213 research outputs found

    Environmental impact of cadmium: a review by the Panel on Hazardous Trace Substances.

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    This report is the result of a review by a Panel on Hazardous Trace Substances, as part of a report to an ad hoc Committee on Environmental Health Research whose chairman was Dr. David Rall, Director of the National Institute of Environmental Health Sciences, NIH

    Multiple metrics of latitudinal patterns in insect pollination and herbivory for a tropical‐temperate congener pair

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    The biotic interactions hypothesis posits that biotic interactions are more important drivers of adaptation closer to the equator, evidenced by “stronger” contemporary interactions (e.g. greater interaction rates) and/or patterns of trait evolution consistent with a history of stronger interactions. Support for the hypothesis is mixed, but few studies span tropical and temperate regions while experimentally controlling for evolutionary history. Here, we integrate field observations and common garden experiments to quantify the relative importance of pollination and herbivory in a pair of tropical‐temperate congeneric perennial herbs. Phytolacca rivinoides and P. americana are pioneer species native to the Neotropics and the eastern USA, respectively. We compared plant‐pollinator and plant‐herbivore interactions between three tropical populations of P. rivinoides from Costa Rica and three temperate populations of P. americana from its northern range edge in Michigan and Ohio. For some metrics of interaction importance, we also included three subtropical populations of P. americana from its southern range edge in Florida. This approach confounds species and region but allows us, uniquely, to measure complementary proxies of interaction importance across a tropical‐temperate range in one system. To test the prediction that lower‐latitude plants are more reliant on insect pollinators, we quantified floral display and reward, insect visitation rates, and self‐pollination ability (autogamy). To test the prediction that lower‐latitude plants experience more herbivore pressure, we quantified herbivory rates, herbivore abundance, and leaf palatability. We found evidence supporting the biotic interactions hypothesis for most comparisons between P. rivinoides and north‐temperate P. americana (floral display, insect visitation, autogamy, herbivory, herbivore abundance, and young‐leaf palatability). Results for subtropical P. americana populations, however, were typically not intermediate between P. rivinoides and north‐temperate P. americana, as would be predicted by a linear latitudinal gradient in interaction importance. Subtropical young‐leaf palatability was intermediate, but subtropical mature leaves were the least palatable, and pollination‐related traits did not differ between temperate and subtropical regions. These nonlinear patterns of interaction importance suggest future work to relate interaction importance to climatic or biotic thresholds. In sum, we found that the biotic interactions hypothesis was more consistently supported at the larger spatial scale of our study

    Stratigraphy, Sequence, and Crater Populations of Lunar Impact Basins from Lunar Orbiter Laser Altimeter (LOLA) Data: Implications for the Late Heavy Bombardment

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    New measurements of the topography of the Moon from the Lunar Orbiter Laser Altimeter (LOLA)[1] provide an excellent base-map for analyzing the large crater population (D.20 km)of the lunar surface [2, 3]. We have recently used this data to calculate crater size-frequency distributions (CSFD) for 30 lunar impact basins, which have implications for their stratigraphy and sequence. These data provide an avenue for assessing the timing of the transitions between distinct crater populations characteristic of ancient and young lunar terrains, which has been linked to the late heavy bombardment (LHB). We also use LOLA data to re-examine relative stratigraphic relationships between key lunar basins

    The Age of Lunar South Circumpolar Craters Haworth, Shoemaker, Faustini, and Shackleton: Implications for Regional Geology, Surface Processes, and Volatile Sequestration

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    The interiors of the lunar south circumpolar craters Haworth, Shoemaker, Faustini, and Shackleton contain permanently shadowed regions (PSRs) and have been interpreted to contain sequestered volatiles including water ice. Altimetry data from the Lunar Orbiter Laser Altimeter (LOLA) onboard the Lunar Reconnaissance Orbiter provide a new means of examining the permanently shadowed interiors of these craters in unprecedented detail. In this study, we used extremely high-resolution gridded LOLA data of Haworth, Shoemaker, Faustini, and Shackleton to determine the size-frequency distributions and the spatial density of craters superposing their rims, inner slopes, and floors. Based on their population of superposed D greater than or equal to 2 km craters, Haworth, Shoemaker, and Faustini have pre-Nectarian formation ages. Shackleton is interpreted as having a Late Imbrian age on the basis of craters with diameter D greater than or equal to 0.5 km superposed on its rim. The local density of craters with sub-km diameters across our study area is strongly dependent on slope; because of its steep interior slopes, the lifetime of craters on the interior of Shackleton is limited. The slope-dependence of the small crater population implies that the population in this size range is controlled primarily by the rate at which craters are destroyed. This is consistent with the hypothesis that crater removal and resurfacing is a result of slopedependent processes such as diffusive mass wasting and seismic shaking, linked to micrometeorite and meteorite bombardment. Epithermal neutron flux data and UV albedo data show that these circumpolar PSRs, particularly Shoemaker, may have approximately 1-2% water ice by mass in their highly porous surface regolith, and that Shoemaker may have approximately 5% or more water ice by mass in the near subsurface. The ancient formation ages of Shoemaker, Faustini and Haworth, and the Late Imbrian (approximately 3.5 Ga) crater retention ages of their floors suggests that any water ice that might have been deposited in their permanently shadowed areas was insufficient to modify the superposed crater population since that time

