ACHILLES Reading Guide 3: Asset scale deterioration

The deterioration of earthworks reduces theirserviceable performance and increases thelikelihood of instability. This can havesignificant impacts on the safe and reliableoperation of the transportation networks thatthey support. These deterioration processesare weather-driven and may lead to failuremany years after construction even in theabsence of increased mechanical loads.Evidence also indicates that climate changewill increase rates of asset deterioration andreduce time to failure. This documentsummarises the key conclusions on assetdeterioration drawn from the ACHILLES bodyof work. A more detailed overview of theACHILLES concept can be found in ReadingGuide 1 [1], the project website (achilles-grant.org.uk), and the following papers: [2,3]

Forecasting the long-term deterioration of a cut slope in high-plasticity clay using a numerical model

This paper details development of a numerical modelling approach that has beenemployed to forecast the long-term performance of a cut slope formed in high plasticity clay. It links hydrological and mechanical behaviour in a coupled saturated and unsaturated model. This is used to investigate the influence of combined dissipation of excavation-generated excess pore water pressures and seasonal weather-driven near-surface cyclic pore water pressures. Deterioration of slope performance is defined in terms of both slope deformations (i.e. service) and factor of safety against shear failure (i.e. safety). Uniquely, the modelling approach has been validated using 16 years of measured pore water pressure data from multiple locations in a London Clay cut slope. Slope deterioration was shown to be a function of both construction-induced pore water pressure dissipation and seasonal weather driven pore water pressure cycles. These lead to both transient and permanent changes in factor of safety due to effective stress variation and mobilisation of post-peak strength reduction over time, respectively, ultimately causing shallow first-time progressive failure. It is demonstrated that this long-term (90 year) deterioration in slope performance is governed by the hydrological processes in the weathered near surface soil zone that forms following slope excavation

Dynamical stabilization and time in open quantum systems

The meaning of time in an open quantum system is considered under the assumption that both, system and environment, are quantum mechanical objects. The Hamilton operator of the system is non-Hermitian. Its imaginary part is the time operator. As a rule, time and energy vary continuously when controlled by a parameter. At high level density, where many states avoid crossing, a dynamical phase transition takes place in the system under the influence of the environment. It causes a dynamical stabilization of the system what can be seen in many different experimental data. Due to this effect, time is bounded from below: the decay widths (inverse proportional to the lifetimes of the states) do not increase limitless. The dynamical stabilization is an irreversible process.Comment: Contribution to the Special Issue "Quantum Physics with Non-Hermitian Operators: Theory and Experiment", Fortschritte der Physik - Progress of Physic

The seasonal ratcheting of clay cut slopes in response to seasonal weather cycles

Many cut slopes in the UK are in the later stages of their operational life but continue to support road and rail transportation networks. Some of these slopes experienced delayed, deep-seated, first-time failures between 10 and 50 years after construction. However, some continue to seasonally deform and then fail at shallow depth due to the process of seasonal, downslope ratcheting. This paper reviews the evidence for seasonally-induced, downslope ratcheting movements in clay cut slopes, gathered from physical model tests, in-situ monitoring and numerical simulations. The evidence shows that seasonal ratcheting is an increasingly dominant mechanism of slope deformation and ultimate failure for some high-plasticity clay cut slopes as they are exposed to many seasonal weather cycles. The rate of downslope ratcheting depends on the slope age (i.e., number of seasonal weather cycles since construction), the slope geometry (i.e., slope height and angle) and the strain-softening behaviour of the slope material (e.g., as observed in stiff, high-plasticity clays). This rate, when measured, can be used to inform monitoring and management strategies for old, clay cut slopes (e.g., ageing railway and highway cuttings) by identifying the slopes that are prone to seasonally-induced, downslope ratcheting towards the end of their operational life

Controlled Synthesis of Carbon-Encapsulated Copper Nanostructures by Using Smectite Clays as Nanotemplates

Rhomboidal and spherical metallic-copper nanostructures were encapsulated within well-formed graphitic shells by using a simple chemical method that involved the catalytic decomposition of acetylene over a copper catalyst that was supported on different smectite clays surfaces by ion-exchange. These metallic-copper nanostructures could be separated from the inorganic support and remained stable for months. The choice of the clay support influenced both the shape and the size of the synthesized Cu nanostructures. The synthesized materials and the supported catalysts from which they were produced were studied in detail by TEM and SEM, powder X-ray diffraction, thermal analysis, as well as by Raman and X-ray photoelectron spectroscopy.

