Solid-gas phase photo-catalytic behaviour of rutile and TiOn (1<n<2) sub-oxide phases for self-cleaning applications

The solid-gas phase photo-catalytic activities of rutile TiO₂ and TiO n (1 &lt; n &lt; 2) sub-oxide phases have been evaluated. Varying concentrations of Ti 3+ defects were introduced into the rutile polymorph of titanium dioxide through carbo-thermal reduction at temperatures ranging from 350 °C to 1300 °C. The resulting sub-oxides formed were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, impedance spectroscopy and UV-visible diffuse reflectance spectroscopy. The presence of Ti 3+ in rutile exposed to high reduction temperatures was confirmed by X-ray diffraction. In addition, a Ti 3+-Ti 4+ system was demonstrated to enhance the photo-catalytic properties of rutile for the degradation of the air pollutants NO₂ and CO₂ under UV irradiation of wavelengths (λ) 376⁻387 nm and 381⁻392 nm. The optimum reduction temperature for photo-catalytic activity was within the range 350⁻400 °C and attributed to improved charge-separation. The materials that were subject to carbo-thermal reduction at temperatures of 350 °C and 400 °C exhibited electrical conductivities over one hundred times higher compared to the non-reduced rutile. The results highlight that sub-oxide phases form an important alternative approach to doping with other elements to improve the photo-catalytic performance of TiO₂. Such materials are important for applications such as self-cleaning where particles can be incorporated into surface coatings. </p

Impact of the absolute rutile fraction on TiO2 visible-light absorption and visible-light-promoted photocatalytic activity

Titanium dioxide is by far the most used semiconductor material for photocatalytic applications. Still, it is transparent to visible-light. Recently, it has been proved that a type-II band alignment for the rutile − anatase mixture would improve visible-light absorption. In this research paper we thoroughly characterised the real crystalline and amorphous phases of synthesised titanias – thermally treated at different temperatures to get distinct ratios of anatase-rutile-amorphous fraction – as well as that of three commercially available photocatalytic nano-TiO2. Optical spectroscopy showed that even a small fraction of rutile (2 wt%) is able to shift to lower energies the apparent optical band gap of an anatase-rutile mixed phase. But is this enough to attain a real photocatalytic activity promoted by merely visible-light? We tried to give an answer to that question. Photocatalytic activity was assessed in the liquid- and gas-solid phase (employing rhodamine B and 4-chlorophenol, and isopropanol, respectively, as the organic substances to degrade) using a light source irradiating exclusively in the visible-range. Photocatalytic activity results in the liquid-solid phase showed that a high surface hydroxylation led to specimen with superior visible light-promoted catalytic activity – i.e. dye and ligand-to-metal charge transfer complexes sensitisation effects, not photocatalysis sensu-strictu. On the other hand, the gas-solid phase results showed that a higher amount of the absolute rutile fraction (around 10 wt%), together with less recombination of the charge carriers, were more effective for both visible-light absorption and a “real” visible-light promoted photocatalytic oxidation of isopropanol.publishe

Solid-gas phase photo-catalytic behaviour of rutile and TiOn (1&lt;n&lt;2) sub-oxide phases for self-cleaning applications

The solid-gas phase photo-catalytic activities of rutile TiO2 and TiOn (1 &lt; n &lt; 2) sub-oxide phases have been evaluated. Varying concentrations of Ti3+ defects were introduced into the rutile polymorph of titanium dioxide through carbo-thermal reduction at temperatures ranging from 350 &deg;C to 1300 &deg;C. The resulting sub-oxides formed were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, impedance spectroscopy and UV-visible diffuse reflectance spectroscopy. The presence of Ti3+ in rutile exposed to high reduction temperatures was confirmed by X-ray diffraction. In addition, a Ti3+-Ti4+ system was demonstrated to enhance the photo-catalytic properties of rutile for the degradation of the air pollutants NO2 and CO2 under UV irradiation of wavelengths (&lambda;) 376&ndash;387 nm and 381&ndash;392 nm. The optimum reduction temperature for photo-catalytic activity was within the range 350&ndash;400 &deg;C and attributed to improved charge-separation. The materials that were subject to carbo-thermal reduction at temperatures of 350 &deg;C and 400 &deg;C exhibited electrical conductivities over one hundred times higher compared to the non-reduced rutile. The results highlight that sub-oxide phases form an important alternative approach to doping with other elements to improve the photo-catalytic performance of TiO2. Such materials are important for applications such as self-cleaning where particles can be incorporated into surface coatings

Creación de un logo para el trabajo en las colonias: La Revolucionaria, Lomas del Pedregal y Balcones del Cuatro

En este proyecto se recopiló información sobre las colonias La Revolucionaria, Pedregales y Balcones del Cuatro con el objetivo de crearles una identidad a través de materiales gráficos. Con esto se pretende dotar a estas comunidades de una identidad y abonar a la integración social

