Structural and vibrational properties of two-dimensional MnxOy\rm Mn_xO_y nanolayers on Pd(100)

Using different experimental techniques combined with density functional based theoretical methods we have explored the formation of interface-stabilized manganese oxide structures grown on Pd(100) at (sub)monolayer coverage. Amongst the multitude of phases experimentally observed we focus our attention on four structures which can be classified into two distinct regimes, characterized by different building blocks. Two oxygen-rich phases are described in terms of MnO(111)-like O-Mn-O trilayers, whereas the other two have a lower oxygen content and are based on a MnO(100)-like monolayer structure. The excellent agreement between calculated and experimental scanning tunneling microscopy images and vibrational electron energy loss spectra allows for a detailed atomic description of the explored models.Comment: 14 pages, 11 figure

Quasar Parallax: a Method for Determining Direct Geometrical Distances to Quasars

We describe a novel method to determine direct geometrical distances to quasars that can measure the cosmological constant, Lambda, with minimal assumptions. This method is equivalent to geometric parallax, with the `standard length' being the size of the quasar broad emission line region (BELR) as determined from the light travel time measurements of reverberation mapping. The effect of non-zero Lambda on angular diameter is large, 40% at z=2, so mapping angular diameter distances vs. redshift will give Lambda with (relative) ease. In principle these measurements could be made in the UV, optical, near infrared or even X-ray bands. Interferometers with a resolution of 0.01mas are needed to measure the size of the BELR in z=2 quasars, which appear plausible given reasonable short term extrapolations of current technology.Comment: 13 pages, with 3 figures. ApJ Letters, in press (Dec 20, 2002

Mid-Infrared line diagnostics of Active Galaxies -- A spectroscopic AGN survey with ISO-SWS

We present medium resolution (R approx. 1500) ISO-SWS 2.4--45 micron spectra of a sample of 29 galaxies with active nuclei. This data set is rich in fine structure emission lines tracing the narrow line regions and (circum-)nuclear star formation regions, and it provides a coherent spectroscopic reference for future extragalactic studies in the mid-infrared. We use the data set to briefly discuss the physical conditions in the narrow line regions (density, temperature, excitation, line profiles) and to test for possible differences between AGN sub-types. Our main focus is on new tools for determining the propertibes of dusty galaxies and on the AGN-starburst connection. We present mid-IR line ratio diagrams which can be used to identify composite (starburst + AGN) sources and to distinguish between emission excited by active nuclei and emission from (circum-nuclear) star forming regions. For instance, line ratios of high to low excitation lines like [O IV]25.9um/[Ne II]12.8um, that have been used to probe for AGNs in dusty objects, can be examined in more detail and with better statistics now. In addition, we present two-dimensional diagnostic diagrams that are fully analogous to classical optical diagnostic diagrams, but better suited for objects with high extinction. Finally, we discuss correlations of mid-infrared line fluxes to the mid- and far-infrared continuum. We compare these relations to similar relations in starburst galaxies in order to examine the contribution of AGNs to the bolometric luminosities of their host galaxies. The spectra are available in electronic form from the authors.Comment: 24 pages, 23 figures, 5 tables. Accepted for A&

A view of the narrow-line region in the infrared: active galactic nuclei with resolved fine-structure lines in the Spitzer archive

We queried the Spitzer archive for high-resolution observations with the Infrared Spectrograph of optically selected active galactic nuclei (AGN) for the purpose of identifying sources with resolved fine-structure lines that would enable studies of the narrow-line region (NLR) at mid-infrared wavelengths. By combining 298 Spitzer spectra with 6 Infrared Space Observatory spectra, we present kinematic information of the NLR for 81 z<=0.3 AGN. We used the [NeV], [OIV], [NeIII], and [SIV] lines, whose fluxes correlate well with each other, to probe gas photoionized by the AGN. We found that the widths of the lines are, on average, increasing with the ionization potential of the species that emit them. No correlation of the line width with the critical density of the corresponding transition was found. The velocity dispersion of the gas, sigma, is systematically higher than that of the stars, sigma_*, in the AGN host galaxy, and it scales with the mass of the central black hole, M_BH. Further correlations between the line widths and luminosities L, and between L and M_BH, are suggestive of a three dimensional plane connecting log(M_BH) to a linear combination of log(sigma) and log(L). Such a plane can be understood within the context of gas motions that are driven by AGN feedback mechanisms, or virialized gas motions with a power-law dependence of the NLR radius on the AGN luminosity. The M_BH estimates obtained for 35 type 2 AGN from this plane are consistent with those obtained from the M_BH-sigma_* relation.Comment: ApJ, revised to match the print versio

