320 research outputs found
Photoelectron spectroscopic study of the anionic transition metalorganic complexes [Fe1,2(COT)]− and [C(COT)]−
Get PDFPhotoelectron spectroscopy and theoretical studies of [Com(pyrene)n]− (m=1,2 and n=1,2) complexes
Get PDFAnion photoelectron spectroscopic experiments and density functional theory based calculations have been used to investigate the structural, electronic, and magnetic properties of neutral and anionic [Com(pyrene)n] (m,n=1–2) complexes. The calculated electron affinities and vertical transition energies of Com(pyrene)n are in good agreement with the measured values. Our results provide clear evidence for dimerization of Co atoms and formation of sandwich structures in these complexes. While the calculated spin magnetic moments of neutral Co2(pyrene)n complexes suggest a preference for ferromagnetic coupling between Co atoms, the spin magnetic moment of Co atom in Co(pyrene) and Co(pyrene)2 complexes was reduced to 1μB
Photoelectron spectroscopy and theoretical studies of [Com(pyrene)n]− (m=1,2 and n=1,2) complexes
Get PDFVolume 40, Number 2, June 2020 OLAC Newsletter
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Volume 39, Number 4, December 2019 OLAC Newsletter
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Volume 39, Number 3, September 2019 OLAC Newsletter
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Volume 40, Number 1, March 2020 OLAC Newsletter
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Volume 41, Number 2, June 2021 OLAC Newsletter
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