89 research outputs found
Model-independent determination of the carrier multiplication time constant in CdSe nanocrystals
The experimental determination of the carrier multiplication (CM) time constant is complicated by the fact that this process occurs within the initial few hundreds of femtoseconds after excitation and, in transient-absorption experiments, cannot be separated from the buildup time of the 1p-state population. This work provides an accurate theoretical determination of the electron relaxation lifetime during the last stage of the p-state buildup, in CdSe nanocrystals, in the presence of a single photogenerated hole (no CM) and of a hole plus an additional electron–hole pair (following CM). From the invariance of the 1p buildup time observed experimentally for excitations above and below the CM threshold producing hot carriers with the same average per-exciton excess energy, and the calculated corresponding variations in the electron decay time in the two cases, an estimate is obtained for the carrier multiplication time constant. Unlike previous estimates reported in the literature so far, this result is model-independent, i.e., is obtained without making any assumption on the nature of the mechanism governing carrier multiplication. It is then compared with the time constant calculated, as a function of the excitation energy, assuming an impact-ionization-like process for carrier multiplication (DCM). The two results are in good agreement and show that carrier multiplication can occur on timescales of the order of tens of femtoseconds at energies close to the observed onset. These findings, which are compatible with the fastest lifetime estimated experimentally, confirm the suitability of the impact-ionization model to explain carrier multiplication in CdSe nanocrystals
The XMM Cluster Survey: Active Galactic Nuclei and Starburst Galaxies in XMMXCS J2215.9-1738 at z=1.46
We use Chandra X-ray and Spitzer infrared observations to explore the AGN and
starburst populations of XMMXCS J2215.9-1738 at z=1.46, one of the most distant
spectroscopically confirmed galaxy clusters known. The high resolution X-ray
imaging reveals that the cluster emission is contaminated by point sources that
were not resolved in XMM observations of the system, and have the effect of
hardening the spectrum, leading to the previously reported temperature for this
system being overestimated. From a joint spectroscopic analysis of the Chandra
and XMM data, the cluster is found to have temperature T=4.1_-0.9^+0.6 keV and
luminosity L_X=(2.92_-0.35^+0.24)x10^44 erg/s extrapolated to a radius of 2
Mpc. As a result of this revised analysis, the cluster is found to lie on the
sigma_v-T relation, but the cluster remains less luminous than would be
expected from self-similar evolution of the local L_X-T relation. Two of the
newly discovered X-ray AGN are cluster members, while a third object, which is
also a prominent 24 micron source, is found to have properties consistent with
it being a high redshift, highly obscured object in the background. We find a
total of eight >5 sigma 24 micron sources associated with cluster members (four
spectroscopically confirmed, and four selected using photometric redshifts),
and one additional 24 micron source with two possible optical/near-IR
counterparts that may be associated with the cluster. Examining the IRAC colors
of these sources, we find one object is likely to be an AGN. Assuming that the
other 24 micron sources are powered by star formation, their infrared
luminosities imply star formation rates ~100 M_sun/yr. We find that three of
these sources are located at projected distances of <250 kpc from the cluster
center, suggesting that a large amount of star formation may be taking place in
the cluster core, in contrast to clusters at low redshift.Comment: Accepted for publication in ApJ, 16 pages, 10 figure
Theory of multiexciton generation in semiconductor nanocrystals
We develop a generalized framework based on a Green's function formalism to
calculate the efficiency of multiexciton gen-eration in nanocrystal quantum
dots. The direct/indirect absorption and coherent/incoherent impact ionization
mechanisms, often used to describe multiexciton generation in nanocrystals, are
reviewed and rederived from the unified theory as certain approximations. In
addition, two new limits are described systematically - the weak Coulomb
coupling limit and the semi-wide band limit. We show that the description of
multiexciton generation in nanocrystals can be described as incoherent process
and we discuss the scaling of multiexciton generation with respect to the
photon energy and nanocrystal size. Illustrations are given for three prototype
systems: CdSe, InAs and silicon quantum dots.Comment: 9 pages, 5 figure
Distribution of carrier multiplication rates in CdSe and InAs nanocrystals
The distribution of rates of carrier multiplication (CM) following photon
absorption is calculated for semiconductor nanocrystals (NCs). The NC
electronic structure is described using a screened pseudopotential method known
to give reliable description of NC excitons. The rates of biexciton generation
are calculated using the Fermi golden rule with all relevant Coulomb matrix
elements, taking into account proper selection rules. In CdSe and InAs NCs we
find a broad distribution biexciton generation rates depending strongly on the
exciton energy and size of the NC. The process becomes inefficient for NC
exceeding 3 nm in diameter in the photon energy range of 2-3 times the band
gap.Comment: 4 pages 3 fi
Can impact excitation explain efficient carrier multiplication in carbon nanotube photodiodes?
We address recent experiments (Science 325, 1367 (2009)) reporting on highly
efficient multiplication of electron-hole pairs in carbon nanotube photodiodes
at photon energies near the carrier multiplication threshold (twice the
quasi-particle band gap). This result is surprising in light of recent
experimental and theoretical work on multiexciton generation in other confined
materials, such as semiconducting nanocrystals. We propose a detailed mechanism
based on carrier dynamics and impact excitation resulting in highly efficient
multiplication of electron-hole pairs. We discuss the important time and energy
scales of the problem and provide analysis of the role of temperature and the
length of the diode
The WiggleZ Dark Energy Survey: galaxy evolution at 0.25 ≤ z ≤ 0.75 using the second red-sequence cluster survey
We study the evolution of galaxy populations around the spectroscopic WiggleZ sample of star-forming galaxies at 0.2
Federated learning enables big data for rare cancer boundary detection.
Although machine learning (ML) has shown promise across disciplines, out-of-sample generalizability is concerning. This is currently addressed by sharing multi-site data, but such centralization is challenging/infeasible to scale due to various limitations. Federated ML (FL) provides an alternative paradigm for accurate and generalizable ML, by only sharing numerical model updates. Here we present the largest FL study to-date, involving data from 71 sites across 6 continents, to generate an automatic tumor boundary detector for the rare disease of glioblastoma, reporting the largest such dataset in the literature (n = 6, 314). We demonstrate a 33% delineation improvement for the surgically targetable tumor, and 23% for the complete tumor extent, over a publicly trained model. We anticipate our study to: 1) enable more healthcare studies informed by large diverse data, ensuring meaningful results for rare diseases and underrepresented populations, 2) facilitate further analyses for glioblastoma by releasing our consensus model, and 3) demonstrate the FL effectiveness at such scale and task-complexity as a paradigm shift for multi-site collaborations, alleviating the need for data-sharing
Author Correction: Federated learning enables big data for rare cancer boundary detection.
10.1038/s41467-023-36188-7NATURE COMMUNICATIONS14
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