Prediction of runoff and discharge in the Simiyu River (tributary of Lake Victoria, Tanzania) using the WetSpa model

International audienceA spatially distributed hydrologic model (WetSpa) is used to estimate daily river water discharge in the Simiyu river a tributary of Lake Victoria, Tanzania. The model combines topography, landuse and soil maps, and observed daily meteorological time series to predict discharge hydrographs and the spatial distribution of hydrological parameters in the catchment. The elevations in the catchment range from 2000 to 1100 m at the outlet, with average slope of 1.4%. The dominant landuse types are, wasteland, grassland, bushland, cultivated land, and a very small area is covered by surface water. The dominant soil types are sandy loam, followed by sandy clay loam, clay loam, clay, loam and sandy clay. There are two distinctive seasons in the Simiyu catchment. Short rains mainly in November, December and January, and long rains in March to May, resulting in a total average annual precipitation of 700 to 1000 mm. The annual potential evapotranspiration is about 1300 mm, and the river discharge at the catchment outlet ranges from 0 to about 200 m3/s. Global parameters of the model are calibrated using three years of daily observed discharge values measured at the mouth of the river at Lake Victoria. The estimated average travel time of the runoff to the outlet of the catchment is about 2.4 d and maximum 8 d for the most remote areas. The model results also show that the surface runoff and interflow provide respectively 38.6% and 61.4% of the total runoff, while the contribution of groundwater drainage is nil. The absence of groundwater drainage is probably due to the high evaporation demand of the atmosphere, which accounts for about 90% of the total precipitation being lost by evapotranspiration. The annual water balance estimated with the model reveals that the total outflow to Lake Victoria is about 500×106 m3 per year, which occurs mainly in the wet seasons, i.e. from March to May and from November to January. The volume of runoff produced by agricultural land amounts to about 9% of the total runoff annually

Simulation of hydrological processes in the Simiyu River, tributary of Lake Victoria, Tanzania

A spatially-distributed hydrologic model (WetSpa) is used to simulate hydrologic processes in the Simiyu River, a tributary of Lake Victoria, Tanzania. The model combines digital maps of topography, land-use and soil texture with observed daily meteorological time series to predict discharge hydrographs and spatial distribution of hydrologic parameters in the basin. The model was calibrated using 3 years of daily observed discharge measured at the mouth of the river at Lake Victoria. The estimated average travel time of the runoff to the outlet of the basin is about 2.4 days and a maximum of 8 days for the most remote areas. The model results show that the surface runoff and interflow provide, respectively, 38.6% and 61.4% of the total discharge, while the contribution of groundwater drainage is about nil. The absence of groundwater drainage is likely due to the high evaporative demand of the atmosphere, which accounts for about 90% of the total precipitation being lost by evapotranspiration. The annual water balance estimated with the model reveals that the total outflow to Lake Victoria is about 475 x 106 m3 per year, which occurs mainly in the wet seasons, i.e. from March to May and from November to January. The discharge volume produced by agricultural land amounts to about 43 x 106 m3 and may carry agrochemicals to Lake Victoria

Post-AGB stars in the Magellanic Clouds and neutron-capture processes in AGB stars

We explore modifications to the current scenario for the slow neutron capture process in asymptotic giant branch (AGB) stars to account for the Pb deficiency observed in post-AGB stars of low metallicity ([Fe/H] ~ -1.2) and low initial mass (~ 1 - 1.5 Msun) in the Large and Small Magellanic Clouds. We calculated the stellar evolution and nucleosynthesis for a 1.3 Msun star with [Fe/H]=-1.3 and tested different amounts and distributions of protons leading to the production of the main neutron source within the 13C-pocket and proton ingestion scenarios. No s-process models can fully reproduce the abundance patterns observed in the post-AGB stars. When the Pb production is lowered the abundances of the elements between Eu and Pb, such as Er, Yb, W, and Hf, are also lowered to below those observed. Neutron-capture processes with neutron densities intermediate between the s and the rapid neutron-capture processes may provide a solution to this problem and be a common occurrence in low-mass, low-metallicity AGB stars.Comment: 6 pages, 4 figures. To be published in Astronomy and Astrophysic

Removal of pesticides from aqueous solutions by adsorption on zeolites as solid adsorbents

To prevent the contamination of groundwater and surface water by pesticides, appropriate measures should be taken to treat the contaminated water before discharge. Zeolites seem to be a promising material to adsorb pesticides. This paper deals with the removal of mobile pesticides from water on different types of zeolites. Experiments were performed to understand the adsorption mechanisms of bentazon, clopyralid, imidacloprid, isoproturon and metalaxyl-m on zeolites and to determine the most efficient adsorbent for the purification of water contaminated by these pesticides. More immobile pesticides (imidacloprid, isoproturon and metalaxyl-m) tended to associate with the zeolites, whereas more mobile pesticides (bentazon and clopyralid) partitioned in water. According to the adsorption percentage, zeolite of the types BEA and FAU showed the best results for adsorbing the pesticides. Two different kinetic models, namely, pseudo-first-order and pseudo-second-order models, were used to fit the kinetics data. The experimental data were best described by the pseudo-second-order model. The rate of adsorption was also in line with the mobility of the pesticides. The adsorption isotherms were determined and modelled based on the observed types according to International Union of Pure and Applied Chemistry. The type III isotherm was most frequently observed in this case. The Freundlich model, which describes this type of isotherm, gave a good fit for the adsorption of the pesticides. Different assumptions, that could describe the meaning of these type III isotherms, are discussed in this paper. These assumptions are based on the particle size of the adsorbates, the water adsorption on the zeolites and the modifications of the crystal structures

