Dynamics of Excited State Proton Transfer in Nitro Substituted 10-Hydroxybenzo[h]quinolines

Barrierless proton transfer in HBQ and a barrier upon nitro substitution.</p

Timing of a Young Mildly Recycled Pulsar with a Massive White Dwarf Companion

We report on timing observations of the recently discovered binary pulsar PSR J1952+2630 using the Arecibo Observatory. The mildly recycled 20.7-ms pulsar is in a 9.4-hr orbit with a massive, M_WD > 0.93 M_sun, white dwarf (WD) companion. We present, for the first time, a phase-coherent timing solution, with precise spin, astrometric, and Keplerian orbital parameters. This shows that the characteristic age of PSR J1952+2630 is 77 Myr, younger by one order of magnitude than any other recycled pulsar-massive WD system. We derive an upper limit on the true age of the system of 50 Myr. We investigate the formation of PSR J1952+2630 using detailed modelling of the mass-transfer process from a naked helium star on to the neutron star following a common-envelope phase (Case BB Roche-lobe overflow). From our modelling of the progenitor system, we constrain the accretion efficiency of the neutron star, which suggests a value between 100 and 300% of the Eddington accretion limit. We present numerical models of the chemical structure of a possible oxygen-neon-magnesium WD companion. Furthermore, we calculate the past and the future spin evolution of PSR J1952+2630, until the system merges in about 3.4 Gyr due to gravitational wave emission. Although we detect no relativistic effects in our timing analysis we show that several such effects will become measurable with continued observations over the next 10 years; thus PSR J1952+2630 has potential as a testbed for gravitational theories.Comment: 12 pages, 10 figures, to be published in MNRA

A concept for stimulated proton transfer in 1-(phenyldiazenyl)naphthalen-2-ols

A series of aryl azo derivatives of naphthols (1–3) were studied by means of UV–Vis and NMR spectroscopy in different solvents as well as by quantum chemical calculations and X-ray analysis. Previous studies have shown that Sudan I (1) exists as a tautomeric mixture. The effect of the solvents is minimized by the existing intramolecular hydrogen bond. Therefore, the influence on the tautomeric state in structurally modified 1 has been investigated. Structure 2 contains an additional OH- group, which deprotonates easily and affects the position of the tautomeric equilibrium by changing the electronic properties of the substituent. The implementation of a sidearm in 3 creates a condition for competition between the nitrogen from the azo group and from the piperidine unit for the tautomeric proton. In this case the use of acid as a stimulus for controlling the tautomeric process was achieved

Timing of a Young Mildly Recycled Pulsar with a Massive White Dwarf Companion

We report on timing observations of the recently discovered binary pulsar PSR J1952+2630 using the Arecibo Observatory. The mildly recycled 20.7-ms pulsar is in a 9.4-hr orbit with a massive, M_WD > 0.93 M_sun, white dwarf (WD) companion. We present, for the first time, a phase-coherent timing solution, with precise spin, astrometric, and Keplerian orbital parameters. This shows that the characteristic age of PSR J1952+2630 is 77 Myr, younger by one order of magnitude than any other recycled pulsar-massive WD system. We derive an upper limit on the true age of the system of 50 Myr. We investigate the formation of PSR J1952+2630 using detailed modelling of the mass-transfer process from a naked helium star on to the neutron star following a common-envelope phase (Case BB Roche-lobe overflow). From our modelling of the progenitor system, we constrain the accretion efficiency of the neutron star, which suggests a value between 100 and 300% of the Eddington accretion limit. We present numerical models of the chemical structure of a possible oxygen-neon-magnesium WD companion. Furthermore, we calculate the past and the future spin evolution of PSR J1952+2630, until the system merges in about 3.4 Gyr due to gravitational wave emission. Although we detect no relativistic effects in our timing analysis we show that several such effects will become measurable with continued observations over the next 10 years; thus PSR J1952+2630 has potential as a testbed for gravitational theories

How strange are compact star interiors ?

