Synergistic effect between hydrodynamic conditions during Ti anodization and acidic treatment on the photoelectric properties of TiO2 nanotubes

In the present work, the combined influence of controlled hydrodynamic conditions during Ti anodization and the acidic treatment with HClO4 on the photoelectric properties of mixed anatase/rutile TiO2 nanotubes has been studied. Anodized samples were analyzed by means of Field Emission Scanning Electronic Microscopy (FE-SEM), Confocal Raman Microscopy, electrochemical measurements (electrochemical impedance spectroscopy and Mott-Schottky analysis) and photoelectrochemical measurements. It has been observed that the use of hydrodynamic conditions increases the surface area of nanotubes, while acidic treatment enhances their conductivity. Besides, there is a clear synergistic effect between the hydrodynamic conditions and the acidic treatment, which results in higher photocurrent densities for the treated nanotubes formed under hydrodynamic conditions.Authors would like to express their gratitude for the financial support to the Ministerio of Economia y Competitividad (Project CTQ2013-42494-R).Sánchez Tovar, R.; Fernández Domene, RM.; Martinez Sanchez, A.; Blasco Tamarit, ME.; García-Antón, J. (2015). Synergistic effect between hydrodynamic conditions during Ti anodization and acidic treatment on the photoelectric properties of TiO2 nanotubes. Journal of Catalysis. 330:434-441. https://doi.org/10.1016/j.jcat.2015.08.002S43444133

Behavioral and psychological effects of coronavirus disease-19 quarantine in patients with dementia

Background: In March 2020, the World Health Organization declared a global pandemic due to the novel coronavirus SARS-CoV-2 and several governments planned a national quarantine in order to control the virus spread. Acute psychological effects of quarantine in frail elderly subjects with special needs, such as patients with dementia, have been poorly investigated. The aim of this study was to assess modifications of neuropsychiatric symptoms during quarantine in patients with dementia and their caregivers. Methods: This is a sub-study of a multicenter nation-wide survey. A structured telephone interview was delivered to family caregivers of patients with diagnosis of Alzheimer disease (AD), dementia with Lewy bodies (DLB), frontotemporal dementia (FTD), and vascular dementia (VD), followed regularly at 87 Italian memory clinics. Variations in behavioral and psychological symptoms (BPSD) were collected after 1 month since quarantine declaration and associations with disease type, severity, gender, and caregiver\u2019s stress burden were analyzed. Results: A total of 4,913 caregivers participated in the survey. Increased BPSD was reported in 59.6% of patients as worsening of preexisting symptoms (51.9%) or as new onset (26%), and requested drug modifications in 27.6% of these cases. Irritability, apathy, agitation, and anxiety were the most frequently reported worsening symptoms and sleep disorder and irritability the most frequent new symptoms. Profile of BPSD varied according to dementia type, disease severity, and patients\u2019 gender. Anxiety and depression were associated with a diagnosis of AD (OR 1.35, CI: 1.12\u20131.62), mild to moderate disease severity and female gender. DLB was significantly associated with a higher risk of worsening hallucinations (OR 5.29, CI 3.66\u20137.64) and sleep disorder (OR 1.69, CI 1.25\u20132.29), FTD with wandering (OR 1.62, CI 1.12\u20132.35), and change of appetite (OR 1.52, CI 1.03\u20132.25). Stress-related symptoms were experienced by two-thirds of caregivers and were associated with increased patients\u2019 neuropsychiatric burden (p<0.0001). Conclusion: Quarantine induces a rapid increase of BPSD in approximately 60% of patients and stress-related symptoms in two-thirds of caregivers. Health services need to plan a post-pandemic strategy in order to address these emerging needs

