Characterisation and categorisation of the diversity in viscoelastic vibrational properties between 98 wood types

Context : Increased knowledge on diversity in wood properties would have implications both for fundamental research and for promoting a diversification of uses as material. Aims : The objective is to contribute to overcoming the critical lack of data on the diversity of wood dynamic mechanical/viscoelastic vibrational properties by testing lesser known species and categorising sources of variability. Methods : Air-dry axial specific dynamic modulus of elasticity (E′/γ) and damping coefficient (tanδ) were measured on a wide sampling (1,792 specimens) of 98 wood types from 79 species. An experimental device and protocol was designed for conducting systematic (i.e. rapid and reproducible) characterisations. Results : Diversity at the specimens' level corroborates the "standard” relationship between tanδ and E′/γ, which is discussed in terms of orientation of wood elements and of chemical composition. Diversity at the species level is expressed on the basis of results for normal heartwood, with specific gravity (γ) ranging from 0.2 to 1.3. Axial E′/γ ranges from 9 to 32GPa and tanδ from 4 × 10−3 to 19 × 10−3. Properties distribution follows a continuum, but with group characteristics. The lowest values of tanδ are only found in certain tropical hardwoods. Results can also suggest alternative species for musical instruments making. Conclusion : The variations in specific gravity, in stiffness or in "viscosity” appear to be predominantly linked to different levels of diversity: between species or between wood types (reaction wood or taxonomy-related differences in heartwood extractives

O-Allylated Pudovik and Passerini Adducts as Versatile Scaffolds for Product Diversification

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Raising the Diversity of Ugi Reactions Through Selective Alkylations and Allylations of Ugi Adducts

We report here selective Tsuji-Trost type allylation of Ugi adducts using a strategy based on the enhanced nucleophilicity of amide dianions. Ugi adducts derived from aromatic aldehydes were easily allylated at their peptidyl position with allyl acetate in the presence of palladium catalysts. These substitutions were compared to more classical transition metal free allylations using allyl bromides

Characterisation and categorisation of the diversity in viscoelastic vibrational properties between 98 wood types

International audienceContext Increased knowledge on diversity in wood properties would have implications both for fundamental research and for promoting a diversification of uses as material. *Aims The objective is to contribute to overcoming the critical lack of data on the diversity of wood dynamic mechanical/viscoelastic vibrational properties, by testing lesser-known species and categorizing sources of variability. *Methods Air-dry axial specific dynamic modulus of elasticity (E'/γ) and damping coefficient (tanδ) were measured on a wide sampling (1792 specimens) of 98 wood types from 79 species. An experimental device and protocol was designed for conducting systematic (i.e. rapid and reproducible) characterizations. *Results Diversity at the specimens' level corroborates the "standard" relationship between tanδ and E'/γ, which is discussed in terms of orientation of wood elements and of chemical composition. Diversity at the species level is expressed on the basis of results for normal heartwood, with specific gravity (γ) ranging from 0.2 to 1.3. Axial E'/γ ranges from 9 to 32 GPa and tanδ from 4×10-3 to 19×10-3. Properties distribution follows a continuum, but with group characteristics. The lowest values of tanδ are only found in certain tropical hardwoods. Results can also suggest alternative species for musical instruments making

Xanthate Based Radical Cascade Toward Multicomponent Formation of Pyrrolopyrimidines

A short sequential synthesis of pyrrolidino- pyridines and pyrimidines illustrates the potential of combining Ugi-Smiles couplings with radical tin-free processes

Code Generation

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