Quantum Statistical Relation for black holes in nonlinear electrodynamics coupled to Einstein-Gauss-Bonnet AdS gravity

We consider curvature-squared corrections to Einstein-Hilbert gravity action in the form of Gauss-Bonnet term in D>4 dimensions. In this theory, we study the thermodynamics of charged static black holes with anti-de Sitter (AdS) asymptotics, and whose electric field is described by nonlinear electrodynamics (NED). These objects have received considerable attention in recent literature on gravity/gauge dualities. It is well-known that, within the framework of anti de-Sitter/Conformal Field Theory (AdS/CFT) correspondence, there exists a nonvanishing Casimir contribution to the internal energy of the system, manifested as the vacuum energy for global AdS spacetime in odd dimensions. Because of this reason, we derive a Quantum Statistical Relation directly from the Euclidean action and not from the integration of the First Law of thermodynamics. To this end, we employ a background-independent regularization scheme which consists in the addition to the bulk action of counterterms that depend on both extrinsic and intrinsic curvatures of the boundary (Kounterterm series). This procedure results in a consistent inclusion of the vacuum energy and chemical potential in the thermodynamic description for Einstein-Gauss-Bonnet AdS gravity regardless the explicit form of the NED Lagrangian.Comment: 22 pages, no figures; 3 references and a subsection on Thermodynamic Charges added; Final version for PR

Topological regularization and self-duality in four-dimensional anti-de Sitter gravity

It is shown that the addition of a topological invariant (Gauss-Bonnet term) to the anti-de Sitter (AdS) gravity action in four dimensions recovers the standard regularization given by holographic renormalization procedure. This crucial step makes possible the inclusion of an odd parity invariant (Pontryagin term) whose coupling is fixed by demanding an asymptotic (anti) self-dual condition on the Weyl tensor. This argument allows to find the dual point of the theory where the holographic stress tensor is related to the boundary Cotton tensor as $T_{j}^{i}=\pm (\ell ^{2}/8\pi G)C_{j}^{i}$, which has been observed in recent literature in solitonic solutions and hydrodynamic models. A general procedure to generate the counterterm series for AdS gravity in any even dimension from the corresponding Euler term is also briefly discussed.Comment: 13 pages, no figures; enlarged discussion on self-duality condition for AAdS spacetimes, references added, final version for PR

EVALUATION OF THE ANTIOXIDANT ACTIVITY OF THE FLAVONOIDS ISOLATED FROM HELIOTROPIUM SINUATUM RESIN USING ORACFL, DPPH AND ESR METHODOLOGIES

Indexación: Web of Science; Scielo.The antioxidant capacity has been determined for a number of flavonoid compounds from Heliotropium sinuatum, a plant that grows in arid areas in the north of Chile. The methodologies used were: ORAC(FL) (oxygen radical absorbance capacity - fluorescein), DPPH (2,2-diphenyl-2-picrylhydrazyl) bleaching and electron spin resonance (ESR). These compounds were studied in homogeneous and heterogeneous media. The results showed that the 7-o-methyleriodictiol and 3-o-methylisorhamnetin are those with the highest antioxidant capacity.http://ref.scielo.org/m82cz

Vacuum energy in Einstein-Gauss-Bonnet AdS gravity

A finite action principle for Einstein-Gauss-Bonnet AdS gravity is presented. The boundary term, which is different for even and odd dimensions, is a functional of the boundary metric, intrinsic curvature and extrinsic curvature. For even dimensions, the boundary term corresponds to the maximal Chern form of the spacetime, and the asymptotic AdS condition for the curvature suffices for the well-posedness of this action. For odd dimensions, the action is stationary under a boundary condition on the variation of the extrinsic curvature. The background-independent Noether charges associated to asymptotic symmetries are found and the Euclidean continuation of the action correctly describes the black hole thermodynamics in the canonical ensemble. In particular, this procedure leads to a covariant formula for the vacuum energy in odd-dimensional asymptotically AdS spacetimes.Comment: RevTex, 5 pages, accepted for publication in PR

Thermodynamics of Large AdS Black Holes

We consider leading order quantum corrections to the geometry of large AdS black holes in a spherical reduction of four-dimensional Einstein gravity with negative cosmological constant. The Hawking temperature grows without bound with increasing black hole mass, yet the semiclassical back-reaction on the geometry is relatively mild, indicating that observers in free fall outside a large AdS black hole never see thermal radiation at the Hawking temperature. The positive specific heat of large AdS black holes is a statement about the dual gauge theory rather than an observable property on the gravity side. Implications for string thermodynamics with an AdS infrared regulator are briefly discussed.Comment: 17 pages, 1 figure, v2. added reference

