Adverse Effects of Heartwood on the Mechanical Properties of Wood-Wool Cement Boards Manufactured from Radiata Pine Wood

Wood-wool cement boards (WWCBs) that are manufactured commercially in Australia from radiata pine occasionally contain localized areas in which there is poor bonding between wood and cement. The cause of this defect, which leads to the rejection of boards before they arc sold, is not known, but it has been suggested that it may be due to the use of blue-stained wood or heartwood in the manufacture of boards. In this study, both wood types were tested for their effects on the hydration of Portland cement and the mechanical properties of WWCBs. Blue-stained sapwood slightly retarded the hydration of cement but had no significant (P < 0.05) effect on the mechanical properties of boards. In contrast, heartwood severely retarded cement hydration, and boards made from heartwood had little structural integrity. The appearance of such boards resembled the defective portions of commercially produced boards, and therefore it can be concluded that the defect arises from the inhibitory effect of heartwood on cement hydration. The problem could be eliminated by processing logs from young radiata pine trees, less than 12-15 years old, which will contain little or no heartwood

Manufacture of Wood-Cement Composites from Acacia Mangium. Part II. Use of Accelerators in the Manufacture of Wood-Wool Cement Boards from A. Mangium

In the second paper in this series, we test the hypothesis that cement-setting accelerators with the ability to chelate phenolic extractives will be more effective at improving the physical properties of wood-wool cement boards made from the heartwood of Acacia mangium than conventional accelerators. Furthermore, we assess whether the use of chelating accelerators will allow boards with acceptable properties to be manufactured from A. mangium wood-wool that has not been subjected to preliminary aqueous extraction to remove phenolic extractives. Batches of wood-wool from A. mangium containing approximately 75% heartwood were either soaked in water or used in their native form. The batches were then treated with an aqueous solution containing an inorganic compound (generally 0.05 or 0.1 M) selected for its ability to accelerate the hydration of Portland cement, and in the case of 5 of the 11 compounds tested, chelate phenolic extractives. Individual wood-wool cement boards were manufactured from each treated batch of wood-wool and tested for their dry and wet bending strength (MOR), stiffness (MOE), and water absorption properties. Boards made from untreated or water-soaked wood-wool acted as controls. The MOR and MOE of boards made from unsoaked A. mangium wood-wool and treated with the chelating accelerators tin or ferric chloride at 0.1 M concentration were 10.8 and 10.9 MPa and 2256 and 2178 MPa, respectively. These same boards showed less than 5% thickness swelling after 24-h immersion in water. In contrast most of the boards containing a conventional non-chelating accelerator had no structural integrity. The combination of a chelating accelerator and a conventional accelerator was particularly effective at improving the physical properties of boards made from unsoaked wood-wool. We conclude that wood-wool cement boards with acceptable physical properties can be manufactured from A. mangium heartwood by treating wood-wool with inorganic compounds that have the ability to chelate phenolic extractives and accelerate the hydration of Portland cement. Our findings could eliminate the need to pre-soak A. mangium wood-wool in water during the manufacture of wood-wool cement boards and may have broader relevance to the manufacture of wood-wool cement boards from other hardwood species containing phenolic extractives

Thermal Modification of Color in Red Alder Veneer. I. Effects of Temperature, Heating Time, and Wood Type

Red alder has become one of the most widely traded hardwood species in North America, and sliced red alder veneer is commonly applied as a decorative overlay on composite wood panels used by the furniture and cabinet industries. Red alder wood, however, acquires a mottled orange color following felling, which is undesirable when the wood is used for decorative purposes. Heating red alder wood remedies this problem to some extent, but there is still an unacceptable level of variability in the color of veneer sliced from heated veneer cants. This study examined the variation in color of red alder wood samples cut sequentially from the pith to the bark and subjected to heating under isothermal conditions. The aim was to examine whether within-tree variation in the susceptibility of red alder wood to thermal darkening can explain variation in color of veneer sliced from steamed red alder cants, and to determine the optimal thermal treatment (temperature and time) that can impart the tan color to red alder wood that industry is seeking. Results indicated that there was within-tree variation in the color of red alder samples following thermal treatment, but differences were pronounced only when wood was heated at a low temperature. Wood close to the bark tended to be redder than wood close to the pith when heated at 30°C, but such a difference was absent in wood heated at higher temperatures (50-90°C). Heating red alder wood, in vitro, at 70°C for 36 h produced wood that was evenly colored from pith to bark and matched the current industry color preference. It is suggested that the color of thermally modified red alder wood depends on the strength of reactions that produce orange/red chromophores in the wood, thermal darkening of the wood, and destruction of orange/red chromophores

Thermal Modification of Color in Red Alder Veneer. Part II. Effects of Season, Log Storage Time, and Location of Wood in Stems

