428 research outputs found
Nature of the spin dynamics and 1/3 magnetization plateau in azurite
We present a specific heat and inelastic neutron scattering study in magnetic
fields up into the 1/3 magnetization plateau phase of the diamond chain
compound azurite Cu(CO)(OH). We establish that the
magnetization plateau is a dimer-monomer state, {\it i.e.}, consisting of a
chain of monomers, which are separated by dimers on the
diamond chain backbone. The effective spin couplings K
and K are derived from the monomer and dimer
dispersions. They are associated to microscopic couplings K,
K and a ferromagnetic K, possibly as
result of orbitals in the Cu-O bonds providing the superexchange
pathways.Comment: 5 pages, 4 figure
Magnetoelastic and structural properties of azurite Cu3(CO3)2(OH)2 from neutron scattering and muon spin rotation
Azurite, Cu3(CO3)2(OH)2, has been considered an ideal example of a
one-dimensional (1D) diamond chain antiferromagnet. Early studies of this
material imply the presence of an ordered antiferromagnetic phase below K while magnetization measurements have revealed a 1/3 magnetization
plateau. Until now, no corroborating neutron scattering results have been
published to confirm the ordered magnetic moment structure. We present recent
neutron diffraction results which reveal the presence of commensurate magnetic
order in azurite which coexists with significant magnetoelastic strain. The
latter of these effects may indicate the presence of spin frustration in zero
applied magnetic field. Muon spin rotation, SR, reveals an onset of
short-range order below 3K and confirms long-range order below .Comment: 5 pages, 4 figures, PHYSICAL REVIEW B 81, 140406(R) (2010
The influence of natural and anthropogenic secondary sources on the glyoxal global distribution
Glyoxal, the smallest dicarbonyl, which has recently been observed from space, is expected to provide indications on volatile organic compounds (VOC) oxidation and secondary aerosol formation in the troposphere. Glyoxal (CHOCHO) is known to be mostly of natural origin and is produced during biogenic VOC oxidation. However, a number of anthropogenically emitted hydrocarbons, like acetylene and aromatics, have been positively identified as CHOCHO precursors. The present study investigates the contribution of pollution to the CHOCHO levels by taking into account the secondary chemical formation of CHOCHO from precursors emitted from biogenic, anthropogenic and biomass burning sources. The impact of potential primary land emissions of CHOCHO is also investigated. A global 3-dimensional chemistry transport model of the troposphere (TM4-ECPL) able to simulate the gas phase chemistry coupled with all major aerosol components is used. <br><br> The secondary anthropogenic contribution from fossil fuel and industrial VOCs emissions oxidation to the CHOCHO columns is found to reach 20–70% in the industrialized areas of the Northern Hemisphere and 3–20% in the tropics. This secondary CHOCHO source is on average three times larger than that from oxidation of VOCs from biomass burning sources. The chemical production of CHOCHO is calculated to equal to about 56 Tg y<sup>&minus;1</sup> with 70% being produced from biogenic hydrocarbons oxidation, 17% from acetylene, 11% from aromatic chemistry and 2% from ethene and propene. CHOCHO is destroyed in the troposphere primarily by reaction with OH radicals (23%) and by photolysis (63%), but it is also removed from the atmosphere through wet (8%) and dry deposition (6%). Potential formation of secondary organic aerosol through CHOCHO losses on/in aerosols and clouds is neglected here due to the significant uncertainties associated with the underlying chemistry. The global annual mean CHOCHO burden and lifetime in the model domain are estimated to be 0.02 Tg (equal to the global burden seen by SCIAMACHY over land for the year 2005) and about 3 h, respectively. The model results are compared with satellite observations of CHOCHO columns. When accounting only for the secondary sources of CHOCHO in the model, the model underestimates CHOCHO columns observed by satellites. This is attributed to an overestimate of CHOCHO sinks or a missing global source of about 20 Tg y<sup>&minus;1</sup>. Using the current primary emissions of CHOCHO from biomass burning together with the anthropogenic combustion sources of about 7 Tg y<sup>&minus;1</sup> leads to an overestimate by the model over hot spot areas
Linear sampling method for identifying cavities in a heat conductor
We consider an inverse problem of identifying the unknown cavities in a heat
conductor. Using the Neumann-to-Dirichlet map as an input data, we develop a
linear sampling type method for the heat equation. A new feature is that there
is a freedom to choose the time variable, which suggests that we have more data
than the linear sampling methods for the inverse boundary value problem
associated with EIT and inverse scattering problem with near field data
Concept of an ionizing time-domain matter-wave interferometer
We discuss the concept of an all-optical and ionizing matter-wave
interferometer in the time domain. The proposed setup aims at testing the wave
nature of highly massive clusters and molecules, and it will enable new
precision experiments with a broad class of atoms, using the same laser system.
