First direct evidence of N-heterocyclic carbene in BMIm acetate ionic liquid. An electrochemical and chemical study on the role of temperature

Cyclic voltammetry provides the first direct evidence of N-­heterocyclic carbene (NHC) presence in neat 1-‐butyl-­3-­methylimidazolium acetate ionic liquid (BMImAcO) at 120°C. The NHC existence, proved by its oxidation current in cyclic voltammetry, was confirmed by the formation of a PhCHO-­NHC adduct in pure ionic liquid. The role of the temperature was considered

Comparative study of the two large flares from SGR1900+14 with the BeppoSAX Gamma-Ray Burst Monitor

We report on spectral and temporal results of the 40-700 keV observations, obtained with the Gamma-Ray Burst Monitor (GRBM) on board BeppoSAX, of the two large flares from the Soft Gamma-ray Repeater SGR1900+14 occurred on August 27, 1998 and April 18, 2001. From their intensity, fluence and duration, the first one was classified as "giant" and the second as "intermediate". The spectral results have been obtained with an improved response function of the GRBM. We find that the two events have similar spectral properties, but different temporal properties. The major difference concerns the time profiles of the light curves, whereas the lack of evidence in the 2001 flare for the erratic time variability found at high frequencies (10-1000 Hz) in the 1998 flare could be ascribed to lower counting statistics. We discuss these results in the light of the magnetar model proposed for SGR sources.Comment: 15 pages, 20 figures, accepted for publication in A&

The radiation environment in a Low Earth Orbit: the case of BeppoSAX

Low-inclination, low altitude Earth orbits (LEO) are of increasing importance for astrophysical satellites, due to their low background environment. Here, the South Atlantic Anomaly (SAA) is the region with the highest amount of radiation. We study the radiation environment in a LEO (500-600 km altitude, 4 degrees inclination) through the particle background measured by the Particle Monitor (PM) experiment onboard the BeppoSAX satellite, between 1996 and 2002. Using time series of particle count rates measured by PM we construct intensity maps and derive SAA passage times and fluences. The low-latitude SAA regions are found to have an intensity strongly decreasing with altitude and dependent on the magnetic rigidity. The SAA extent, westward drift and strength vs altitude is shown.Comment: 16 pages, 12 figures. Accepted for publication in Experimental Astronom

Role of Anion and Cation in the 1-Methyl-3-butyl Imidazolium Ionic Liquids BMImX: The Knoevenagel Condensation

1-Methyl-3-butylimidazolium ionic liquids BMImX (X anions: Ac−, HCO3−, Cl−, BF4−, PF6−, I−, CF3CO2−, (CF3SO2)2N−, CF3SO3−) were used as catalysts in the Knoevenagel condensation reaction. The catalytic activity was compared with that of the inorganic salts NaAc, NaHCO3, NaCl. Whereas it is quite important to select suitable cation and anion depending on the purpose, the basicity of the anion X−and the ability of the counter-ion BMIm+to avoid the ion pairing with anion X−was investigated. 1-Methyl-3-butyl imidazolium acetate [BMImAc] and 1-methyl-3-butyl imidazolium hydrogen carbonate [BMImHCO3] show the most significant catalytic power and their catalytic effect was studied on a wide range of aromatic, heteroaromatic or aliphatic aldehydes or ketones with active methylene compounds. The corresponding substituted alkenes were obtained in excellent yields (up to 98%) in the absence of any solvent at room temperature within short times. The interesting feature of this study includes explanation on role of the cation BMIm+as proton donor (versus anions Ac−or HCO3−), in ion pair formation (with anion X−) and activator of the aldehyde structure

The XMM-Newton view of GRS1915+105 during a "plateau"

Two XMM-Newton observations of the black-hole binary GRS1915+105 were triggered in 2004 (April 17 and 21), during a long "plateau" state of the source. We analyzed the data collected with EPIC-pn in Timing and Burst modes, respectively. No thermal disc emission is required by the data; the spectrum is well fitted by four components: a primary component (either a simple power law or thermal Comptonization) absorbed by cold matter with abundances different than those of standard ISM; reprocessing from an ionized disc; emission and absorption lines; and a soft X-ray excess around 1 keV. The latter is not confirmed by RGS (which were used in the second observation only); if real, the excess could be due to reflection from the optically thin, photoionized plasma of a disc wind, in which case it may provide a way to disentangle intrinsic from interstellar absorption. Indeed, the former is best traced by the higher abundances of heavier elements, while an independent estimate of the latter may be given by the value we get for the disc wind component only, which roughly coincides with what is found for lower-Z species.Comment: 5 pages, 3 figures, 1 table. Submitte

