High turnover in electro-oxidation of alcohols and ethers with a glassy carbon-supported phenanthroimidazole mediator.

Glassy carbon electrodes covalently modified with a phenanthroimidazole mediator promote electrochemical alcohol and ether oxidation: three orders of magnitude increase in TON, to ∼15 000 in each case, was observed compared with homogeneous mediated reactions. We propose the deactivation pathways in homogeneous solution are prevented by the immobilization: modified electrode reversibility is increased for a one-electron oxidation reaction. The modified electrodes were used to catalytically oxidize p-anisyl alcohol and 1-((benzyloxy)methyl)-4-methoxybenzene, selectively, to the corresponding benzaldehyde and benzyl ester, respectively

Selection of landcover types by translocated female eastern wild turkeys in east Texas

Restoration of eastern wild turkeys (Meleagris gallopavo silvestris) is among the greatest conservation achievements in North America. However, restoration efforts in east Texas have had limited success, resulting in a fragmented distribution of turkeys across the landscape. Restoration success is largely dependent on the ability of translocated individuals to quickly select habitat patches on the landscape. Information on habitat selection of translocated wild turkeys is important to identify high quality release locations that should reduce the probability of translocation failure. Our objective was to describe selection of landcover types by translocated female wild turkeys in east Texas. During 2016–2017, we translocated 78 GPS‐tagged wild turkeys to Angelina National Forest in east Texas. We quantified third order selection for females during 3 temporal periods—the exploratory phase (days 1–20), the exploitation phase (days 21–80), and within the annual range. During the exploratory phase, females selected shrub‐scrub and open landcover types, as well as linear paths (roads, rights-of‐way). During the exploitation phase, females selected shrub-scrub, mixed, and open landcover types, but not linear paths. Overall, wild turkeys translocated into forested landscapes of east Texas selected for early successional and other open landcover types. Prior to translocation attempts in forest-dominated landscapes, managers should consider ways to increase availability of open landcover types with herbaceous cover for nesting and brood rearing

Global Cue Inconsistency Diminishes Learning of Cue Validity

We present a novel two-stage probabilistic learning task that examines the participants’ ability to learn and utilize valid cues across several levels of probabilistic feedback. In the first stage, participants sample from one of three cues that gives predictive information about the outcome of the second stage. Participants are rewarded for correct prediction of the outcome in stage two. Only one of the three cues gives valid predictive information and thus participants can maximise their reward by learning to sample from the valid cue. The validity of this predictive information, however, is reinforced across several levels of probabilistic feedback. A second manipulation involved changing the consistency of the predictive information in stage one and the outcome in stage two. The results show that participants, with higher probabilistic feedback, learned to utilise the valid cue. In inconsistent task conditions, however, participants were significantly less successful in utilising higher validity cues. We interpret this result as implying that learning in probabilistic categorization is based on developing a representation of the task that allows for goal-directed action

Anthropometric and physiological predictors of flat-water 1000 m kayak performance in young adolescents and the effectiveness of a high volume training camp.

Our purpose was to determine the relationship of anthropometric and physiological variables with 1000m flat-water kayak (K1000) performance. A secondary purpose was to determine the effectiveness of a high volume training camp. High performance young adolescent kayakers (n=13, 8 males, 5 females, 15±1 yrs) participated in this study. Testing before and after the 3-4 week training camp included anthropometric measurements (height, sitting height, arm span, and body mass), strength (1-RM: bench press and bench pull), flexibility (sit and reach), and an incremental kayak ergometer test to determine peak oxygen uptake (VO2peak) and anaerobic threshold, and an open water K1000 time trial. K1000 time was significantly correlated with height (r=-0.81; p\u3c0.01), sitting height (r=-0.85; p\u3c0.01), arm span (r=-0.87; p\u3c0.01), bench press (r=-0.92; p\u3c0.01), bench pull (r=-0.85; p\u3c0.01), VO2peak (r=-0.87; p\u3c0.01) and anaerobic threshold (r=-0.83; p\u3c0.05). Following the training camp there were no significant differences in body mass, strength, and VO2 peak, however, anaerobic threshold (33.6±6.2 to 42.3±8.8 ml•kg-1•min-1, p=0.001) and K1000 (302±44 to 289±31 sec, p=0.007) significantly improved. The results of this study suggest that K1000 performance in young adolescent kayakers appears to require a high aerobic and strength contribution and that a high volume training camp is effective for improving anaerobic threshold and performance

