67 research outputs found
Quantum Tunneling of Magnetization in Single Molecular Magnets Coupled to Ferromagnetic Reservoirs
The role of spin polarized reservoirs in quantum tunneling of magnetization
and relaxation processes in a single molecular magnet (SMM) is investigated
theoretically. The SMM is exchange-coupled to the reservoirs and also subjected
to a magnetic field varying in time, which enables the quantum tunneling of
magnetization (QTM). The spin relaxation times are calculated from the Fermi
golden rule. The exchange interaction with tunneling electrons is shown to
affect the spin reversal due to QTM. Furthermore, it is shown that the
switching is associated with transfer of a certain charge between the leads.Comment: 5 pages, 3 EPS figures, final version as publishe
Quantum Noise Interference and Back-action Cooling in Cavity Nanomechanics
We present a theoretical analysis of a novel cavity electromechanical system
where a mechanical resonator directly modulates the damping rate kappa of a
driven electromagnetic cavity. We show that via a destructive interference of
quantum noise, the driven cavity can effectively act like a zero-temperature
bath irrespective of the ratio kappa / omega_M, where omega_M is the mechanical
frequency. This scheme thus allows one to cool the mechanical resonator to its
ground state without requiring the cavity to be in the so-called `good cavity'
limit kappa << omega_M.Comment: 4+ pages, 2 figures. Error in second last paragraph correcte
Strong and Tunable Nonlinear Optomechanical Coupling in a Low-Loss System
A major goal in optomechanics is to observe and control quantum behavior in a
system consisting of a mechanical resonator coupled to an optical cavity. Work
towards this goal has focused on increasing the strength of the coupling
between the mechanical and optical degrees of freedom; however, the form of
this coupling is crucial in determining which phenomena can be observed in such
a system. Here we demonstrate that avoided crossings in the spectrum of an
optical cavity containing a flexible dielectric membrane allow us to realize
several different forms of the optomechanical coupling. These include cavity
detunings that are (to lowest order) linear, quadratic, or quartic in the
membrane's displacement, and a cavity finesse that is linear in (or independent
of) the membrane's displacement. All these couplings are realized in a single
device with extremely low optical loss and can be tuned over a wide range in
situ; in particular, we find that the quadratic coupling can be increased three
orders of magnitude beyond previous devices. As a result of these advances, the
device presented here should be capable of demonstrating the quantization of
the membrane's mechanical energy.Comment: 12 pages, 4 figures, 1 tabl
Signatures of Molecular Magnetism in Single-Molecule Transport Spectroscopy
Single-molecule transistors provide a unique experimental tool to investigate
the coupling between charge transport and the molecular degrees of freedom in
individual molecules. One interesting class of molecules for such experiments
are the single-molecule magnets, since the intramolecular exchange forces
present in these molecules should couple strongly to the spin of transport
electrons, thereby providing both new mechanisms for modulating electron flow
and also new means for probing nanoscale magnetic excitations. Here we report
single-molecule transistor measurements on devices incorporating Mn12
molecules. By studying the electron-tunneling spectrum as a function of
magnetic field, we are able to identify clear signatures of magnetic states and
their associated magnetic anisotropy. A comparison of the data to simulations
also suggests that electron flow can strongly enhance magnetic relaxation of
the magnetic molecule
Green function techniques in the treatment of quantum transport at the molecular scale
The theoretical investigation of charge (and spin) transport at nanometer
length scales requires the use of advanced and powerful techniques able to deal
with the dynamical properties of the relevant physical systems, to explicitly
include out-of-equilibrium situations typical for electrical/heat transport as
well as to take into account interaction effects in a systematic way.
Equilibrium Green function techniques and their extension to non-equilibrium
situations via the Keldysh formalism build one of the pillars of current
state-of-the-art approaches to quantum transport which have been implemented in
both model Hamiltonian formulations and first-principle methodologies. We offer
a tutorial overview of the applications of Green functions to deal with some
fundamental aspects of charge transport at the nanoscale, mainly focusing on
applications to model Hamiltonian formulations.Comment: Tutorial review, LaTeX, 129 pages, 41 figures, 300 references,
submitted to Springer series "Lecture Notes in Physics
Comparison of OH reactivity measurements in the atmospheric simulation chamber SAPHIR
Hydroxyl (OH) radical reactivity (kOH) has been measured for 18 years with different measurement techniques. In order to compare the performances of instruments deployed in the field, two campaigns were conducted performing experiments in the atmospheric simulation chamber SAPHIR at Forschungszentrum Jülich in October 2015 and April 2016. Chemical conditions were chosen either to be representative of the atmosphere or to test potential limitations of instruments. All types of instruments that are currently used for atmospheric measurements were used in one of the two campaigns. The results of these campaigns demonstrate that OH reactivity can be accurately measured for a wide range of atmospherically relevant chemical conditions (e.g. water vapour, nitrogen oxides, various organic compounds) by all instruments. The precision of the measurements (limit of detection < 1 s−1 at a time resolution of 30 s to a few minutes) is higher for instruments directly detecting hydroxyl radicals, whereas the indirect comparative reactivity method (CRM) has a higher limit of detection of 2 s−1 at a time resolution of 10 to 15 min. The performances of the instruments were systematically tested by stepwise increasing, for example, the concentrations of carbon monoxide (CO), water vapour or