. MEASUREMENTS: Clinical outcomes and mean NHS costs per patient. RESULTS: 266 new patients were studied: 75 had teleconsultations (19 of 42 newborns and 56 of 224 infants and children). Teleconsultation patients generally were younger (49% being under 1 year compared with 32% seen personally (p = 0.025)) and their symptoms were not as severe. A cardiac intervention was undertaken immediately or planned for five telemedicine patients (7%) and 30 conventional patients (16%). However, similar proportions of patients were discharged after being assessed (32% telemedicine and 39% conventional). During scheduled teleconferences the mean duration of time per patient in sessions involving real-time echocardiography was 14.4 min, and 8.5 min in sessions where pre-recorded videos were transmitted. Mean cost comparisons for telemedicine and face-to-face patients over 14-day and 6-month follow-up showed the telecardiology service to be cost-neutral for the three hospitals with infrequently-held outreach clinics (1519 UK pounds vs 1724 UK pounds respectively after 14 days). CONCLUSION: Paediatric cardiology centres with small cadres of specialists are under pressure to cope with ever-expanding caseloads of new patients with suspected anomalies. Innovative use of telecardiology alongside conventional outreach services should suitably, and economically, enhance access to these specialists.The Department of Health and the Charitable Funds Committee of the Royal Brompton and Harefield NHS Trust funded the project

The role of the sea-surface temperature distribution on numerically simulated cyclogenesis during ERICA

The goal was to quantify the extent to which a sea surface temperature (SST) front can influence cyclogenesis. The approach was to use the Drexel Limited-Area Mesoscale Prediction System (LAMPS) dynamical model to simulate cyclogenesis over various SST fields. Research during the past year focused on the development and testing of a four dimensional data assimilation (FDDA) technique within LAMPS. The technique is a continuous dynamical assimilation where forcing terms are added to the governing model equations to gradually nudge the model solution toward a gridded analysis. Here, the nudging is used as a dynamic initialization tool during a 12 hour preforecast to generate model balanced initial conditions for a subsequent 24 hour numerical prediction. Tests were performed to determine which variables to nudge and how to specify the four dimensional weighting function used to scale the nudging terms. To date, optimal results were obtained by nudging the u and v components of the wind along with the potential temperature. The weighting function ranged from 0 to 1 and varies in time as a quadratic polynomial. It was initialized at 0, reached its maximum at 9 hours into the preforecast, and fell back at 0 to 12 hours. The nudging terms are included in the model equations for all grid points except those within the model predicted oceanic boundary layer. This design attempts to confine changes imposed by the specified SST field to the oceanic boundary layer during the preforecast period

The Cape San Blas Ecological Study

Eglin AFB on Cape San Blas consists of approximately 250 acres located about 180 miles east of the main Eglin reservation. This area lies on the S1. Joseph peninsula, part of a dynamic barrier island chain that extends across the northern Gulf of Mexico. Due to the natural forces that formed Cape San Blas and those that maintain this area, St. Joseph Peninsula has experienced severe land form change over time (see GIS land form change maps). These changes allow for fluctuations in habitat types along Cape San Blas (see GIS land cover change maps)that influence the floral and faunal species using this area. The dynamic environment along Cape San Blasincludes flatwoods, interdunal swale, rosemary scrub, and beachfront. These habitats support a wide array of species, including several threatened and endangered species such as the loggerhead sea turtle (Caretta caretta), PipingPlover (Charadnus melodus), Least Tern (Sterna antillarum), and Bald Eagle (Haliaeetus leucocephalus). Proper management of these species and their habitats require knowledge of their abundance and distribution, and the effects disturbances have on their survival. In addition to threatened and endangered flora and fauna, Cape San Blas also supports tourists and recreationists. Although Gulf County is sparsely populated, with approximately 13,000 inhabitants throughout 578 square miles, summer tourism and heavy recreational use of beaches for fishing, crabbing, and shelling place continued and increasing pressure on the natural resources of these areas (Rupert 1991). Gulf County is also one of the few remaining counties in Florida that permits vehicular traffic on its beaches, including Cape San Blas. In addition to recreational use of these habitats;EAFB also uses the area for military missions. Air Force property on Cape San Blas is primarily used for radar tracking of flying missions over the Gulf of Mexico, although in recent years it has been used for missile launchings and other various military activities. To allow continued military and public use of Air Force property while also protecting the unique flora and fauna of the area,EAFB proposed a characterization of the resources found along Cape San Blas. A complete inventory of the physical features of the area included investigating topography, soil chemistry, hydrology, archeology, and the dynamics of land mass and land cover change over time. Various thematic layers within a geographic information system (GIS) were used to spatially portray georeferenced data. Large scale changes over time were assessed using stereo aerial photography. Vegetation transects, soil samples, elevation transects, an archeological survey, freshwater wells, and a tidal monitor were used to investigate the remaining features. (247 page document

A selected history of expectation bias in physics

The beliefs of physicists can bias their results towards their expectations in a number of ways. We survey a variety of historical cases of expectation bias in observations, experiments, and calculations.Comment: 6 pages, 2 figure