The value of red alder lumber is diminished by discoloration caused by the enzyme-mediated polymerization of the diarylheptanoid xyloside, Oregonin that results in the formation of red-colored chromophores in freshly felled wood. This discoloration can be reduced by pre-steaming wood prior to kiln drying of lumber or veneer slicing, but in practice, there is still variation in the color of heat-treated wood, particularly in veneer sliced from heat-treated cants processed at different times of the year. There is seasonal variation in the concentration of Oregonin that is involved in the discoloration of red alder wood and it is hypothesized here that heat-treated red alder wood will be redder and darker when the wood is obtained from logs harvested during spring when the concentration of Oregonin is known to be higher than in other seasons. The aim of this research was to test this hypothesis, and also examine the effects of log storage time and location of wood in stems on the color of heat-treated red alder wood. The color of red alder wood subjected to an isothermal heat treatment at 70°C was strongly influenced by the season in which parent trees were harvested and the length of time that logs were stored prior to heat treatment of wood. In particular, wood harvested in spring and stored for 2 wk prior to heat treatment was significantly darker than similarly treated wood obtained from logs harvested in other seasons, and redder than wood harvested in summer and winter. If the storage time of logs harvested in spring and summer was extended to 4 wk, however, the heat-treated wood became lighter and less red. Heat-treated wood from the inner part of the logs was redder and darker than heat-treated wood from the outer part of the logs except occasionally, when the outer sapwood was obtained from logs harvested in spring or summer. Careful control of log storage time, heating temperature, and duration of heat treatment could be used to minimize seasonal variation in the color of veneer sliced from heated red alder cants

The Role of Legal Services in the Antipoverty Program

Large-scale adaptive radiations might explain the runaway success of a minority of extant vertebrate clades. This hypothesis predicts, among other things, rapid rates of morphological evolution during the early history of major groups, as lineages invade disparate ecological niches. However, few studies of adaptive radiation have included deep time data, so the links between extant diversity and major extinct radiations are unclear. The intensively studied Mesozoic dinosaur record provides a model system for such investigation, representing an ecologically diverse group that dominated terrestrial ecosystems for 170 million years. Furthermore, with 10,000 species, extant dinosaurs (birds) are the most speciose living tetrapod clade. We assembled composite trees of 614-622 Mesozoic dinosaurs/birds, and a comprehensive body mass dataset using the scaling relationship of limb bone robustness. Maximum-likelihood modelling and the node height test reveal rapid evolutionary rates and a predominance of rapid shifts among size classes in early (Triassic) dinosaurs. This indicates an early burst niche-filling pattern and contrasts with previous studies that favoured gradualistic rates. Subsequently, rates declined in most lineages, which rarely exploited new ecological niches. However, feathered maniraptoran dinosaurs (including Mesozoic birds) sustained rapid evolution from at least the Middle Jurassic, suggesting that these taxa evaded the effects of niche saturation. This indicates that a long evolutionary history of continuing ecological innovation paved the way for a second great radiation of dinosaurs, in birds. We therefore demonstrate links between the predominantly extinct deep time adaptive radiation of non-avian dinosaurs and the phenomenal diversification of birds, via continuing rapid rates of evolution along the phylogenetic stem lineage. This raises the possibility that the uneven distribution of biodiversity results not just from large-scale extrapolation of the process of adaptive radiation in a few extant clades, but also from the maintenance of evolvability on vast time scales across the history of life, in key lineages

DISTINGUISHING NATIVE AND PLANTATION-GROWN MAHOGANY (SWIETENIA MACROPHYLLA) TIMBER USING CHROMATOGRAPHY AND HIGH-RESOLUTION QUADRUPOLE TIME-OF-FLIGHT MASS SPECTROMETRY

Plantation-grown mahogany (Swietenia macrophylla) from Fiji has been preferred as a sus- tainable wood source for the craftingof electric guitars because its trade is not restricted by Convention on International Trade in Endangered Species of Wild Fauna andFlora (CITES), unlike S. macrophylla sourced from native forests. Ability to differentiate between the two wood types would deter sale of illegally harvested native-grown S. macrophylla to luthiers and other artisans. The chemical composition of wood is influenced bycambial age and geographical factors, and there are chemical differences between S. macrophylla grown in different regions. Thisstudy tested the ability of high-resolution mass spectrometry to chemotypically dif- ferentiate plantation-grown Fijian S. macrophylla from the same wood species obtained from native forests. Multiple heartwood specimens of both wood types were extracted and chromatographically profiled using gas and liquid chromatography tandem high-resolution quadrupole time-of-flight massspectrometry (GC/QToF, LC/QToF). Visual comparison of mass spectral ions, together with modern analytical data-mining techniques,were employed to screen the results. Principal component analysis scatter plots with 95% confidence ellipses showed unambiguousseparation of the two wood types by GC/LC/QToF. We conclude that screening of heartwood extractives using high-resolution massspectrometry offers an effective way of identifying and sepa- rating plantation-grown Fijian S. macrophylla from wood grown in native forests

