Chemical composition and radiative properties of nascent particulate matter emitted by an aircraft turbofan burning conventional and alternative fuels

Aircraft engines are a unique source of carbonaceous aerosols in the upper troposphere. There, these particles can more efficiently interact with solar radiation than at ground. Due to the lack of measurement data, the radiative forcing from aircraft exhaust aerosol remains uncertain. To better estimate the global radiative effects of aircraft exhaust aerosol, its optical properties need to be comprehensively characterized. In this work we present the link between the chemical composition and the optical properties of the particulate matter (PM) measured at the engine exit plane of a CFM56-7B turbofan. The measurements covered a wide range of power settings (thrust), ranging from ground idle to take-off, using four different fuel blends of conventional Jet A-1 and hydro-processed ester and fatty acids (HEFA) biofuel. At the two measurement wavelengths (532 and 870 nm) and for all tested fuels, the absorption and scattering coefficients increased with thrust, as did the PM mass. The analysis of elemental carbon (EC) and organic carbon (OC) revealed a significant mass fraction of OC (up to 90 %) at low thrust levels, while EC mass dominated at medium and high thrust. The use of HEFA blends induced a significant decrease in the PM mass and the optical coefficients at all thrust levels. The HEFA effect was highest at low thrust levels, where the EC mass was reduced by up to 50 %–60 %. The variability in the chemical composition of the particles was the main reason for the strong thrust dependency of the single scattering albedo (SSA), which followed the same trend as the fraction of OC to total carbon (TC). Mass absorption coefficients (MACs) were determined from the correlations between aerosol light absorption and EC mass concentration. The obtained MAC values (MAC532=7.5±0.3 m2 g−1 and MAC870=5.2±0.9 m2 g−1) are in excellent agreement with previous literature values of absorption cross section for freshly generated soot. While the MAC values were found to be independent of the thrust level and fuel type, the mass scattering coefficients (MSCs) significantly varied with thrust. For cruise conditions we obtained MSC532=4.5±0.4 m2 g−1 and MSC870=0.54±0.04 m2 g−1, which fall within the higher end of MSCs measured for fresh biomass smoke. However, the latter comparison is limited by the strong dependency of MSC on the particles' size, morphology and chemical composition. The use of the HEFA fuel blends significantly decreased PM emissions, but no changes were observed in terms of EC∕OC composition and radiative properties

Gender, Depression, and Blue-collar Work: A Retrospective Cohort Study of US Aluminum Manufacturers.

BACKGROUND: Industrial blue-collar workers face multiple work-related stressors, but evidence regarding the burden of mental illness among today's blue-collar men and women remains limited. METHODS: In this retrospective cohort study, we examined health and employment records for 37,183 blue- and white-collar workers employed by a single US aluminum manufacturer from 2003 to 2013. Using Cox proportional hazards regression, we modeled time to first episode of treated depression by gender and occupational class. Among cases, we modeled rates of depression-related service utilization with generalized gamma regression. RESULTS: Compared with their white-collar counterparts, blue-collar men were more likely to be treated for depression (hazard ratio [HR] = 1.3; 95% confidence interval [CI] = 1.1, 1.4) as were blue-collar women (HR = 1.4; 1.2, 1.6). Blue-collar women were most likely to be treated for depression as compared with white-collar men (HR = 3.2; 95% CI = 2.1, 5.0). However, blue-collar workers used depression-related services less frequently than their white-collar counterparts among both men (rate ratio = 0.91; 95% CI = 0.84, 0.98) and women (rate ratio = 0.82; 95% CI = 0.77, 0.88). CONCLUSIONS: Blue-collar women were more likely to be treated for depression than white-collar workers, and blue-collar women were most likely to be treated for depression compared with white-collar men. However, blue-collar men and women used depression-related healthcare services less frequently than white-collar workers. These findings underscore that blue-collar women may be uniquely susceptible to depression, and suggest that blue-collar workers may encounter barriers to care-seeking related mental illness other than their insurance status

Sistema de climatización automático para mantener la temperatura de confort en la Piscina del Centro Recreacional La Merced Laredo – La Libertad

Los centros campestres de recreación son un negocio que en la actualidad está teniendo un gran impacto económico para toda empresa que se dedicada a este rubro. Todas buscan brindar un servicio de calidad con instalaciones acogedoras. Sin embargo, existen una serie de dificultades que obstaculizan la realización y conservación de estos objetivos; los cuales están relacionado principalmente con las limitaciones ambientales (climatológicas) que provee el medio; como por ejemplo, el uso de piscinas convencionales a cualquier hora del día, ya que por salud personal dependiendo el horario podría ser perjudicial al organismo del usuario; para las prácticas de deporte, ya que para ello existen una serie de requerimiento en especiales térmicos. Por ello la presente tesis propuso el diseño de un sistema de climatización automático para mantener la temperatura de confort en la piscina del Centro Recreacional La Merced, Laredo – La Libertad, el cual se encargará de suplir los requerimientos del Gerente General del lugar. El proyecto se dividió principalmente en 5 etapas. La primera se encargó de realizar un balance de masa y energía, para determinar la demanda térmica requerida. La segunda consistió en realizar una evaluación de sistemas y tecnología que se acoplen con mayor eficiencia, tanto en el aspecto técnico como en lo económico. Tercero se propuso el diseño y selección de los componentes que conforman el sistema. En la cuarta etapa se realizó un análisis de impacto ambiental, el cual demuestra que el sistema por intermedio de una tecnología puede reducir contaminantes en comparación con los métodos convencionales. Finalmente se realizó un análisis económico con un monto y retorno de inversión aproximado. El proyecto concluyo con la demostración del algoritmo de cálculo, planos, simulación, diagramas de funcionamiento y componentes que participaran en el sistema de climatización