We discuss a Nambu--Jona-Lasinio (NJL) type quantum field theoretical approach to the quark matter equation of state with color superconductivity and construct hybrid star models on this basis. It has recently been demonstrated that with increasing baryon density, the different quark flavors may occur sequentially, starting with down-quarks only, before the second light quark flavor and at highest densities also the strange quark flavor appears. We find that color superconducting phases are favorable over non-superconducting ones which entails consequences for thermodynamic and transport properties of hybrid star matter. In particular, for NJL-type models no strange quark matter phases can occur in compact star interiors due to mechanical instability against gravitational collapse, unless a sufficiently strong flavor mixing as provided by the Kobayashi-Maskawa-'t Hooft determinant interaction is present in the model. We discuss observational data on mass-radius relationships of compact stars which can put constraints on the properties of dense matter equation of state.Comment: 7 pages, 2 figures, to appear in the Proceedings of the International Conference SQM2009, Buzios, Rio de Janeiro, Brazil, Sep.27-Oct.2, 200

The repeating Fast Radio Burst FRB 121102: Multi-wavelength observations and additional bursts

We report on radio and X-ray observations of the only known repeating Fast Radio Burst (FRB) source, FRB 121102. We have detected six additional radio bursts from this source: five with the Green Bank Telescope at 2 GHz, and one at 1.4 GHz at the Arecibo Observatory for a total of 17 bursts from this source. All have dispersion measures consistent with a single value ($\sim559$ pc cm$^{-3}$) that is three times the predicted maximum Galactic value. The 2-GHz bursts have highly variable spectra like those at 1.4 GHz, indicating that the frequency structure seen across the individual 1.4 and 2-GHz bandpasses is part of a wideband process. X-ray observations of the FRB 121102 field with the Swift and Chandra observatories show at least one possible counterpart; however, the probability of chance superposition is high. A radio imaging observation of the field with the Jansky Very Large Array at 1.6 GHz yields a 5$\sigma$ upper limit of 0.3 mJy on any point-source continuum emission. This upper limit, combined with archival WISE 22-$\mu$m and IPHAS H$\alpha$ surveys, rules out the presence of an intervening Galactic HII region. We update our estimate of the FRB detection rate in the PALFA survey to be 1.1$^{+3.7}_{-1.0} \times 10^4$ FRBs sky$^{-1}$ day$^{-1}$ (95% confidence) for peak flux density at 1.4 GHz above 300 mJy. We find that the intrinsic widths of the 12 FRB 121102 bursts from Arecibo are, on average, significantly longer than the intrinsic widths of the 13 single-component FRBs detected with the Parkes telescope.Comment: 18 pages, 5 figures. Accepted for publication in Ap

An Eccentric Binary Millisecond Pulsar in the Galactic Plane

Binary pulsar systems are superb probes of stellar and binary evolution and the physics of extreme environments. In a survey with the Arecibo telescope, we have found PSR J1903+0327, a radio pulsar with a rotational period of 2.15 ms in a highly eccentric (e = 0.44) 95-day orbit around a solar mass companion. Infrared observations identify a possible main-sequence companion star. Conventional binary stellar evolution models predict neither large orbital eccentricities nor main-sequence companions around millisecond pulsars. Alternative formation scenarios involve recycling a neutron star in a globular cluster then ejecting it into the Galactic disk or membership in a hierarchical triple system. A relativistic analysis of timing observations of the pulsar finds its mass to be 1.74+/-0.04 Msun, an unusually high value.Comment: 28 pages, 4 figures inc Supplementary On-Line Material. Accepted for publication in Science, published on Science Express: 10.1126/science.115758