Five years of SGR 1900+14 observations with BeppoSAX

We present a systematic analysis of all the BeppoSAX data of the soft gamma-ray repeater SGR 1900+14: these observations allowed us to study the long term properties of the source quiescent emission. In the observation carried out before the 1998 giant flare the spectrum in the 0.8-10 keV energy range was harder and there was evidence for a 20-150 keV emission, possibly associated with SGR 1900+14. This possible hard tail, if compared with the recent INTEGRAL detection of SGR 1900+14, has a harder spectrum (power-law photon index ~1.6 versus ~3) and a 20-100 keV flux ~4 times larger. In the last BeppoSAX observation (April 2002), while the source was entering the long quiescent period that lasted until 2006, the 2-10 keV flux was ~25% below the historical level. We also studied in detail the spectral evolution during the 2001 flare afterglow. This was characterized by a softening that can be interpreted in terms of a cooling blackbody-like component.Comment: Accepted for publication on Astronomy and Astrophysics on August 31, 200

Baseline design of the filters for the LAD detector on board LOFT

The Large Observatory for X-ray Timing (LOFT) was one of the M3 missions selected for the phase A study in the ESA's Cosmic Vision program. LOFT is designed to perform high-time-resolution X-ray observations of black holes and neutron stars. The main instrument on the LOFT payload is the Large Area Detector (LAD), a collimated experiment with a nominal effective area of ~10 m 2 @ 8 keV, and a spectral resolution of ~240 eV in the energy band 2-30 keV. These performances are achieved covering a large collecting area with more than 2000 large-area Silicon Drift Detectors (SDDs) each one coupled to a collimator based on lead-glass micro-channel plates. In order to reduce the thermal load onto the detectors, which are open to Sky, and to protect them from out of band radiation, optical-thermal filter will be mounted in front of the SDDs. Different options have been considered for the LAD filters for best compromise between high quantum efficiency and high mechanical robustness. We present the baseline design of the optical-thermal filters, show the nominal performances, and present preliminary test results performed during the phase A study.Comment: Proc. SPIE 9144, Space Telescopes and Instrumentation 2014: Ultraviolet to Gamma Ray, 91446

The complex behaviour of the microquasar GRS 1915+105 in the rho class observed with BeppoSAX. I: Timing analysis

GRS 1915+105 was observed by BeppoSAX for about 10 days in October 2000. For about 80% of the time, the source was in the variability class $\rho$, characterised by a series of recurrent bursts. We describe the results of the timing analysis performed on the MECS (1.6--10 keV) and PDS (15--100 keV) data. The X-ray count rate from \grss showed an increasing trend with different characteristics in the various energy bands. Fourier and wavelet analyses detect a variation in the recurrence time of the bursts, from 45--50 s to about 75 s, which appear well correlated with the count rate. From the power distribution of peaks in Fourier periodograms and wavelet spectra, we distinguished between the {\it regular} and {\it irregular} variability modes of the $\rho$ class, which are related to variations in the count rate in the 3--10 keV range. We identified two components in the burst structure: the slow leading trail, and the pulse, superimposed on a rather stable level. We found that the change in the recurrence time of the regular mode is caused by the slow leading trails, while the duration of the pulse phase remains far more stable. The evolution in the mean count rates shows that the time behaviour of both the leading trail and the baseline level are very similar to those observed in the 1.6--3 and 15--100 keV ranges, while that of the pulse follows the peak number. These differences in the time behaviour and count rates at different energies indicate that the process responsible for the pulses must produce the strongest emission between 3 and 10 keV, while that associated with both the leading trail and the baseline dominates at lower and higher energiesComment: Astronomy and Astrophysics, in pres

A Robust Filter for the BeppoSAX Gamma Ray Burst Monitor Triggers

The BeppoSAX Gamma Ray Burst Monitor (GRBM) is triggered any time a statistically significant counting excess is simultaneously revealed by at least two of its four independent detectors. Several spurious effects, including highly ionizing particles crossing two detectors, are recorded as onboard triggers. In fact, a large number of false triggers is detected, in the order of 10/day. A software code, based on an heuristic algorithm, was written to discriminate between real and false triggers. We present the results of the analysis on an homogeneous sample of GRBM triggers, thus providing an estimate of the efficiency of the GRB detection system consisting of the GRBM and the software.Comment: Proc. 5th Huntsville GRB Symposiu