Origin of magnetic moments in defective TiO2 single crystals

In this paper we show that ferromagnetism can be induced in pure TiO2 single crystals by oxygen ion irradiation. By combining x-ray diffraction, Raman-scattering, and electron spin resonance spectroscopy, a defect complex, \emph{i.e.} Ti$^{3+}$ ions on the substitutional sites accompanied by oxygen vacancies, has been identified in irradiated TiO2. This kind of defect complex results in a local (TiO$_{6-x}$) stretching Raman mode. We elucidate that Ti$^{3+}$ ions with one unpaired 3d electron provide the local magnetic moments.Comment: 4 pages, 4 figures, to be published at Phys. Rev.

XMMU J100750.5+125818: A strong lensing cluster at z=1.082

We report on the discovery of the X-ray luminous cluster XMMU J100750.5+125818 at redshift 1.082 based on 19 spectroscopic members, which displays several strong lensing features. SED modeling of the lensed arc features from multicolor imaging with the VLT and the LBT reveals likely redshifts ~2.7 for the most prominent of the lensed background galaxies. Mass estimates are derived for different radii from the velocity dispersion of the cluster members, M_200 ~ 1.8 10^{14} Msun, from the X-ray spectral parameters, M_500 ~ 1.0 10^{14} Msun, and the largest lensing arc, M_SL ~ 2.3 10^{13} Msun. The projected spatial distribution of cluster galaxies appears to be elongated, and the brightest galaxy lies off center with respect to the X-ray emission indicating a not yet relaxed structure. XMMU J100750.5+125818 offers excellent diagnostics of the inner mass distribution of a distant cluster with a combination of strong and weak lensing, optical and X-ray spectroscopy.Comment: A&A, accepted for publicatio

Spinel ferrite nanocrystals embedded inside ZnO: magnetic, electronic and magneto-transport properties

In this paper we show that spinel ferrite nanocrystals (NiFe2O4, and CoFe2O4) can be texturally embedded inside a ZnO matrix by ion implantation and post-annealing. The two kinds of ferrites show different magnetic properties, e.g. coercivity and magnetization. Anomalous Hall effect and positive magnetoresistance have been observed. Our study suggests a ferrimagnet/semiconductor hybrid system for potential applications in magneto-electronics. This hybrid system can be tuned by selecting different transition metal ions (from Mn to Zn) to obtain various magnetic and electronic properties.Comment: 12 pages, 14 figs. accepted for publication at PR

Crystallographically oriented magnetic ZnFe2O4 nanoparticles synthesized by Fe implantation into ZnO

In this paper, a correlation between structural and magnetic properties of Fe implanted ZnO is presented. High fluence Fe^+ implantation into ZnO leads to the formation of superparamagnetic alpha-Fe nanoparticles. High vacuum annealing at 823 K results in the growth of alpha-Fe particles, but the annealing at 1073 K oxidized the majority of the Fe nanoparticles. After a long term annealing at 1073 K, crystallographically oriented ZnFe2O4 nanoparticles were formed inside ZnO with the orientation relationship of ZnFe2O4(111)[110]//ZnO(0001)[1120]. These ZnFe2O4 nanoparticles show a hysteretic behavior upon magnetization reversal at 5 K.Comment: 21 pages, 7 figures, accepted by J. Phys. D: Appl. Phy

Fe-implanted ZnO: Magnetic precipitates versus dilution

Nowadays ferromagnetism is often found in potential diluted magnetic semiconductor systems. However, many authors argue that the observed ferromagnetism stems from ferromagnetic precipitates or spinodal decomposition rather than from carrier mediated magnetic impurities, as required for a diluted magnetic semiconductor. In the present paper we answer this question for Fe-implanted ZnO single crystals comprehensively. Different implantation fluences and temperatures and post-implantation annealing temperatures have been chosen in order to evaluate the structural and magnetic properties over a wide range of parameters. Three different regimes with respect to the Fe concentration and the process temperature are found: 1) Disperse Fe$^{2+}$ and Fe$^{3+}$ at low Fe concentrations and low processing temperatures, 2) FeZn$_2$O$_4$ at very high processing temperatures and 3) an intermediate regime with a co-existence of metallic Fe (Fe$^0$) and ionic Fe (Fe$^{2+}$ and Fe$^{3+}$). Ferromagnetism is only observed in the latter two cases, where inverted ZnFe$_2$O$_4$ and $\alpha$-Fe nanocrystals are the origin of the observed ferromagnetic behavior, respectively. The ionic Fe in the last case could contribute to a carrier mediated coupling. However, their separation is too large to couple ferromagnetically due to the lack of p-type carrier. For comparison investigations of Fe-implanted epitaxial ZnO thin films are presented.Comment: 14 pages, 17 figure

Exploring the galaxy cluster-group transition regime at high redshifts: Physical properties of two newly detected z > 1 systems