The propagating particles are illuminated by three pulses of a standing
ultraviolet laser beam, which detaches an electron via efficient single
photon-absorption. Optical gratings may have periods as small as 80 nm, leading
to wide diffraction angles for cold atoms and to compact setups even for very
massive clusters. Accounting for the coherent and the incoherent parts of the
particle-light interaction, we show that the combined effect of phase and
amplitude modulation of the matter waves gives rise to a Talbot-Lau-like
interference effect with a characteristic dependence on the pulse delay time.Comment: 25 pages, 5 figure
Evidence for Efimov quantum states in an ultracold gas of cesium atoms
Systems of three interacting particles are notorious for their complex
physical behavior. A landmark theoretical result in few-body quantum physics is
Efimov's prediction of a universal set of bound trimer states appearing for
three identical bosons with a resonant two-body interaction.
Counterintuitively, these states even exist in the absence of a corresponding
two-body bound state. Since the formulation of Efimov's problem in the context
of nuclear physics 35 years ago, it has attracted great interest in many areas
of physics. However, the observation of Efimov quantum states has remained an
elusive goal. Here we report the observation of an Efimov resonance in an
ultracold gas of cesium atoms. The resonance occurs in the range of large
negative two-body scattering lengths, arising from the coupling of three free
atoms to an Efimov trimer. Experimentally, we observe its signature as a giant
three-body recombination loss when the strength of the two-body interaction is
varied. We also detect a minimum in the recombination loss for positive
scattering lengths, indicating destructive interference of decay pathways. Our
results confirm central theoretical predictions of Efimov physics and represent
a starting point with which to explore the universal properties of resonantly
interacting few-body systems. While Feshbach resonances have provided the key
to control quantum-mechanical interactions on the two-body level, Efimov
resonances connect ultracold matter to the world of few-body quantum phenomena.Comment: 18 pages, 3 figure
Observation of an Efimov spectrum in an atomic system
In 1970 V. Efimov predicted a puzzling quantum-mechanical effect that is
still of great interest today. He found that three particles subjected to a
resonant pairwise interaction can join into an infinite number of loosely bound
states even though each particle pair cannot bind. Interestingly, the
properties of these aggregates, such as the peculiar geometric scaling of their
energy spectrum, are universal, i.e. independent of the microscopic details of
their components. Despite an extensive search in many different physical
systems, including atoms, molecules and nuclei, the characteristic spectrum of
Efimov trimer states still eludes observation. Here we report on the discovery
of two bound trimer states of potassium atoms very close to the Efimov
scenario, which we reveal by studying three-particle collisions in an ultracold
gas. Our observation provides the first evidence of an Efimov spectrum and
allows a direct test of its scaling behaviour, shedding new light onto the
physics of few-body systems.Comment: 10 pages, 3 figures, 1 tabl
Chassis organism from Corynebacterium glutamicum – a top-down approach to identify and delete irrelevant gene clusters
Unthan S, Baumgart M, Radek A, et al. Chassis organism from Corynebacterium glutamicum – a top-down approach to identify and delete irrelevant gene clusters. Biotechnology Journal. 2015;10(2):290-301
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