Redox and Catalytic Properties of Promoted NiO Catalysts for the Oxidative Dehydrogenation of Ethane

[EN] NiO and metal-promoted NiO catalysts (M-NiO, with a M/(M+Ni) atomic ratio of 0.08, with M = Nb, Sn, or La) have been prepared, tested in the oxidative dehydrogenation (ODH) of ethane, and characterized by means of XRD, TPR, HRTEM, Raman, XPS, and in situ XAS (using H-2/He, air or C2H6/He mixtures). The selectivity to ethylene during the ODH of ethane decreases according to the following trend: Nb NiO Sn NiO > La NiO > NiO, whereas the catalyst reducibility (determined by both TPR and XAS using H-2/He mixtures) shows the opposite trend. However, different reducibility and catalytic behavior in the absence of oxygen (ethane/He mixtures) have been observed, especially when comparing Nb- and Sn-promoted NiO samples. These differences can be ascribed mainly to a different phase distribution of the promoter. The results presented here are discussed in terms of the nature of active and selective sites for ODH of ethane in selective and unselective catalysts, but also the role of promoters and the importance of their phase distribution.The authors would like to acknowledge the DGICYT in Spain CTQ2012-37925-C03-2, CTQ2015-68951-C3-1-R, and CTQ2015-68951-C3-3-R. Authors thank European Synchrotron Radiation Facility, ESRF (Project CH-4512; BM25-SpLine Beamlime). Authors from ITQ also thank Project SEV-2016-0683 for financial support. D.D. thanks MINECO and Severo Ochoa Excellence Program for his fellowship (SVP-2014-068669). B.S. also thanks UV-INV-AE16-484416. Finally, the authors thank the Electron Microscopy Service of Universitat Politecnica de Valencia for their support.Delgado-Muñoz, D.; Solsona Espriu, BE.; Ykrelef, A.; Rodriguez-Gomez, A.; Caballero, A.; Rodríguez-Aguado, E.; Rodriguez-Castellón, E.... (2017). Redox and Catalytic Properties of Promoted NiO Catalysts for the Oxidative Dehydrogenation of Ethane. The Journal of Physical Chemistry C. 121(45):25132-25142. https://doi.org/10.1021/acs.jpcc.7b07066S25132251421214

Plan de trabajo Arrendadora ProParking, S. de R.L de C.V Investigación de Mercado Paralelo en China

El proyecto PAP elaborado para la empresa Arrendadora Pro-Parking S. de R.L de C.V. plantea realizar una investigación en mercados internacionales de donde surge el interés por un mercado particular, o mejor dicho un régimen preferencial para la importación de automóviles nuevos a China llamado “Parallel imports” de donde emana el know how el trabajo y a donde se vio dirigido todo el esfuerzo. Para ello, se investigará con especialistas en el rubro, que puedan proporcionar información que no está escrita en la Web, periódico o en libros. Esta afirmación surge de un constante freno en la búsqueda de información sensible del país destino (China). Creemos, con ello, obtener Información pertinente que nos dé la pauta para que ProParking pueda comenzar a exportar vehículos a este mercado, a la vez tratar de eliminar intermediarios y crear un flujo de efectivo más sano y rentable para la empresa y quienes están involucrados.ITESO, A.C

First simultaneous multi-wavelength observations of the black hole candidate IGR J17091-3624: ATCA, INTEGRAL, Swift, and RXTE views of the 2011 outburst

