Spin fluctuations with two-dimensional XY behavior in a frustrated S = 1/2 square-lattice ferromagnet

The spin dynamics of the layered square-lattice vanadate Pb2VO(PO4)2 is investigated by electron spin resonance at various magnetic fields and at temperatures above magnetic ordering. The linewidth divergence towards low temperatures seems to agree with isotropic Heisenberg-type spin exchange suggesting that the spin relaxation in this quasi-two dimensional compound is governed by low-dimensional quantum fluctuations. However, a weak easy- plane anisotropy of the g factor points to the presence of a planar XY type of exchange. Indeed, we found that the linewidth divergence is described best by XY-like spin fluctuations which requires a single parameter only. Therefore, ESR-probed spin dynamics could establish Pb2VO(PO4)2 as the first frustrated square lattice system with XY-inherent spin topological fluctuations.Comment: 5 pages, 3 figure

Respiration rates of soil invertebrates from temperate and tropical zones as measured by infrared gas analysis.

The aim of our investigation was to measure the amount of carbon that is directly contributed by the soil fauna. Therefore a devide to measure the small amounts of CO2 released by soil invertebrates was developed. A commercially available portable photosynthesis measuring system, based on an infrared gas analyzer (IRGA) and designed to quantifity the CO2 uktake to single plant leaves, was modified in such a way that the CO2 production of soil invertebrates could be measured

Assessing flood risk for a rural detention area

International audienceFlood detention areas serve the primary purpose of controlled water storage during large flood events in order to decrease the flood risk downstream along the river. These areas are often used for agricultural production. While various damage estimation methods exist for urban areas, there are only a few, most often simpler approaches for loss estimation in rural areas. The loss assessment can provide an estimate of the financial provisions required for the farmers' compensation (e.g., in the context of cost-benefit analyses of detention measures). Flood risk is a combination of potential damage and probability of flooding. Losses in agricultural areas exhibit a strong seasonal pattern, and the flooding probability also has a seasonal variation. In the present study, flood risk is assessed for a planned detention area alongside the Elbe River in Germany based on two loss and probability estimation approaches of different time frames, namely a monthly and an annual approach. The results show that the overall potential damage in the proposed detention area amounts to approximately 40 000 ? a?1, with approximately equal losses for each of the main land uses, agriculture and road infrastructure. A sensitivity analysis showed that the probability of flooding (i.e., the frequency of operation of the detention area) has the largest impact on the overall flood risk

Spectroscopic studies of fluorescent perylene dyes

The lowest electronic transition of the fluorescent perylene dye bis-(3,5-di-tertbutylphenyl)-perylene-3, 4:9,10-biscarboximide has been investigated

K+ and K- production in heavy-ion collisions at SIS-energies

The production and the propagation of K+ and of K- mesons in heavy-ion collisions at beam energies of 1 to 2 AGeV have systematically been investigated with the Kaon Spectrometer KaoS at the SIS at the GSI. The ratio of the K+ production excitation function for Au+Au and for C+C reactions increases with decreasing beam energy, which is expected for a soft nuclear equation-of-state. At 1.5 AGeV a comprehensive study of the K+ and of the K- emission as a function of the size of the collision system, of the collision centrality, of the kaon energy, and of the polar emission angle has been performed. The K-/K+ ratio is found to be nearly constant as a function of the collision centrality. The spectral slopes and the polar emission patterns are different for K- and for K+. These observations indicate that K+ mesons decouple earlier from the reaction zone than K- mesons.Comment: invited talk given at the SQM2003 conference in Atlantic Beach, USA (March 2003), to be published in Journal of Physics G, 10pages, 7 figure

Circadian Organization in Hemimetabolous Insects

The circadian system of hemimetabolous insects is reviewed in respect to the locus of the circadian clock and multioscillatory organization. Because of relatively easy access to the nervous system, the neuronal organization of the clock system in hemimetabolous insects has been studied, yielding identification of the compound eye as the major photoreceptor for entrainment and the optic lobe for the circadian clock locus. The clock site within the optic lobe is inconsistent among reported species; in cockroaches the lobula was previously thought to be a most likely clock locus but accessory medulla is recently stressed to be a clock center, while more distal part of the optic lobe including the lamina and the outer medulla area for the cricket. Identification of the clock cells needs further critical studies. Although each optic lobe clock seems functionally identical, in respect to photic entrainment and generation of the rhythm, the bilaterally paired clocks form a functional unit. They interact to produce a stable time structure within individual insects by exchanging photic and temporal information through neural pathways, in which serotonin and pigment-dispersing factor (PDF) are involved as chemical messengers. The mutual interaction also plays an important role in seasonal adaptation of the rhythm

An anionic phosphenium complex as an ambident nucleophile

A unique anionic phosphenium complex was prepared from reaction of an N-heterocyclic chlorophosphine with Collman's reagent or K[HFe(CO)(4)]/NaH and characterized by spectral and XRD data. The complex behaves as an ambident nucleophile. Reactions with acetic acid, ClSnPh3, and a further equivalent of an N-heterocyclic chlorophosphine proceed via electrophilic functionalization at the metal site to yield appropriate mono- or bis-phosphenium complexes. Reaction with MeI at -70 degrees C produces a P-alkylation product as the first spectroscopically detectable intermediate, which decays at a higher temperature to give a mixture of free P-methylated N-heterocyclic phosphine and its Fe(CO)(4) complex. The different reaction products were characterized by spectral and XRD data. Computational studies indicate that the NHP units in all complexes display p-acceptor behaviour but show no disposition to adopt phosphide-like character or formally oxidize the metal centre.Peer reviewe