    Cold and COVID: Recurrent Pernio during the COVID-19 Pandemic

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    Pernio is a commonly reported cutaneous manifestation of SARS-CoV-2 infection.(1) Our international registry of COVID-19 dermatologic manifestations has collected 1,176 total cases of COVID-19 skin manifestations, including 619 cases of pernio in suspected or confirmed COVID-19 patients.(1) Most patients with new-onset pernio were entered into the registry after the first pandemic wave (79% in March-May 2020). Starting in September 2020, the registry received reports of a subset of these patients who developed recurrent pernio in the following months

    Inductively coupled plasma mass spectrometric detection for multielement flow injection analysis and elemental speciation by reversed-phase liquid chromatography

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    The feasibility of using an inductively coupled plasma mass spectrometer as a muitieiement detector for flow injection analysis (FIA) and ion-pair reversed-phase liquid chromatography was investigated. Sample introduction was by uitrasonk nebulization with aerosol desolvation. Absolute detecton limits for FIA ranged from 0.01 to 0.1 ng for most elements using 10-pL injections. Over 30 elements were surveyed for their response to both anionic and cationic ion pairing reagents. The separation and selective detection of various As and Se species were demonstrated, yielding detection limits near 0.1 ng (as element) for ail six species present. Determination of 15 elements in a single injection with multiple ion monitoring produced shniiar detection limits. Isotope ratios were measured with sufficient precision (better than 2%) and accuracy (about 1 %) on eluting peaks of Cd and Pb to demonstrate that liquid chromatographyhductively coupled plasma mass spectrometry should make speciation studies with stable tracer isotopes feasible

    Subsurface morphology and scaling of lunar impact basins

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    Impact bombardment during the first billion years after the formation of the Moon produced at least several tens of basins. The Gravity Recovery and Interior Laboratory (GRAIL) mission mapped the gravity field of these impact structures at significantly higher spatial resolution than previous missions, allowing for detailed subsurface and morphological analyses to be made across the entire globe. GRAIL-derived crustal thickness maps were used to define the regions of crustal thinning observed in centers of lunar impact basins, which represents a less unambiguous measure of a basin size than those based on topographic features. The formation of lunar impact basins was modeled numerically by using the iSALE-2D hydrocode, with a large range of impact and target conditions typical for the first billion years of lunar evolution. In the investigated range of impactor and target conditions, the target temperature had the dominant effect on the basin subsurface morphology. Model results were also used to update current impact scaling relationships applicable to the lunar setting (based on assumed target temperature). Our new temperature-dependent impact-scaling relationships provide estimates of impact conditions and transient crater diameters for the majority of impact basins mapped by GRAIL. As the formation of lunar impact basins is associated with the first ~700 Myr of the solar system evolution when the impact flux was considerably larger than the present day, our revised impact scaling relationships can aid further analyses and understanding of the extent of impact bombardment on the Moon and terrestrial planets in the early solar system

    Pickup ion measurements by MAVEN: A diagnostic of photochemical oxygen escape from Mars

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    A key process populating the oxygen exosphere at Mars is the dissociative recombination of ionospheric O 2 + , which produces fast oxygen atoms, some of which have speeds exceeding the escape speed and thus contribute to atmospheric loss. Theoretical studies of this escape process have been carried out and predictions made of the loss rate; however, directly measuring the escaping neutral oxygen is difficult but essential. This paper describes how energetic pickup ion measurements to be made near Mars by the SEP (Solar Energetic Particle) instrument on board the MAVEN (Mars Atmosphere and Volatile EvolutioN) spacecraft can be used to constrain models of photochemical oxygen escape. In certain solar wind conditions, neutral oxygen atoms in the distant Martian exosphere that are ionized and picked up by the solar wind can reach energies high enough to be detected near Mars by SEP. Key Points Photochemical hot oxygen escape rate at Mars is predicted Martian exospheric neutral oxygen model is constructed Pickup ion fluxes measured by SEP will constrain neutral oxygen escape from MarsPeer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/108375/1/grl51888.pd
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