Breaking the Crowther Limit: Combining Depth-Sectioning and Tilt Tomography for High-Resolution, Wide-Field 3D Reconstructions

To date, high-resolution (< 1 nm) imaging of extended objects in three-dimensions (3D) has not been possible. A restriction known as the Crowther criterion forces a tradeoff between object size and resolution for 3D reconstructions by tomography. Further, the sub-Angstrom resolution of aberration-corrected electron microscopes is accompanied by a greatly diminished depth of field, causing regions of larger specimens (> 6 nm) to appear blurred or missing. Here we demonstrate a three-dimensional imaging method that overcomes both these limits by combining through-focal depth sectioning and traditional tilt-series tomography to reconstruct extended objects, with high-resolution, in all three dimensions. The large convergence angle in aberration corrected instruments now becomes a benefit and not a hindrance to higher quality reconstructions. A through-focal reconstruction over a 390 nm 3D carbon support containing over one hundred dealloyed and nanoporous PtCu catalyst particles revealed with sub-nanometer detail the extensive and connected interior pore structure that is created by the dealloying instability

Effective density of aircraft engine PM revisited : effects of engine thrust, engine type, fuel, and sample conditioning

Aircraft gas turbine engines emit soot agglomerates with varying size, shape, and composition as a function of their operating condition. A useful parameter, which accounts for particle morphology, is effective density. Effective density is used to relate particle number and mass emissions in aviation PM emission models. However, measurement data of PM effective density from commercial aircraft turbine engines are very limited. Here, we report the size‐dependent effective density of PM sampled from commercial aircraft turbine engines in an engine test cell using a standardized sampling and measurement system. We used tandem DMA‐CPMA classification as in our previous study (Durdina et al. 2014). The novelty of this work is reduced scan time from over 10 minutes down to 1 minute per sample with the same hardware configuration, wider range of particle sizes, measurement of different engines, and a larger database with better data quality. The fast method allowed us to measure various engine types during their post‐overhaul test runs with short test points. We also performed effective density measurements during two dedicated test campaigns of the same engine. These campaigns investigated the effects of an alternative fuel blend on emissions and the evolution of the exhaust plume downstream of the engine exit plane. In the latter campaign, the effective density was measured with and without the treatment with a catalytic stripper approximately 25 m downstream of the engine exit plane. Figure 1 shows the compiled results obtained for all engines and fuels tested with exhaust samples taken at the engine exit plane and 25 m downstream with a catalytic stripper. The results confirm the thrust dependence of the effective density distributions reported previously. The most distinct differences are between the effective density distributions at idle thrust (Figure 1, a) and medium to high thrust (Figure 1, b). This trend was qualitatively the same for all engines tested. In contrast to our previous report, the effective densities at medium and high thrust did not follow the mass‐mobility relationship determined previously. The best fit of the data is an exponential function. The fit functions determined have potential applications in aircraft PM emissions modeling and measurement. The size‐dependent densities can be used to estimate PM mass concentration from particle size distributions measured using mobility particle sizers. The density functions can be used to improve particle loss correction models in sampling systems for aircraft engine emissions

Thermal conductivity of porous materials

Incorporation of porosity into a monolithic material decreases the effective thermal conductivity. Porous ceramics were prepared by different methods to achieve pore volume fractions from 4 to 95%. A toolbox of analytical relations is proposed to describe the effective thermal conductivity as a function of solid phase thermal conductivity, pore thermal conductivity, and pore volume fraction (νp). For νp 0.65, the thermal conductivity of kaolin-based foams and calcium aluminate foams was well described by the Hashin Shtrikman upper bound and Russell's relation. Finally, numerical simulation on artificially generated microstructures yields accurate predictions of thermal conductivity when fine detail of the spatial distribution of the phases needs to be accounted for, as demonstrated with a bio-aggregate materia

Non-volatile particle emissions from aircraft turbine engines at ground-idle induce oxidative stress in bronchial cells

Aircraft emissions contribute to local and global air pollution. Health effects of particulate matter (PM) from aircraft engines are largely unknown, since controlled cell exposures at relevant conditions are challenging. We examined the toxicity of non-volatile PM (nvPM) emissions from a CFM56-7B26 turbofan, the world's most used aircraft turbine using an unprecedented exposure setup. We combined direct turbine-exhaust sampling under realistic engine operating conditions and the Nano-Aerosol Chamber for In vitro Toxicity to deposit particles onto air-liquid-interface cultures of human bronchial epithelial cells (BEAS-2B) at physiological conditions. We evaluated acute cellular responses after 1-h exposures to diluted exhaust from conventional or alternative fuel combustion. We show that single, short-term exposures to nvPM impair bronchial epithelial cells, and PM from conventional fuel at ground-idle conditions is the most hazardous. Electron microscopy of soot reveals varying reactivity matching the observed cellular responses. Stronger responses at lower mass concentrations suggest that additional metrics are necessary to evaluate health risks of this increasingly important emission source

Landau levels in the case of two degenerate coupled bands: kagome lattice tight-binding spectrum

The spectrum of charged particles hopping on a kagome lattice in a uniform transverse magnetic field shows an unusual set of Landau levels at low field. They are unusual in two respects: the lowest Landau levels are paramagnetic so their energies decrease linearly with increasing field magnitude, and the spacings between the levels are not equal. These features are shown to follow from the degeneracy of the energy bands in zero magnetic field. We give a general discussion of Landau levels in the case of two degenerate bands, and show how the kagome lattice tight-binding model includes one special case of this more general problem. We also discuss the consequences of this for the behavior of the critical temperature of a kagome grid superconducting wire network, which is the experimental system that originally motivated this work.Comment: 18 pages, 8 figure