Anthropogenic and Climate-Exacerbated Landscape Disturbances Converge to Alter Phosphorus Bioavailability in an Oligotrophic River

Cumulative effects of landscape disturbance in forested source water regions can alter the storage of fine sediment and associated phosphorus in riverbeds, shift nutrient dynamics and degrade water quality. Here, we examine longitudinal changes in major element chemistry and particulate phosphorus (PP) fractions of riverbed sediment in an oligotrophic river during environmentally sensitive low flow conditions. Study sites along 50 km of the Crowsnest River were located below tributary inflows from sub-watersheds and represent a gradient of increasing cumulative sediment pressures across a range of land disturbance types (harvesting, wildfire, and municipal wastewater discharges). Major elements (Si2O, Al2O3, Fe2O3, MnO, CaO, MgO, Na2O, K2O, Ti2O, V2O5, P2O5), loss on ignition (LOI), PP fractions (NH4CI-RP, BD-RP, NaOH-RP, HCI-RP and NaOH(85)-RP), and absolute particle size were evaluated for sediments collected in 2016 and 2017. While total PP concentrations were similar across all sites, bioavailable PP fractions (BD-RP, NaOH-RP) increased downstream with increased concentrations of Al2O3 and MnO and levels of landscape disturbance. This study highlights the longitudinal water quality impacts of increasing landscape disturbance on bioavailable PP in fine riverbed sediments and shows how the convergence of climate (wildfire) and anthropogenic (sewage effluent, harvesting, agriculture) drivers can produce legacy effects on nutrients

A New Framework for Modelling Fine Sediment Transport in Rivers Includes Flocculation to Inform Reservoir Management in Wildfire Impacted Watersheds

Fine-grained cohesive sediment is the primary vector for nutrient and contaminant redistribution through aquatic systems and is a critical indicator of land disturbance. A critical limitation of most existing sediment transport models is that they assume that the transport characteristics of fine sediment can be described using the same approaches that are used for coarse-grained non-cohesive sediment, thereby ignoring the tendency of fine sediment to flocculate. Here, a modelling framework to simulate flow and fine sediment transport in the Crowsnest River, the Castle River, the Oldman River and the Oldman Reservoir after the 2003 Lost Creek wildfire in Alberta, Canada was developed and validated. It is the first to include explicit description of fine sediment deposition/erosion processes as a function of bed shear stress and the flocculation process. This framework integrates four existing numerical models: MOBED, RIVFLOC, RMA2 and RMA4 using river geometry, flow, fine suspended sediment characteristics and bathymetry data. Sediment concentration and particle size distributions computed by RIVFLOC were used as the upstream boundary condition for the reservoir dispersion model RMA4. The predicted particle size distributions and mass of fine river sediment deposited within various sections of the reservoir indicate that most of the fine sediment generated by the upstream disturbance deposits in the reservoir. Deposition patterns of sediment from wildfire-impacted landscapes were different than those from unburned landscapes because of differences in settling behaviour. These differences may lead to zones of relatively increased internal loading of phosphorus to reservoir water columns, thereby increasing the potential for algae proliferation. In light of the growing threats to water resources globally from wildfire, the generic framework described herein can be used to model propagation of fine river sediment and associated nutrients or contaminants to reservoirs under different flow conditions and land use scenarios. The framework is thereby a valuable tool to support decision making for water resources management and catchment planning

Evaluation of Legacy Forest Harvesting Impacts on Dominant Stream Water Sources and Implications for Water Quality Using End Member Mixing Analysis

Forests are critical water supply regions that are increasingly threatened by natural and anthropogenic disturbance. Evaluation of runoff-generating processes within harvested and undisturbed headwater catchments provides insight into disturbance impacts on water quality and drinking water treatability. In this study, an extensive hydrologic dataset collected at the experimental Turkey Lakes Watershed (TLW) located on the Canadian Shield was used to quantify sources of stormflow in legacy clear-cut (24-years post harvesting) and forested (control) headwater catchments using an end member mixing analysis (EMMA) model. Stream water, groundwater, soil water, and throughfall water quality were evaluated during spring snowmelt, stormflow, and fall wet-up. Groundwater chemistry was similar to stream water chemistry in both catchments, suggesting that groundwater is a major contributor to stream flow. The water chemistry in small wetlands within the study catchments was comparable to stream water chemistry, suggesting that wetlands are also important contributors to stream flow. Differences in wetland position between the legacy clear-cut and control catchments appeared to have a greater influence on source contributions than legacy harvesting. Results from this study provide insight into runoff-generation processes that reflect event/seasonal flow dynamics and the impacts on water quality

Sediment source fingerprinting: benchmarking recent outputs, remaining challenges and emerging themes