We present the results of the first four (quasi-)simultaneous radio (ATCA), X-ray (Swift, RXTE), and Gamma-ray (INTEGRAL) observations of the black hole candidate IGR J17091-3624, performed in February and March 2011. The X-ray analysis shows that the source was in the hard state, and then it transited to a soft intermediate state. We study the correlated radio/X-ray behaviour of this source for the first time. The radio counterpart to IGR J17091-3624 was detected during all four observations with the ATCA. In the hard state, the radio spectrum is typical of optically thick synchrotron emission from a self-absorbed compact jet. In the soft intermediate state, the detection of optically thin synchrotron emission is probably due to a discrete ejection event associated with the state transition. The position of IGR J17091-3624 in the radio versus X-ray luminosity diagram (aka fundamental plane) is compatible with that of the other black hole sources for distances greater than 11 kpc. IGR J17091-3624 also appears as a new member of the few sources that show a strong quenching of radio emission after the state transition. Using the estimated luminosity at the spectral transition from the hard state, and for a typical mass of 10 M_sun, we estimate a distance to the source between ~11 and ~17 kpc, compatible with the radio behaviour of the source.Comment: 6 pages, 4 figures, 1 online table, accepted for publication in A&

Spectroscopic ellipsometry study of Cu2ZnSnS4 bulk poly-crystals

The linear optical properties of Cu2ZnSnS4 bulk poly-crystals have been investigated using spectroscopic ellipsometry in the range of 1.2-4.6 eV at room temperature. The characteristic features identified in the optical spectra are explained by using the Adachi analytical model for the interband transitions at the corresponding critical points in the Brillouin zone. The experimental data have been modeled over the entire spectral range taking into account the lowest E0 transition near the fundamental absorption edge and E1A and E1B higher energy interband transitions. In addition, the spectral dependences of the refractive index, extinction coefficient, absorption coefficient, and normal-incidence reflectivity values have been accurately determined and are provided since they are essential data for the design of Cu2ZnSnS4 based optoelectronic devicesThe research leading to the presented results was partially supported by the European Project INFINITE-CELL (Ref. H2020-MSCA-RISE-2017-777968, 2017–2021, www.infinitecell.eu) and the Spanish MINECO Projects “WINCOST” (ENE2016-80788-C5-2-R) and PHOTOMANA (TEC2015- 69916-C2-1-R). The authors from the Institute of Applied Physics appreciate the financial support from STCU 6224 and from the Institutional Project No. CSSDT 15.817.02.04

Hard X-ray spectral variability of the brightest Seyfert AGN in the Swift/BAT sample

Aims: We used data from the 58 month long, continuous Swift/Burst Alert Telescope (BAT) observations of the five brightest Seyfert galaxies at hard X-rays, to study their flux and spectral variability in the 20-100 keV energy band. The column density in these objects is less than 10^24 cm-2, which implies that the Swift/BAT data allow us to study the "true" variability of the central source. Results: All objects show significant variations, with an amplitude which is similar to the AGN variability amplitude at energies below 10 keV. We found evidence for an anti-correlation between variability amplitude and black hole mass. The light curves in both bands are well correlated, with no significant delays on time scales as short as 2 days. NGC 4151 and NGC 2110 do not show spectral variability, but we found a significant anti-correlation between hardness ratios and source flux in NGC 4388 (and NGC 4945, IC 4329, to a lesser extent). This "softer when brighter" behaviour is similar to what has been observed at energies below 10 keV, and cannot be explained if the continuum varies only in flux; the intrinsic shape should also steepen with increasing flux. Conclusions: The presence of significant flux variations indicate that the central source in these objects is intrinsically variable on time scales as short as 1-2 days. The intrinsic slope of the continuum varies with the flux (at least in NGC 4388). The positive "spectral slope-flux" correlation can be explained if the temperature of the hot corona decreases with increasing flux. The lack of spectral variations in two objects, could be due to the fact that they may operate in a different "state", as their accretion rate is less than 1% of the Eddington limit (significantly smaller than the rate of the other three objects in the sample).Comment: Accepted (29/10/11) for publication in A&A (12 pages, containing 14 figures and 2 tables). (Abstract shortened --see link for the complete one

Prognostic ability of EndoPredict compared to research-based versions of the PAM50 risk of recurrence (ROR) scores in node-positive, estrogen receptor-positive, and HER2-negative breast cancer. A GEICAM/9906 sub-study