Changes to the Fossil Record of Insects through Fifteen Years of Discovery

The first and last occurrences of hexapod families in the fossil record are compiled from publications up to end-2009. The major features of these data are compared with those of previous datasets (1993 and 1994). About a third of families (>400) are new to the fossil record since 1994, over half of the earlier, existing families have experienced changes in their known stratigraphic range and only about ten percent have unchanged ranges. Despite these significant additions to knowledge, the broad pattern of described richness through time remains similar, with described richness increasing steadily through geological history and a shift in dominant taxa, from Palaeoptera and Polyneoptera to Paraneoptera and Holometabola, after the Palaeozoic. However, after detrending, described richness is not well correlated with the earlier datasets, indicating significant changes in shorter-term patterns. There is reduced Palaeozoic richness, peaking at a different time, and a less pronounced Permian decline. A pronounced Triassic peak and decline is shown, and the plateau from the mid Early Cretaceous to the end of the period remains, albeit at substantially higher richness compared to earlier datasets. Origination and extinction rates are broadly similar to before, with a broad decline in both through time but episodic peaks, including end-Permian turnover. Origination more consistently exceeds extinction compared to previous datasets and exceptions are mainly in the Palaeozoic. These changes suggest that some inferences about causal mechanisms in insect macroevolution are likely to differ as well

Bond slip model for generalized excitations

Correct evaluation for bond-slip effects is a crucial point when investigating progressive damage of reinforced concrete structures under random or earthquake excitations. For bridges, this aspect affects in particular the seismic response of piles' base and pier-deck joint in Integral Abutment Bridges as well. The need for a bond model, more accurate than those currently available in literature, without renouncing to ease of implementation, suggested to develop a new one. This model is defined by summing the effects of different bond resistance contributes (namely mechanical bond, friction bond and virgin bond) defined by means of continuous functions. This allows to fit, with reasonable precision, experimental monotonic and cyclic bond-slip paths, even along reloading branches. New relationships have been provided for updating the main law parameters at each load reversal. Moreover a specific progressive damage rule is introduced, able to account for generalized excitation. The proposed law has been validated by comparison with several existing pull-out cyclic data obtained from short-anchorage tests in good confinement conditions. © 2012 Taylor & Francis Group

Bridge structural optimization through step-by-step evolutionary process

In this paper, the structural optimization process aiming to reduce the weight of the superstructure of a five span arch bridge, built in the Province of Venice, Italy, and spanning the Piave River in the town of San Donà, is presented. The original project, with a pre-stressed concrete superstructure, was re-considered during construction because of the following two unexpected events. First, the approved new seismic national regulation became effective when the bridge was already partially built. As a result, existing foundations became unable to withstand the prescribed new seismic action. Furthermore, the Venice Water Authority, responsible for the management of the river spanned by the bridge, declared that erection phases without any provisional supports and scaffolding , resting on the riverbed, as foreseen by the original project, should be preferred. Between the two possible identified design strategies able to deal with the mentioned problems, namely, the strengthening of the foundations or the lightening of the superstructure, the second option was chosen, on the basis of engineering judgement concerning the simplification of construction procedures, timing and budget. The search for the lightest possible solution, with the restraint given by the approved aesthetics of the original design and the need of keeping within the former budget, brought to the conclusion that an evolutionary structural optimization (ESO) process could be suitably applied to a composite steel and concrete superstructure

Friction pendulum system as a retrofit technique for existing reinforced concrete building

Friction pendulum system (FPS) is one of the most effective base isolation systems, which is widely used for seismic upgrading of existing buildings. FPS is almost always non-linear and often strongly non-linear, so a mechanical model of FPS bearing is of great importance in seismic analysis. In this paper, three different models of FPS bearing are described and a building severely damaged by the L'Aquila earthquake in 2009 is examined according to the latest Italian code. Then, a case study presenting briefly an innovative technique that is able to introduce base isolation on existing buildings is provided with reference to the use of FPS. Different kinds of analyses, including response spectrum analysis and linear and non-linear dynamic analyses, are performed under the life-safety limit state. Storey shear, inter-storey drift, effective stiffness and energy dissipation are the considered parameters to investigate the effectiveness of the retrofitting procedure and analysis techniques