Abstract: Purpose: This review of sediment source fingerprinting assesses the current state-of-the-art, remaining challenges and emerging themes. It combines inputs from international scientists either with track records in the approach or with expertise relevant to progressing the science. Methods: Web of Science and Google Scholar were used to review published papers spanning the period 2013–2019, inclusive, to confirm publication trends in quantities of papers by study area country and the types of tracers used. The most recent (2018–2019, inclusive) papers were also benchmarked using a methodological decision-tree published in 2017. Scope: Areas requiring further research and international consensus on methodological detail are reviewed, and these comprise spatial variability in tracers and corresponding sampling implications for end-members, temporal variability in tracers and sampling implications for end-members and target sediment, tracer conservation and knowledge-based pre-selection, the physico-chemical basis for source discrimination and dissemination of fingerprinting results to stakeholders. Emerging themes are also discussed: novel tracers, concentration-dependence for biomarkers, combining sediment fingerprinting and age-dating, applications to sediment-bound pollutants, incorporation of supportive spatial information to augment discrimination and modelling, aeolian sediment source fingerprinting, integration with process-based models and development of open-access software tools for data processing. Conclusions: The popularity of sediment source fingerprinting continues on an upward trend globally, but with this growth comes issues surrounding lack of standardisation and procedural diversity. Nonetheless, the last 2 years have also evidenced growing uptake of critical requirements for robust applications and this review is intended to signpost investigators, both old and new, towards these benchmarks and remaining research challenges for, and emerging options for different applications of, the fingerprinting approach

The use of composite fingerprints to quantify sediment sources in a wildfire impacted landscape, Alberta, Canada

There is increasing global concern regarding the impacts of large scale land disturbance by wildfire on a wide range of water and related ecological services. This study explores the impact of the 2003 Lost Creek wildfire in the Crowsnest River basin, Alberta, Canada on regional scale sediment sources using a tracing approach. A composite geochemical fingerprinting procedure was used to apportion the sediment efflux among three key spatial sediment sources: 1) unburned (reference) 2) burned and 3) burned sub-basins that were subsequently salvage logged. Spatial sediment sources were characterized by collecting time-integrated suspended sediment samples using passive devices during the entire ice free periods in 2009 and 2010. The tracing procedure combines the Kruskal-Wallis H-test, principal component analysis and genetic-algorithm driven discriminant function analysis for source discrimination. Source apportionment was based on a numerical mass balance model deployed within a Monte Carlo framework incorporating both local optimization and global (genetic algorithm) optimization. The mean relative frequency-weighted average median inputs from the three spatial source units were estimated to be 17% (inter-quartile uncertainty range 0-32%) from the reference areas, 45% (inter-quartile uncertainty range 25-65%) from the burned areas and 38% (inter-quartile uncertainty range 14-59%) from the burned-salvage logged areas. High sediment inputs from burned and the burned-salvage logged areas, representing spatial source units 2 and 3, reflect the lasting effects of forest canopy and forest floor organic matter disturbance during the 2003 wildfire including increased runoff and sediment availability related to high terrestrial erosion, streamside mass wasting and river bank collapse. The results demonstrate the impact of wildfire and incremental pressures associated with salvage logging on catchment spatial sediment sources in higher elevation Montane regions where forest growth and vegetation recovery are relatively slow

Basic oxygen furnace slag as a treatment material for pathogens: Contribution of inactivation and attachment in virus attenuation

Basic oxygen furnace (BOF) slag media were studied as a potential treatment material in on-site sanitation systems. Batch and column studies were conducted to evaluate attenuation of the bacteriophage PR772 and 0.190 mu m diameter microspheres by BOF media, and to delineate the relative contributions of two principle processes of virus attenuation: inactivation and attachment. In the batch studies, conducted at 4 degrees C, substantial inactivation of PR772 did not occur in the pH 7.6 and 9.5 suspensions. At pH 11.4, bimodal inactivation of PR772 was observed, at an initial rate of 2.1 log C/C(0) day(-1) for the first two days, followed by a much slower rate of 0.124 log C/C(0) day(-1) over the following 10 days. Two column studies were conducted at 4 degrees C at a flow rate of 1 pore volume day(-1) using two slag sources (Stelco, Ontario; Tubarao, Brazil) combined with sand and pea gravel. In both column experiments, the effluent microsphere concentration approached input concentrations over time (reductions of 0.1-0.2 log C/C(0)), suggesting attachment processes for microspheres were negligible. Removal of PR772 virus was more pronounced both during the early stages of the experiments, but also after longer transport times (0.5-1.0 log C/C(0)). PR772 reduction appeared to be primarily as a result of virus inactivation in response to the elevated pH conditions generated by the BOF mixture (10.6-11.4). On-site sanitation systems using BOF media should be designed to maintain sufficient contact time between the BOF media and the wastewater to allow sufficient residence time of pathogens at elevated pH conditions. (C) 2009 Published by Elsevier Ltd.NSERCNSERCEnvironment CanadaEnvironment CanadaInternational Network on Water, Environment and Health at the United Nations University, Hamilton, OntarioInternational Network on Water, Environment and Health at the United Nations University, Hamilton, OntarioSao Paulo State Research Fund (FAPESP)[05/00315-5]Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)KIGAM (Korea Institute of Geosciences and Mineral Resources)KIGAM (Korea Institute of Geosciences and Mineral Resources)[06-7627