Predicting protein decomposition: the case of aspartic-acid racemization kinetics

The increase in proportion of the non-biological (D-) isomer of aspartic acid (Asp) relative to the L- isomer has been widely used in archaeology and geochemistry as a tool for dating. The method has proved controversial, particularly when used for bones. The non-linear kinetics of Asp racemization have prompted a number of suggestions as to the underlying mechanism(s) and have led to the use of mathe- matical transformations which linearize the increase in D-Asp with respect to time. Using one example, a suggestion that the initial rapid phase of Asp racemization is due to a contribution from asparagine (Asn), we demonstrate how a simple model of the degradation and racemization of Asn can be used to predict the observed kinetics. A more complex model of peptide bound Asx (Asn+Asp) racemization, which occurs via the formation of a cyclic succinimide (Asu), can be used to correctly predict Asx racemi- zation kinetics in proteins at high temperatures (95-140 °C). The model fails to predict racemization kinetics in dentine collagen at 37 °C. The reason for this is that Asu formation is highly conformation dependent and is predicted to occur extremely slowly in triple helical collagen. As conformation strongly in£uences the rate of Asu formation and hence Asx racemization, the use of extrapolation from high temperatures to estimate racemization kinetics of Asx in proteins below their denaturation temperature is called into question. In the case of archaeological bone, we argue that the D:L ratio of Asx re£ects the proportion of non- helical to helical collagen, overlain by the e¡ects of leaching of more soluble (and conformationally unconstrained) peptides. Thus, racemization kinetics in bone are potentially unpredictable, and the proposed use of Asx racemization to estimate the extent of DNA depurination in archaeological bones is challenged

The diastereoselective Meth-Cohn epoxidation of camphor-derived vinyl sulfones

Some camphor-derived vinyl sulfones bearing oxygen functionality at the allylic position have been synthesized and their nucleophilic epoxidation reactions under Meth-Cohn conditions have been explored. The γ-oxygenated camphor-derived vinyl sulfones underwent mildly diastereoselective nucleophilic epoxidation reactions, affording the derived sulfonyloxiranes in up to 5.8:1 dr. The observed diastereoselectivities were sensitive to the reaction conditions employed. In contrast, no stereoselectivity was observed in the nucleophilic epoxidation of the corresponding γ-oxygenated isobornyl vinyl sulfone. A tentative mechanism has been proposed to explain the origins of the diastereoselectivit

Pain assessment for people with dementia: a systematic review of systematic reviews of pain assessment tools.

BACKGROUND: There is evidence of under-detection and poor management of pain in patients with dementia, in both long-term and acute care. Accurate assessment of pain in people with dementia is challenging and pain assessment tools have received considerable attention over the years, with an increasing number of tools made available. Systematic reviews on the evidence of their validity and utility mostly compare different sets of tools. This review of systematic reviews analyses and summarises evidence concerning the psychometric properties and clinical utility of pain assessment tools in adults with dementia or cognitive impairment. METHODS: We searched for systematic reviews of pain assessment tools providing evidence of reliability, validity and clinical utility. Two reviewers independently assessed each review and extracted data from them, with a third reviewer mediating when consensus was not reached. Analysis of the data was carried out collaboratively. The reviews were synthesised using a narrative synthesis approach. RESULTS: We retrieved 441 potentially eligible reviews, 23 met the criteria for inclusion and 8 provided data for extraction. Each review evaluated between 8 and 13 tools, in aggregate providing evidence on a total of 28 tools. The quality of the reviews varied and the reporting often lacked sufficient methodological detail for quality assessment. The 28 tools appear to have been studied in a variety of settings and with varied types of patients. The reviews identified several methodological limitations across the original studies. The lack of a 'gold standard' significantly hinders the evaluation of tools' validity. Most importantly, the samples were small providing limited evidence for use of any of the tools across settings or populations. CONCLUSIONS: There are a considerable number of pain assessment tools available for use with the elderly cognitive impaired population. However there is limited evidence about their reliability, validity and clinical utility. On the basis of this review no one tool can be recommended given the existing evidence