Human Resource Needs and Demand for Post-Secondary Education in the Canadian Secondary Wood Products Industry

Skilled labor shortages in manufacturing industries are being reported in a number of countries. The extent to which such shortages are affecting Canadian wood manufacturing industries is not known. The aim of this study was to survey the skills and educational needs of Canadian wood manufacturing industries, the status, capacity, and challenges that post-secondary education institutes face in meeting industries' human resource needs, and finally the attractiveness of the industry to high school job-seekers. The majority (83%) of wood manufacturing companies in Canada are experiencing problems in hiring skilled tradespeople, and 54.5% of the companies face difficulties in hiring and retaining professionals and supervisory personnel. Skilled staff shortages and competitive pressures were nominated by companies as the two most important factors restricting their growth. The skills needs of companies have changed over the last 10 years, and companies now place a much higher premium on leadership and communication skills from management, and attitude and advanced technical skills from tradespeople. Most companies offered some kind of in-house training to redress skills gaps, but less than half were likely to use the Internet to deliver in-house training. The majority of high school students were not interested in pursuing a career in the wood manufacturing industry because of its association with unsustainable forestry practices and manual labor, and the availability of more attractive career options. Lack of student interest in wood manufacturing is affecting the institutions offering relevant vocational and professional training, and nine of the thirteen institutes suffer from under-enrollment in their wood manufacturing programs. Comprehensive strategies are required to address the labor market imbalances currently affecting Canada's wood manufacturing industries

Single-Bottleneck Approximation for Driven Lattice Gases with Disorder and Open Boundary Conditions

We investigate the effects of disorder on driven lattice gases with open boundaries using the totally asymmetric simple exclusion process as a paradigmatic example. Disorder is realized by randomly distributed defect sites with reduced hopping rate. In contrast to equilibrium, even macroscopic quantities in disordered non-equilibrium systems depend sensitively on the defect sample. We study the current as function of the entry and exit rates and the realization of disorder and find that it is, in leading order, determined by the longest stretch of consecutive defect sites (single-bottleneck approximation, SBA). Using results from extreme value statistics the SBA allows to study ensembles with fixed defect density which gives accurate results, e.g. for the expectation value of the current. Corrections to SBA come from effective interactions of bottlenecks close to the longest one. Defects close to the boundaries can be described by effective boundary rates and lead to shifts of the phase transitions. Finally it is shown that the SBA also works for more complex models. As an example we discuss a model with internal states that has been proposed to describe transport of the kinesin KIF1A.Comment: submitted to J. Stat. Mec

Avifauna and urban encroachment in time and space

AIM: Urban expansion significantly alters fringe environments often with unde-sirable impacts on biodiversity. Consequently, there is a need to define clearconservation objectives for areas subject to urban encroachment. Urban fringe development is a highly dynamic process, both spatially and temporally, but few studies are equipped to examine its temporal effects on biota. We aimed to explore the impacts of urban encroachment on avifauna through space and time.LOCATION: The Australian Capital Territory, Australia. METHODS: We used records from an extensive 14-year monitoring programme undertaken in temperate woodland. We fitted hierarchical generalized linear models to assess individual species responses to the distance from monitoring sites to the urban boundary, and the temporal rate of change in this distance through time. We used factorial analysis on mixed data to examine trait group responses to these predictors.RESULTS: Our results indicated that the occurrence of approximately half of the study region’s avifauna is strongly linked to the proximity of their habitat to the urban fringe, but that the impact of urban fringe development on the occurrence of some species changed through time. We identified several species of conservation concern that respond negatively to large annual increases in urban fringe development, irrespective of its proximity to suitable habitat. Species responses to urban proximity were linked to life history traits, with small,migratory, woodland-dependent species that rely on mid- and upper-canopy structures, clearly disadvantaged by urban environments.MAIN CONCLUSIONS: Our findings demonstrate the breadth of species responses to urban encroachment over much larger distances than is typically investigated in urban ecological studies. We identify guilds vulnerable to the impacts of urban fringe development and therefore in need of ecologically sensitive urban design. We argue that future urban expansion towards important fringe habitats will need to be planned strategically through space and time.This research received funding support from Conservation Planning and Research, Environment and Sustainable Devel-opment Directorate ACT Government and the Fenner Schoolof Environment and Society. DBL, PG and KI were sup-ported by the National Environmental Research Program. ADM was supported by an ARC Future Fellowship (FT100100358)