Photocatalytic activity for exposed building materials

Photocatalysis is a very promising method to face most of the problems connected with the increasing environmental pollution. Titanium dioxide in its anatase crystallographic phase is the most investigated photocatalytic material and results to be perfectly compatible with silicate body mixes. The possibility to obtain photocatalytic heavy clays materials, to be used for outdoor applications, such as roof tiles, floor tile and outdoor covering tiles, could represent an important goal. In the present work, several titania powders and a titania nanosuspension were added to a body mix used for heavy clay products and the influence of their morphological characteristics on the photoactivity of the fired materials was studied. The titania powders, characterised by the aid of SEM, X-ray diffraction analysis and surface area measurements, BET, presented particles with different aspect ratio and size, ranging from micrometric to nanoparticles. Besides, the nanosuspension was characterised by FEG, TEM, DLS and XRD on the dried suspension. The photocatalytic activity was assessed in aqueous mixtures, by analysing the degradation of an organic dye with a spectrophotometer. The results were explained taking into account the anatase to rutile phase transformation and its possible reaction, during sintering, with the starting raw materials

Formulation of mortars with nano-SiO2 and nano-TiO2 for degradation of pollutants in buildings

This paper reports on the design of cement mortars that use nano-SiO2 (nS) and nano-TiO2 (nT) particles, aiming to improve the durability of traditional building materials while giving new functionalities (aerial decontamination of pollutants). Samples with 0–2 wt.% nS, 0–20 wt.% nT, 0.45–7 wt.% superplasticizer (SP) and 0.45–0.58 water/binder weight ratio were prepared. The formulations of mortars were defined according to rheology and flow table measurements, then showing suitable workability. The temperature of hydration, compressive strength, water absorption, and photocatalytic degradation of pollutants (NOx and Orange II dye) were also evaluated. In general, the rheological behavior and the temperature of hydration changed in distinct levels, depending on the dosage and type of nanoadditives, but nT influenced more significantly the results. However, such differences were not identified on the compressive strength and water absorption. In addition, NOx photocatalytic degradation up to 1 h under solar light ranged from 65% to 80%, while Orange II degradation after 9 h under visible light changed from 18% to 50%

Nitrogen-modified nano-titania: True phase composition, microstructure and visible-light induced photocatalytic NOx abatement

Titanium dioxide (TiO2) is a popular photocatalyst used for many environmental and anti-pollution applications, but it normally operates under UV light, exploiting similar to 5% of the solar spectrum. Nitrification of titania to form N-doped TiO2 has been explored as a way to increase its photocatalytic activity under visible light, and anionic doping is a promising method to enable TiO2 to harvest visible-light by changing its photo-absorption properties. In this paper, we explore the insertion of nitrogen into the TiO2 lattice using our green sol gel nanosynthesis method, used to create 10 nm TiO2 NPs. Two parallel routes were studied to produce nitrogen-modified TiO2 nanoparticles (NPs), using HNO3+NH3 (acid-precipitated base-peptised) and NH4OH (totally base catalysed) as nitrogen sources. These NPs were thermally treated between 450 and 800 degrees C. Their true phase composition (crystalline and amorphous phases), as well as their micro-/nanostructure (crystalline domain shape, size and size distribution, edge and screw dislocation density) was fully characterised through advanced X-ray methods (Rietveld-reference intensity ratio, RIR, and whole powder pattern modelling, WPPM). As pollutants, nitrogen oxides (NO) are of particular concern for human health, so the photocatalytic activity of the NPs was assessed by monitoring NO, abatement, using both solar and white-light (indoor artificial lighting), simulating outdoor and indoor environments, respectively. Results showed that the onset of the anatase-to-rutile phase transformation (ART) occurred at temperatures above 450 degrees C, and NPs heated to 450 degrees C possessed excellent photocatalytic activity (PCA) under visible white-light (indoor artificial lighting), with a PCA double than that of the standard P25 TiO2 NPs. However, higher thermal treatment temperatures were found to be detrimental for visible-light photocatalytic activity, due to the effects of four simultaneous occurrences: (i) loss of OH groups and water adsorbed on the photocatalyst surface; (ii) growth of crystalline domain sizes with decrease in specific surface area; (iii) onset and progress of the ART; (iv) the increasing instability of the nitrogen in the titania lattice. (C) 2015 Elsevier Inc. All rights reserved

Effective removal of anionic and cationic dyes by kaolinite and TiO2/kaolinite composites

The present study investigated the removal of methylene blue (MB) and orange II (OII) dyes from synthetic wastewater by means of adsorption and photocatalysis using natural kaolins. For MB adsorption, the raw kaolinite-rich samples showed the greatest adsorption capacity, with rapid uptake (90% after 20 min). The experimental results were fitted better using the Langmuir isotherm model parameters compared to the Freundlich model, suggesting that the adsorption corresponds to monolayer coverage of MB molecules over the kaolinite surface. For OII, neither the Langmuir nor the Freundlich model gave reliable results, because the adsorption of anionic dye molecules by the clayey particles is not favoured. Mixtures of kaolinite/Degussa TiO2 were also prepared, and their photocatalytic properties under UV-light exposure were investigated. Decolourization of MB solutions was observed, even in a mixture with low TiO2 content. This is related to the combined effect of adsorption and photocatalysis and, unlike the pure clay samples, the efficiency of such mixtures against OII was only slightly weaker (80-94%). For TiO2-impregnated clays, with the kaolinite layers separated by sol-gel TiO2 particles, the MB removal was slow and effective only after > 24 h due to the complexity of the bonding of MB molecules. On the other hand, the removal performance against OII solutions was very efficient (nearly 100%) within only 2 h. This excellent performance was attributed to morphological changes in clay particles