1,053 research outputs found
Exploring the spatial, temporal, and vertical distribution of methane in Pluto's atmosphere
High-resolution spectra of Pluto in the 1.66 um region, recorded with the
VLT/CRIRES instrument in 2008 (2 spectra) and 2012 (5 spectra), are analyzed to
constrain the spatial and vertical distribution of methane in Pluto's
atmosphere and to search for mid-term (4 year) variability. A sensitivity study
to model assumptions (temperature structure, surface pressure, Pluto's radius)
is performed. Results indicate that (i) no variation of the CH4 atmospheric
content (column-density or mixing ratio) with Pluto rotational phase is present
in excess of 20 % (ii) CH4 column densities show at most marginal variations
between 2008 and 2012, with a best guess estimate of a ~20 % decrease over this
time frame. As stellar occultations indicate that Pluto's surface pressure has
continued to increase over this period, this implies a concomitant decrease of
the methane mixing ratio (iii) the data do not show evidence for an
altitude-varying methane distribution; in particular, they imply a roughly
uniform mixing ratio in at least the first 22-27 km of the atmosphere, and high
concentrations of low-temperature methane near the surface can be ruled out.
Our results are also best consistent with a relatively large (> 1180 km) Pluto
radius. Comparison with predictions from a recently developed global climate
model GCM indicates that these features are best explained if the source of
methane occurs in regional-scale CH4 ice deposits, including both low latitudes
and high Northern latitudes, evidence for which is present from the rotational
and secular evolution of the near-IR features due to CH4 ice. Our "best guess"
predictions for the New Horizons encounter in 2015 are: a 1184 km radius, a 17
ubar surface pressure, and a 0.44 % CH4 mixing ratio with negligible
longitudinal variations.Comment: 21 pages, 6 figure
Gain properties of dye-doped polymer thin films
Hybrid pumping appears as a promising compromise in order to reach the much
coveted goal of an electrically pumped organic laser. In such configuration the
organic material is optically pumped by an electrically pumped inorganic device
on chip. This engineering solution requires therefore an optimization of the
organic gain medium under optical pumping. Here, we report a detailed study of
the gain features of dye-doped polymer thin films. In particular we introduce
the gain efficiency , in order to facilitate comparison between different
materials and experimental conditions. The gain efficiency was measured with
various setups (pump-probe amplification, variable stripe length method, laser
thresholds) in order to study several factors which modify the actual gain of a
layer, namely the confinement factor, the pump polarization, the molecular
anisotropy, and the re-absorption. For instance, for a 600 nm thick 5 wt\% DCM
doped PMMA layer, the different experimental approaches give a consistent value
80 cm.MW. On the contrary, the usual model predicting the gain
from the characteristics of the material leads to an overestimation by two
orders of magnitude, which raises a serious problem in the design of actual
devices. In this context, we demonstrate the feasibility to infer the gain
efficiency from the laser threshold of well-calibrated devices. Besides,
temporal measurements at the picosecond scale were carried out to support the
analysis.Comment: 15 pages, 17 figure
Use of the neutrophil-to-lymphocyte ratio as a component of a score to predict postoperative mortality after surgery for hip fracture in elderly subjects
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Data assimilation insights on selecting the most valuable atmospheric measurements
We discuss how objective guidance on selecting the most valuable atmospheric measurements on future Mars spacecraft missions can be provided through already developed Martian atmospheric data assimilation systems, and in particular through Observing System Simulation Experiments (OSSEs) which are widely used to design instruments for the Earthâs atmosphere
Controls on the CO2 seasonal cycle
Surface pressure measurement performed by the Viking landers show substantial variations in pressure on seasonal timescales that are characterized by two local minima and two local maxima. These variations have widely been attributed to the seasonal condensation and sublimation of CO2 in the two polar regions. It has been somewhat of a surprise that the amplitude of the minimum and maximum that is dominated by the CO2 cycle in the north was much weaker than the corresponding amplitude of the south-dominated extrema. Another surprise was that the seasonal pressure cycle during years 2 and 3 of the Viking mission was so similar to that for year 1, despite the occurrence of two global dust storms during year 1 and none during years 2 and 3. An energy balance model that incorporates dynamical factors from general circulation model (GCM) runs in which the atmospheric dust opacity and seasonal date were systematically varied was used to model the observed seasonal pressure variations. The energy balance takes account of the following processes in determining the rates of CO2 condensation and sublimation at each longitudinal and latitudinal grid point: solar radiation, infrared radiation from the atmosphere and surface, subsurface heat conduction, and atmospheric heat advection. Condensation rates are calculated both at the surface and in the atmosphere. In addition, the energy balance model also incorporates information from the GCM runs on seasonal redistribution of surface pressure across the globe. Estimates of surface temperature of the seasonal CO2 caps were used to define the infrared radiative losses from the seasonal polar caps. The seasonal pressure variations measured at the Viking lander sites were closely reproduced
Variational assimilation of Lagrangian data in oceanography
We consider the assimilation of Lagrangian data into a primitive equations
circulation model of the ocean at basin scale. The Lagrangian data are
positions of floats drifting at fixed depth. We aim at reconstructing the
four-dimensional space-time circulation of the ocean. This problem is solved
using the four-dimensional variational technique and the adjoint method. In
this problem the control vector is chosen as being the initial state of the
dynamical system. The observed variables, namely the positions of the floats,
are expressed as a function of the control vector via a nonlinear observation
operator. This method has been implemented and has the ability to reconstruct
the main patterns of the oceanic circulation. Moreover it is very robust with
respect to increase of time-sampling period of observations. We have run many
twin experiments in order to analyze the sensitivity of our method to the
number of floats, the time-sampling period and the vertical drift level. We
compare also the performances of the Lagrangian method to that of the classical
Eulerian one. Finally we study the impact of errors on observations.Comment: 31 page
Doped and non-doped organic light-emitting diodes based on a yellow carbazole emitter into a blue-emitting matrix
A new carbazole derivative with a 3,3'-bicarbazyl core 6,6'-substituted by dicyanovinylene groups (6,6'-bis(1-(2,2'-dicyano)vinyl)-N,N'-dioctyl-3,3'-bicarbazyl; named (OcCz2CN)2, was synthesized by carbonyl-methylene Knovenagel condensation, characterized and used as a component of multilayer organic light-emitting diodes (OLEDs). Due to its -donor-acceptor type structure, (OcCz2CN)2 was found to emit a yellow light at max=590 nm (with the CIE coordinates x=0.51; y = 0.47) and was used either as a dopant or as an ultra-thin layer in a blue-emitting matrix of 4,4'-bis(2,2'-diphenylvinyl)-1,1'-biphenyl (DPVBi). DPVBi (OcCz2CN)2-doped structure exhibited, at doping ratio of 1.5 weight %, a yellowish-green light with the CIE coordinates (x = 0.31; y = 0.51), an electroluminescence efficiency EL=1.3 cd/A, an external quantum efficiency ext= 0.4 % and a luminance L= 127 cd/m2 (at 10 mA/cm2) whereas for non-doped devices utilizing the carbazolic fluorophore as a thin neat layer, a warm white with CIE coordinates (x = 0.40; y= 0.43), EL= 2.0 cd/A, ext= 0.7 %, L = 197 cd/m2 (at 10 mA/cm2) and a color rendering index (CRI) of 74, were obtained. Electroluminescence performances of both the doped and non-doped devices were compared with those obtained with 5,6,11,12-tetraphenylnaphtacene (rubrene) taken as a reference of highly efficient yellow emitter
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