There are several prognostic multigene-based tests for managing breast cancer (BC), but limited data comparing them in the same cohort. We compared the prognostic performance of the EndoPredict (EP) test (standardized for pathology laboratory) with the research-based PAM50 non-standardized qRT-PCR assay in node-positive estrogen receptor-positive (ER+) and HER2-negative (HER2−) BC patients receiving adjuvant chemotherapy followed by endocrine therapy (ET) in the GEICAM/9906 trial. EP and PAM50 risk of recurrence (ROR) scores [based on subtype (ROR-S) and on subtype and proliferation (ROR-P)] were compared in 536 ER+/HER2− patients. Scores combined with clinical information were evaluated: ROR-T (ROR-S, tumor size), ROR-PT (ROR-P, tumor size), and EPclin (EP, tumor size, nodal status). Patients were assigned to risk-categories according to prespecified cutoffs. Distant metastasis-free survival (MFS) was analyzed by Kaplan–Meier. ROR-S, ROR-P, and EP scores identified a low-risk group with a relative better outcome (10-year MFS: ROR-S 87%; ROR-P 89%; EP 93%). There was no significant difference between tests. Predictors including clinical information showed superior prognostic performance compared to molecular scores alone (10-year MFS, low-risk group: ROR-T 88%; ROR-PT 92%; EPclin 100%). The EPclin-based risk stratification achieved a significantly improved prediction of MFS compared to ROR-T, but not ROR-PT. All signatures added prognostic information to common clinical parameters. EPclin provided independent prognostic information beyond ROR-T and ROR-PT. ROR and EP can reliably predict risk of distant metastasis in node-positive ER+/HER2− BC patients treated with chemotherapy and ET. Addition of clinical parameters into risk scores improves their prognostic ability.Electronic supplementary materialThe online version of this article (doi:10.1007/s10549-016-3725-z) contains supplementary material, which is available to authorized users

Use of sonic tomography to detect and quantify wood decay in living trees.

Premise of the studyField methodology and image analysis protocols using acoustic tomography were developed and evaluated as a tool to estimate the amount of internal decay and damage of living trees, with special attention to tropical rainforest trees with irregular trunk shapes.Methods and resultsLiving trunks of a diversity of tree species in tropical rainforests in the Republic of Panama were scanned using an Argus Electronic PiCUS 3 Sonic Tomograph and evaluated for the amount and patterns of internal decay. A protocol using ImageJ analysis software was used to quantify the proportions of intact and compromised wood. The protocols provide replicable estimates of internal decay and cavities for trees of varying shapes, wood density, and bark thickness.ConclusionsSonic tomography, coupled with image analysis, provides an efficient, noninvasive approach to evaluate decay patterns and structural integrity of even irregularly shaped living trees

Extreme Starbursts in the Local Universe

The "Extreme starbursts in the local universe" workshop was held at the Insituto de Astrofisica de Andalucia in Granada, Spain on 21-25 June 2010. Bearing in mind the advent of a new generation of facilities such as JWST, Herschel, ALMA, eVLA and eMerlin, the aim of the workshop was to bring together observers and theorists to review the latest results. The purpose of the workshop was to address the following issues: what are the main modes of triggering extreme starbursts in the local Universe? How efficiently are stars formed in extreme starbursts? What are the star formation histories of local starburst galaxies? How well do the theoretical simulations model the observations? What can we learn about starbursts in the distant Universe through studies of their local counterparts? How important is the role of extreme starbursts in the hierarchical assembly of galaxies? How are extreme starbursts related to the triggering of AGN in the nuclei of galaxies? Overall, 41 talks and 4 posters with their corresponding 10 minutes short talks were presented during the workshop. In addition, the workshop was designed with emphasis on discussions, and therefore, there were 6 discussion sessions of up to one hour during the workshop. Here is presented a summary of the purposes of the workshop as well as a compilation of the abstracts corresponding to each of the presentations. The summary and conclusions of the workshop along with a description of the future prospects by Sylvain Veilleux can be found in the last section of this document. A photo of the assistants is included.Comment: worksho