The PALFA Survey: Going to great depths to find radio pulsars

The on-going PALFA survey is searching the Galactic plane (|b| < 5 deg., 32 < l < 77 deg. and 168 < l < 214 deg.) for radio pulsars at 1.4 GHz using ALFA, the 7-beam receiver installed at the Arecibo Observatory. By the end of August 2012, the PALFA survey has discovered 100 pulsars, including 17 millisecond pulsars (P < 30 ms). Many of these discoveries are among the pulsars with the largest DM/P ratios, proving that the PALFA survey is capable of probing the Galactic plane for millisecond pulsars to a much greater depth than any previous survey. This is due to the survey's high sensitivity, relatively high observing frequency, and its high time and frequency resolution. Recently the rate of discoveries has increased, due to a new more sensitive spectrometer, two updated complementary search pipelines, the development of online collaborative tools, and access to new computing resources. Looking forward, focus has shifted to the application of artificial intelligence systems to identify pulsar-like candidates, and the development of an improved full-resolution pipeline incorporating more sophisticated radio interference rejection. The new pipeline will be used in a complete second analysis of data already taken, and will be applied to future survey observations. An overview of recent developments, and highlights of exciting discoveries will be presented.Comment: Proceedings of IAUS 291 "Neutron Stars and Pulsars: Challenges and Opportunities after 80 years", J. van Leeuwen (ed.); 6 pages, 4 figure

Arecibo Pulsar Survey Using ALFA. I. Survey Strategy and First Discoveries

We report results from the initial stage of a long-term pulsar survey of the Galactic plane using the Arecibo L-band Feed Array (ALFA), a seven-beam receiver operating at 1.4 GHz with 0.3 GHz bandwidth. The search targets Galactic latitudes |b| < 5 deg in the longitude ranges 32 deg < l < 77 deg and 168 deg < l < 77 deg. Data discussed here were collected over a 100 MHz passband centered on 1.42 GHz using a spectrometer that recorded 256 channels every 64 microsec. In a preliminary, standard period-DM analysis, we have detected 29 previously known pulsars and discovered 11 new ones. One of these, with a period of 69 ms and a low characteristic age of 82 kyr, is a plausible candidate for association with the unidentified EGRET source 3EG J1928+1733. Another is a non-recycled pulsar in a relativistic binary with orbital period of 3.98 hr. We also search the data for isolated dispersed pulses, a technique that yielded discovery of an extremely sporadic radio emitter with a spin period of 1.2 s. Simulations we have carried out indicate that about 1000 new pulsars will be found in the ALFA survey. In addition to providing a large sample for use in population analyses and for probing the magnetoionic interstellar medium, the survey maximizes the chances of finding rapidly spinning millisecond pulsars and pulsars in compact binary systems. Our search algorithms will exploit the multiple data streams from ALFA to discriminate between radio frequency interference and celestial signals, including pulsars and possibly new classes of transient radio sources.Comment: 10 pp, 9 figures, accepted by the Astrophysical Journa

PSR J1856+0245: Arecibo Discovery of a Young, Energetic Pulsar Coincident with the TeV Gamma-ray Source HESS J1857+026

We present the discovery of the Vela-like radio pulsar J1856+0245 in the Arecibo PALFA survey. PSR J1856+0245 has a spin period of 81ms, a characteristic age of 21kyr, and a spin-down luminosity Edot = 4.6 x 10^36 ergs/s. It is positionally coincident with the TeV gamma-ray source HESS J1857+026, which has no other known counterparts. Young, energetic pulsars create wind nebulae, and more than a dozen pulsar wind nebulae have been associated with very-high-energy (100GeV-100TeV) gamma-ray sources discovered with the HESS telescope. The gamma-ray emission seen from HESS J1857+026 is potentially produced by a pulsar wind nebula powered by PSR J1856+0245; faint X-ray emission detected by ASCA at the pulsar's position supports this hypothesis. The inferred gamma-ray efficiency is epsilon_gamma = L_gamma/Edot = 3.1% (1-10TeV, for a distance of 9kpc), comparable to that observed in similar associations.Comment: 13 pages, 1 figure, accepted for publication in The Astrophysical Journal Letter