nitric oxide (NO). In further experiments, mixtures of organic reactants were injected into the chamber to simulate urban and forested environments. Overall, the results show that the instruments are capable of measuring OH reactivity in the presence of CO, alkanes, alkenes and aromatic compounds. The transmission efficiency in Teflon inlet lines could have introduced systematic errors in measurements for low-volatile organic compounds in some instruments. CRM instruments exhibited a larger scatter in the data compared to the other instruments. The largest differences to reference measurements or to calculated reactivity were observed by CRM instruments in the presence of terpenes and oxygenated organic compounds (mixing ratio of OH reactants were up to 10 ppbv). In some of these experiments, only a small fraction of the reactivity is detected. The accuracy of CRM measurements is most likely limited by the corrections that need to be applied to account for known effects of, for example, deviations from pseudo first-order conditions, nitrogen oxides or water vapour on the measurement. Methods used to derive these corrections vary among the different CRM instruments. Measurements taken with a flow-tube instrument combined with the direct detection of OH by chemical ionisation mass spectrometry (CIMS) show limitations in cases of high reactivity and high NO concentrations but were accurate for low reactivity (< 15 s−1) and low NO (< 5 ppbv) conditions
Tunneling Spectra of Individual Magnetic Endofullerene Molecules
The manipulation of single magnetic molecules may enable new strategies for
high-density information storage and quantum-state control. However, progress
in these areas depends on developing techniques for addressing individual
molecules and controlling their spin. Here we report success in making
electrical contact to individual magnetic N@C60 molecules and measuring spin
excitations in their electron tunneling spectra. We verify that the molecules
remain magnetic by observing a transition as a function of magnetic field which
changes the spin quantum number and also the existence of nonequilibrium
tunneling originating from low-energy excited states. From the tunneling
spectra, we identify the charge and spin states of the molecule. The measured
spectra can be reproduced theoretically by accounting for the exchange
interaction between the nitrogen spin and electron(s) on the C60 cage.Comment: 7 pages, 4 figures. Typeset in LaTeX, updated text of previous
versio
Nano-Opto-Electro-Mechanical Systems
A new class of hybrid systems that couple optical, electrical and mechanical
degrees of freedom in nanoscale devices is under development in laboratories
worldwide. These nano-opto-electro-mechanical systems (NOEMS) offer
unprecedented opportunities to dynamically control the flow of light in
nanophotonic structures, at high speed and low power consumption. Drawing on
conceptual and technological advances from cavity optomechanics, they also bear
the potential for highly efficient, low-noise transducers between microwave and
optical signals, both in the classical and quantum domains. This Progress
Article discusses the fundamental physical limits of NOEMS, reviews the recent
progress in their implementation, and suggests potential avenues for further
developments in this field.Comment: 27 pages, 3 figures, 2 boxe
OH in the coastal boundary layer of Crete during MINOS : measurements and relationship with ozone photolysis
Hydroxyl radical (OH) concentrations were measured in August 2001 at Finokalia Station on the northeastern coast of Crete during the Mediterranean Intensive Oxidant Study (MINOS). OH was measured based on selected ion chemical ionization mass spectrometry (SI/CIMS) with a time resolution of 30 sec and signal integration of 5 min. The corresponding accuracy, precision, and detection limit were 20% (1sigma), 11% (1sigma), and 2.4 x 10(5) molecules cm(-3) (2sigma), respectively. OH levels showed a strong diurnal variability with high maxima (approximately 2 x 10(7) molecules cm(-3)) occurring around 13:30 LT (10:30 UTC) and nighttime values below the detection limit. Daily 24-hour average concentrations varied between 3.6-6.7 x 10(6) cm(-3). For the total measurement period (6-21 August) the mean and standard deviation were 4.5 +/- 1.1 x 10(6) cm(-3). The OH data set is analyzed based on a classification into three periods: I: Aug 6-8, II: Aug 9-11, III: Aug 13-18. For each of the three periods the measured OH concentrations are described by the empirical function [OH] = a J((OD)-D-1)(b), with J((OD)-D-1) being the ozone photolysis frequency and a = 1.4 x 10(10) s cm(-3), 1.7 x 10(10) s cm(-3), 2.2 x 10(10) s cm(-3), and b = 0.68, respectively. Taking into account the estimated precision of the OH measurements this empirical function using three values for a and one value for b explains 99% of the observed variance of OH. A detailed sensitivity analysis using a CH4-CO box model was performed to interpret this relationship, in particular the meanings of the pre-exponential factor a and the exponent b. It was found that the value of b which represents the total logarithmic dependence of [OH] on J((OD)-D-1) includes the individual contributions from the photolysis of O-3, NO2, HCHO, HONO, and H2O2 which could be determined using the box model. For the conditions prevailing during the MINOS campaign the exponent b was found to be dominated by the contributions from O-3- and NO2-photolysis. For the in-dividual functional dependences between [OH] and J((OD)-D-1), [OH] and J(NO2), and J(NO2) and J((OD)-D-1) the partial logarithmic derivatives were determined to be 0.5, 0.6, and 0.3, respectively. Overall, the box model yields a value of 0.70 for the exponent b in very good agreement with the corresponding value derived from the empirical analysis of the measurements. This empirical approach in which the chemical air mass characteristics influencing the OH radical balance and thereby, the self-cleansing efficiency of the atmosphere, are represented by only two parameters which are constant over quite substantial time periods may be used in future experiments to test and compare OH measurements made in different atmospheric environments
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