Context: Multi-wavelength surveys for clusters of galaxies are opening a window on the elusive high-redshift (z>1) cluster population. Well controlled statistical samples of distant clusters will enable us to answer questions about their cosmological context, early assembly phases and the thermodynamical evolution of the intracluster medium. Aims: We report on the detection of two z>1 systems, XMMU J0302.2-0001 and XMMU J1532.2-0836, as part of the XMM-Newton Distant Cluster Project (XDCP) sample. We investigate the nature of the sources, measure their spectroscopic redshift and determine their basic physical parameters. Methods: The results of the present paper are based on the analysis of XMM-Newton archival data, optical/near-infrared imaging and deep optical follow-up spectroscopy of the clusters. Results: We confirm the X-ray source XMMU J0302.2-0001 as a gravitationally bound, bona fide cluster of galaxies at spectroscopic redshift z=1.185. We estimate its M500 mass to (1.6+/-0.3) times 10^{14} Msun from its measured X-ray luminosity. This ranks the cluster among intermediate mass system. In the case of XMMU J1532.2-0836 we find the X-ray detection to be coincident with a dynamically bound system of galaxies at z=1.358. Optical spectroscopy reveals the presence of a central active galactic nucleus, which can be a dominant source of the detected X-ray emission from this system. We provide upper limits of X-ray parameters for the system and discuss cluster identification challenges in the high-redshift low-mass cluster regime. A third, intermediate redshift (z=0.647) cluster, XMMU J0302.1-0000, is serendipitously detected in the same field as XMMU J0302.2-0001. We provide its analysis as well.Comment: Accepted to A&A, 13/04/2011. 15 pages, 18 figures, 5 tables, 2 appendice

Ion beam induced modification of exchange interaction and spin-orbit coupling in the Co2_2FeSi Heusler compound

A Co$_2$FeSi (CFS) film with L2$_1$ structure was irradiated with different fluences of 30 keV Ga$^+$ ions. Structural modifications were subsequently studied using the longitudinal (LMOKE) and quadratic (QMOKE) magneto-optical Kerr effect. Both the coercivity and the LMOKE amplitude were found to show a similar behavior upon irradiation: they are nearly constant up to ion fluences of $\approx6\times10^{15}$ ion/cm$^2$, while they decrease with further increasing fluences and finally vanish at a fluence of $\approx9\times10^{16}$ ion/cm$^2$, when the sample becomes paramagnetic. However, contrary to this behavior, the QMOKE signal nearly vanishes even for the smallest applied fluence of $3\times10^{14}$ ion/cm$^2$. We attribute this reduction of the QMOKE signal to an irradiation-induced degeneration of second or higher order spin-orbit coupling, which already happens at small fluences of 30 keV Ga$^+$ ions. On the other hand, the reduction of coercivity and LMOKE signal with high ion fluences is probably caused by a reduction of the exchange interaction within the film material

Discovery of an X-ray-Luminous Galaxy Cluster at z=1.4

We report the discovery of a massive, X-ray-luminous cluster of galaxies at z=1.393, the most distant X-ray-selected cluster found to date. XMMU J2235.3-2557 was serendipitously detected as an extended X-ray source in an archival XMM-Newton observation of NGC 7314. VLT-FORS2 R and z band snapshot imaging reveals an over-density of red galaxies in both angular and color spaces. The galaxy enhancement is coincident in the sky with the X-ray emission; the cluster red sequence at R-z ~ 2.1 identifies it as a high-redshift candidate. Subsequent VLT-FORS2 multi-object spectroscopy unambiguously confirms the presence of a massive cluster based on 12 concordant redshifts in the interval 1.38<z<1.40. The preliminary cluster velocity dispersion is 762+/-265 km/s. VLT-ISAAC Ks and J band images underscore the rich distribution of red galaxies associated with the cluster. Based on a 45 ks XMM-Newton observation, we find the cluster has an aperture-corrected, unabsorbed X-ray flux of f_X = (3.6 +/- 0.3) x 10^{-14} erg/cm^2/s, a rest-frame X-ray luminosity of L_X = (3.0 +/- 0.2) x 10^{44} h_70^{-2} erg/s (0.5--2.0 keV), and a temperature of kT=6.0 (+2.5, -1.8) keV. Though XMMU J2235.3-2557 is likely the first confirmed z>1 cluster found with XMM-Newton, the relative ease and efficiency of discovery demonstrates that it should be possible to build large samples of z>1 clusters through the joint use of X-ray and large, ground-based telescopes.Comment: 4 pages, 3 figures, accepted for publication in ApJ Letters, a high-resolution version is available at http://www.astro.lsa.umich.edu/~cmullis/papers/Mullis_et_al_2005a.pdf, additional information is available at http://www.astro.lsa.umich.edu/~cmullis/research/xmmuj223