Reversible Eu²⁺ ↔ Eu³⁺ transitions at Eu‐Si interfaces

Valence switching at Eu‐Si interfaces is demonstrated by resonant photoemission during repeated oxidation‐reduction cycles performed by room‐temperature O2 exposure and mild heating. The Eu2+ ↔ Eu3+ transitions are accompanied by Fermi level switching associated with changes in the stoichiometry of the surface heterostructure. The ability to cycle between two well‐defined magnetic states at a surface may be attractive in technological applications

The X-ray Emission from the Nucleus of the Dwarf Elliptical Galaxy NGC 3226

We present the first high resolution X-ray image of the dwarf elliptical galaxy NGC 3226. The data were obtained during an observation of the nearby Seyfert Galaxy NGC 3227 using the Chandra X-ray Observatory. We detect a point X-ray source spatially consistent with the optical nucleus of NGC 3226 and a recently-detected, compact, flat-spectrum, radio source. The X-ray spectrum can be measured up to ~10 keV and is consistent with a power law with a photon index 1.7 <~ Gamma <~ 2.2, or thermal bremmstrahlung emission with 4 <~ kT <~ 10 keV. In both cases the luminosity in the 2--10 keV band ~10^{40} h_{75}^{-1} erg/s. We find marginal evidence that the nucleus varies within the observation. These characteristics support evidence from other wavebands that NGC 3226 harbors a low-luminosity, active nucleus. We also comment on two previously-unknown, fainter X-ray sources <~ 15 arcsec from the nucleus of NGC 3226. Their proximity to the nucleus (with projected distances <~ 1.3/h_{75} kpc) suggests both are within NGC 3226, and thus have luminosities (~few x 10^{38} -- few x 10^{39} erg/s) consistent with black-hole binary systems.Comment: Accepted for publication in ApJ. Figures in colo

The outflow in Mrk 509: A method to calibrate XMM-Newton EPIC-pn and RGS

We have analyzed three XMM-Newton observations of the Seyfert 1 galaxy Mrk 509, with the goal to detect small variations in the ionized outflow properties. Such measurements are limited by the quality of the cross-calibration between RGS, the best instrument to characterize the spectrum, and EPIC-pn, the best instrument to characterize the variability. For all three observations we are able to improve the relative calibration of RGS and pn consistently to 4 %. In all observations we detect three different outflow components and, thanks to our accurate cross-calibration we are able to detect small differences in the ionization parameter and column density in the highest ionized component of the outflow. This constrains the location of this component of the outflow to within 0.5 pc of the central source. Our method for modeling the relative effective area is not restricted to just this source and can in principle be extended to other types of sources as well.Comment: 11 pages, 9 figure

The Very Highly Ionized Broad Absorption Line System of the QSO SBS1542+541

We have analyzed the broad absorption line system of the bright (V=16.5) high-redshift (z=2.361) QSO SBS1542+541 using UV spectra from the HST FOS along with optical data from the MMT and the Steward Observatory 2.3m telescope. These spectra give continuous wavelength coverage from 1200 to 8000 Angstroms, corresponding to 340 to 2480 Angstroms in the QSO rest frame. This object therefore offers a rare opportunity to study broad absorption lines in the rest-frame extreme UV. We find that the absorption system is dominated by very high-ionization species, including O VI, NeVIII, and SiXII. We also identify apparently saturated broad Lyman-series lines of order Ly-gamma and higher. There is strong evidence for partial occultation of the QSO emission source, particularly from the higher-order Lyman lines which indicate a covered fraction less than 0.2. Overall, the data suggest a correlation between a larger covered fraction and a higher state of ionization. We suggest that the different covered fractions can be explained by either a special line of sight through a disk-like geometry or by the existence of density fluctuations of a factor >2 in the BAL gas. Our photoionization models of the system indicate a large column density and high ionization state similar to that found in X-ray ``warm absorbers''.Comment: 31 pages, 13 figures, to be published in Ap