14 research outputs found
Pesticide Removal from Aqueous Solutions by Adding Salting Out Agents
Phase segregation in aqueous biphasic systems (ABS) composed of four hydrophilic ionic liquids (ILs): 1-butyl-3-methylimidazolium methylsulfate and 1-ethyl-3-methylimidazolium methylsulfate (CnC1im C1SO4, n = 2 and 4), tributylmethyl phosphonium methylsulfate (P4441 C1SO4) and methylpyridinium methylsulfate (C1Py C1SO4) and two high charge density potassium inorganic salts (K2CO3 and K2HPO4) were determined by the cloud point method at 298.15 K. The influence of the addition of the selected inorganic salts to aqueous mixtures of ILs was discussed in the light of the Hofmeister series and in terms of molar Gibbs free energy of hydration. The effect of the alkyl chain length of the cation on the methylsulfate-based ILs has been investigated. All the solubility data were satisfactorily correlated to several empirical equations. A pesticide (pentachlorophenol, PCP) extraction process based on the inorganic salt providing a greater salting out effect was tackled. The viability of the proposed process was analyzed in terms of partition coefficients and extraction efficiencies
Environmentally Benign Sequential Extraction of Heavy Metals from Marine Sediments
An
environmentally friendly heavy metals remediation process from
polluted marine sediments is proposed. The efficiency of three organic
and inorganic salts (ammonium acetate, ammonium nitrate, and sodium
potassium tartrate) to salt out these pollutants was ascertained in
sediment washing waters containing nonionic surfactants. The immiscibility
regions were correlated by means of three known models, and the experimental
data were interpreted in the light of thermodynamic parameters such
as Gibbs free energy of hydration and molar entropy of hydration.
The proposed process was applied to model aqueous solutions containing
two representative heavy metals (zinc and copper). The viability of
the suggested strategy was checked in real contaminated marine sediments
by including a sequential treatment: marine sediment washing–contaminant
extraction, which led to total remediation values higher than 80%
for copper and 90% for zinc
Salting out potential of cholinium dihydrogen citrate in aqueous solution of Triton surfactants
Biocompatible amino acid-based ionic liquids for extracting hormones and antibiotics from swine effluents
Testing True Choline Ionic Liquid Biocompatibility from a Biotechnological Standpoint
This
work is a first approach to demonstrate the viability of a
quantitative biotechnological removal of choline chloride from aqueous
effluents. Despite the much vaunted biocompatibility of this ammonium-based
ionic liquid, it was demonstrated (both by an ad-hoc F test recommended
by the Organization for Economic Co-operation and Development and
flask assays) that different microorganisms able to degrade persistent
chemicals were not able to metabolize it. Only a halophilic bacterium,
recently isolated in our research group (Halomonas sp.), exhibits the enzymatic mechanism to catalyze the cleavage
of the ionic liquid cation. The biotechnological process was optimized
by carefully cherry-picking the carbon source and proposing an adaptation
strategy. In this way, a complete choline removal was attained in
less than 24 h when the surfactant Tween 80 was added to the ionic
liquid-containing aqueous effluent