Aurora Credit Services, a Minnesota corporation, on behalf of itself and all other shareholders of Liberty West Development, a corporation, v. Liberty West Development, a Utah corporation, XM INTERNATIONAL, a Utah limited liability company, and DENNIS W. GAY, an individual : Reply Brief

APPEAL COURT FROM JUDGMENT OF IN AND FOR JUDGE L. SALT THIRD LAKE A. DEVER DISTRICT COUNTY

Photopolymerized thermosensitive poly(HPMAlactate)-PEG-based hydrogels : effect of network design on mechanical properties, degradation, and release behavior

Photopolymerized thermosensitive A-B-A triblock copolymer hydrogels composed of poly(N-(2-hydroxypropyl)-methacrylamide lactate) A-blocks, partly derivatizal with methacrylate groups to different extents (10, 20, and 30%) and hydrophilic poly(ethylene glycol) B-blocks of different molecular weights (4, 10, and 20 kDa) were synthesized. The aim of the present study was to correlate the polymer architecture with the hydrogel properties, particularly rheological, swelling, degradation properties and release behavior. It was found that an increasing methacrylation extent and a decreasing PEG molecular weight resulted in increasing gel strength and cross-link density, which tailored the degradation profiles from 25 to more than 300 days. Polymers having small PEG blocks showed a remarkable phase separation into polymer- and water-rich domains, as demonstrated by confocal microscopy. Depending on the hydrophobic domain density, the loaded protein resides in the hydrophilic pores or is partitioned into hydrophilic and hydrophobic domains, and its release from these compartments is tailored by the extent of methacrylation and by PEG length, respectively. As the mechanical properties, degradation, and release profiles can be fully controlled by polymer design and concentration, these hydrogels are suitable for controlled protein release

Study of cavernous underground conduits in Nam La (Northwest Vietnam) by an integrative approach

This paper presents the result of an investigation of underground conduits, which connect the swallow holes and the resurgence of a blind river in the tropical, highly karstified limestone Nam La catchment in the NW of Vietnam. The Nam La River disappears underground in several swallow holes near the outlet of the catchment. In the rainy season this results in flooding upstream of the sinkholes. A hypothesis is that the Nam La River resurges at a large cavern spring 4.5 km east of the catchment outlet. A multi-thematic study of the possible connections between the swallow holes and the resurgence was carried out to investigate the geological structure, tectonics, cave structure analysis and discharge time series. The existence of the underground conduits was also tested and proven by tracer experiments. On the basis of a lineament analysis the location of the underground conduits were predicted. A remote sensing derived lineament-length density map was used to track routes from the swallow holes to the resurgence, having the shortest length but highest lineament density. This resulted in a plan-view prediction of underground conduits that matches with the cave and fault development. The functioning of the conduits was further explained by analysing flooding records of a nearby doline, which turns out to act as a temporary storage reservoir mitigating flooding of the catchment outlet area

Unveiling the prehistoric landscape at Stonehenge through multi-receiver EMI

YesArchaeological research at Stonehenge (UK) is increasingly aimed at understanding the dynamic of the wider archaeological landscape. Through the application of state-of-the-art geophysical techniques, unprecedented insight is being gathered into the buried archaeological features of the area. However, applied survey techniques have rarely targeted natural soil variation, and the detailed knowledge of the palaeotopography is consequently less complete. In addition, metallic topsoil debris, scattered over different parts of the Stonehenge landscape, often impacts the interpretation of geophysical datasets. The research presented here demonstrates how a single multi-receiver electromagnetic induction (EMI) survey, conducted over a 22 ha area within the Stonehenge landscape, offers detailed insight into natural and anthropogenic soil variation at Stonehenge. The soil variations that were detected through recording the electrical and magnetic soil variability, shed light on the genesis of the landscape, and allow for a better definition of potential palaeoenvironmental and archaeological sampling locations. Based on the multi-layered dataset, a procedure was developed to remove the influence of topsoil metal from the survey data, which enabled a more straightforward identification of the detected archaeology. The results provide a robust basis for further geoarchaeological research, while potential to differentiate between modern soil disturbances and the underlying sub-surface variations can help in solving conservation and management issues. Through expanding this approach over the wider area, we aim at a fuller understanding of the human–landscape interactions that have shaped the Stonehenge landscape

Effect of native gastric mucus on in vivo hybridization therapies directed at Helicobacter pylori

Helicobacter pylori infects more than 50% of the worldwide population. It is mostly found deep in the gastric mucus lining of the stomach, being a major cause of peptic ulcers and gastric adenocarcinoma. To face the increasing resistance of H. pylori to antibiotics, antimicrobial nucleic acid mimics are a promising alternative. In particular, locked nucleic acids (LNA)/2'-OMethyl RNA (2'OMe) have shown to specifically target H. pylori, as evidenced by in situ hybridization. The success of in vivo hybridization depends on the ability of these nucleic acids to penetrate the major physical barriers-the highly viscoelastic gastric mucus and the bacterial cell envelope. We found that LNA/2'OMe is capable of diffusing rapidly through native, undiluted, gastric mucus isolated from porcine stomachs, without degradation. Moreover, although LNA/2'OMe hybridization was still successful without permeabilization and fixation of the bacteria, which is normally part of in vitro studies, the ability of LNA/2'OMe to efficiently hybridize with H. pylori was hampered by the presence of mucus. Future research should focus on developing nanocarriers that shield LNA/2'OMe from components in the gastric mucus, while remaining capable of diffusing through the mucus and delivering these nucleic acid mimics directly into the bacteria