Public acceptance of Privacy-Encroaching Policies to Address the COVID-19 Pandemic in the United Kingdom

The nature of the COVID-19 pandemic may require governments to use privacy-encroaching technologies to help contain its spread. One technology involves co-location tracking through mobile Wi-Fi, GPS, and Bluetooth to permit health agencies to monitor people's contact with each other, thereby triggering targeted social-distancing when a person turns out to be infected. The effectiveness of tracking relies on the willingness of the population to support such privacy encroaching measures. We report the results of two large surveys in the United Kingdom, conducted during the peak of the pandemic, that probe people's attitudes towards various tracking technologies. The results show that by and large there is widespread acceptance for co-location tracking. Acceptance increases when the measures are explicitly time-limited and come with opt-out clauses or other assurances of privacy. Another possible future technology to control the pandemic involves "immunity passports", which could be issued to people who carry antibodies for the COVID-19 virus, potentially implying that they are immune and therefore unable to spread the virus to other people. Immunity passports have been considered as a potential future step to manage the pandemic. We probe people's attitudes towards immunity passports and find considerable support overall, although around 20% of the public strongly oppose passports

Alpha-Synuclein Oligomers Interact with Metal Ions to Induce Oxidative Stress and Neuronal Death in Parkinson's Disease

Protein aggregation and oxidative stress are both key pathogenic processes in Parkinson's disease, although the mechanism by which misfolded proteins induce oxidative stress and neuronal death remains unknown. In this study, we describe how aggregation of alpha-synuclein (α-S) from its monomeric form to its soluble oligomeric state results in aberrant free radical production and neuronal toxicity

Evaluation of the allocated resources of the Greek NSRF 2007-2013 in sectoral and regional level

<p>The broken line shows that chance performance is 25%. Error bars are within-observers standard error. **Significantly different at <i>p</i><0.001.</p

The acceptability and uptake of smartphone tracking for COVID-19 in Australia

In response to the COVID-19 pandemic, many Governments are instituting mobile tracking technologies to perform rapid contact tracing. However, these technologies are only effective if the public is willing to use them, implying that their perceived public health benefits must outweigh personal concerns over privacy and security. The Australian federal government recently launched the 'COVIDSafe' app, designed to anonymously register nearby contacts. If a contact later identifies as infected with COVID-19, health department officials can rapidly followup with their registered contacts to stop the virus' spread. The current study assessed attitudes towards three tracking technologies (telecommunication network tracking, a government app, and Apple and Google's Bluetooth exposure notification system) in two representative samples of the Australian public prior to the launch of COVIDSafe. We compared these attitudes to usage of the COVIDSafe app after its launch in a further two representative samples of the Australian public. Using Bayesian methods, we find widespread acceptance for all tracking technologies, however, observe a large intention-behaviour gap between people's stated attitudes and actual uptake of the COVIDSafe app. We consider the policy implications of these results for Australia and the world at large

Quantization of Superflow Circulation and Magnetic Flux with a Tunable Offset

Quantization of superflow-circulation and of magnetic-flux are considered for systems, such as superfluid $^3$He-A and unconventional superconductors, having nonscalar order parameters. The circulation is shown to be the anholonomy in the parallel transport of the order parameter. For multiply-connected samples free of distributed vorticity, circulation and flux are predicted to be quantized, but generically to nonintegral values that are tunably offset from integers. This amounts to a version of Aharonov-Bohm physics. Experimental settings for testing these issues are discussed.Comment: 5 two-column pages, ReVTeX, figure available upon request (to [email protected]