Hamilton-Jacobi Counterterms for Einstein-Gauss-Bonnet Gravity

The on-shell gravitational action and the boundary stress tensor are essential ingredients in the study of black hole thermodynamics. We employ the Hamilton-Jacobi method to calculate the boundary counterterms necessary to remove the divergences and allow the study of the thermodynamics of Einstein-Gauss-Bonnet black holes.Comment: 21 pages, LaTe

Black strings in AdS_5

We present non-extremal magnetic black string solutions in five-dimensional gauged supergravity. The conformal infinity is the product of time and S^1xS_h, where S_h denotes a compact Riemann surface of genus h. The construction is based on both analytical and numerical techniques. We compute the holographic stress tensor, the Euclidean action and the conserved charges of the solutions and show that the latter satisfy a Smarr-type formula. The phase structure is determined in the canonical ensemble, and it is shown that there is a first order phase transition from small to large black strings, which disappears above a certain critical magnetic charge that is obtained numerically. For another particular value of the magnetic charge, that corresponds to a twisting of the dual super Yang-Mills theory, the conformal anomalies coming from the background curvature and those arising from the coupling to external gauge fields exactly cancel. We also obtain supersymmetric solutions describing waves propagating on extremal BPS magnetic black strings, and show that they possess a Siklos-Virasoro reparametrization invariance.Comment: 40 pages, 7 figures, JHEP3. v2: minor corrections, 2 references added. v3: typos in holographic stress tensor corrected, 3 references adde

Quenching of excited carbonyl triplets by benzene derivatives

Se ha medido la velocidad de desactivación de tripletes carbonilicos (biacetilo, bencilo, benzofenona y 4-metil-2-pentanona) por una serie d,e derivados del benceno. Los resultados pueden ser interpretados por un mecanismo de transferencia de carga. Los compuestos con hidrógenos lábiles (i.e.cumeno) muestran una mayor reactividad. La abstracción de hidrógeno ocurre desde el complejo de transferencia de carga. La desactivación del triplete de la 4-metil-2-pentanona fue medida entre - 5 y 70°C. Las energias de activación obtenidas variaron entre 8.1 kcal (para el cumeno) y 10 kcal (para el benceno)

S-Abscisic acid, 2-chloroethylphosphonic acid and indole-3-acetic acid treatments modify grape (Vitis vinifera L. 'Cabernet Sauvignon') hormonal balance and wine quality

The phenolic composition of red wine strongly determines its quality. Even when the applications of plant  growth regulator (PGR) affect grape quality, there is  almost no information on the effect of these treatments  on the grape’s internal hormonal balance and the wine  composition and quality. In the present study, changes in the internal hormonal content following the application of (+)-S-abscisic acid (S-ABA), 2-chloroethylphosphonic acid (CEPA) and indole-3-acetic acid (IAA) at veraison were examined to determine their effects on 'Cabernet Sauvignon' grapes and wine composition in a plants in containers experiment and in a commercial vineyard experiment. Applied PGRs had a significant effect on the hormonal balance and phenolic composition of grape skins. The S-ABA-treated grapes showed a significantly higher skin internal free abscisic acid concentration in the plants in container experiment and the CEPA-treated grapes showed a reduction in skin internal IAA concentration in the commercial vineyard experiment. Winemaking was performed in the commercial vineyard experiment. Wine’s chemical composition was affected by these treatments and an up-to 63 % increase in malvidin-3-glucoside concentration and an up-to 70 % increase in total tannin concentration were found in wines made from the CEPA-treated grapes. The alcohol content was 10.3 % higher (from 12.6 to 13.9 % v v-1) in wines made from the CEPA-treated grapes. No significant differences in the wine sensory attributes (aroma and mouth-feel) between the control and the PGR-treated wines were identified by a sensory panel.

Produtos químicos como desreguladores endócrinos: substâncias danosas e como devem ser testadas

This paper presents an analysis of the opinions of different groups from: scientists, international regulatory bodies, non-governmental organizations and industry; with an interest in the problem of identifying chemical substances with endocrine disrupting activity. There is also discussion of the consequences that exposure to endocrine disruptors may have for human health, considering concrete issues related to: the estimation of risk; the tests that must be used to detect endocrine disruption; the difficulties to establish an association between dose, time of exposure, individual susceptibility, and effect; and the attempts to create a census of endocrine disruptors. Finally, it is proposed that not all hormonal mimics should be included under the single generic denomination of endocrine disruptors.This work was supported by a 96/99 Research Project from the Health Department of the Andalusian Regional Government