A simple modeling approach to study the regional impact of a Mediterranean forest isoprene emission on anthropogenic plumes

Research during the past decades has outlined the importance of biogenic isoprene emission in tropospheric chemistry and regional ozone photo-oxidant pollution. The first part of this article focuses on the development and validation of a simple biogenic emission scheme designed for regional studies. Experimental data sets relative to Boreal, Tropical, Temperate and Mediterranean ecosystems are used to estimate the robustness of the scheme at the canopy scale, and over contrasted climatic and ecological conditions. A good agreement is generally found when comparing field measurements and simulated emission fluxes, encouraging us to consider the model suitable for regional application. Limitations of the scheme are nevertheless outlined as well as further on-going improvements. In the second part of the article, the emission scheme is used on line in the broader context of a meso-scale atmospheric chemistry model. Dynamically idealized simulations are carried out to study the chemical interactions of pollutant plumes with realistic isoprene emissions coming from a Mediterranean oak forest. Two types of anthropogenic sources, respectively representative of the Marseille (urban) and Martigues (industrial) French Mediterranean sites, and both characterized by different VOC/NOx are considered. For the Marseille scenario, the impact of biogenic emission on ozone production is larger when the forest is situated in a sub-urban configuration (i.e.&nbsp;downwind distance TOWN-FOREST <30km, considering an advection velocity of 4.2 m.s^-1). In this case the enhancement of ozone production due to isoprene can reach +37% in term of maximum surface concentrations and +11% in term of total ozone production. The impact of biogenic emission decreases quite rapidly when the TOWN-FOREST distance increases. For the Martigues scenario, the biogenic impact on the plume is significant up to TOWN-FOREST distance of 90km where the ozone maximum surface concentration enhancement can still reach +30%. For both cases, the importance of the VOC/NO_x ratio in the anthropogenic plume and its evolution when interacting with the forest emission are outlined. In complement to real case studies, this idealized approach can be particularly useful for process and sensitivity studies and constitutes a valuable tool to build regional ozone control strategies

Updated African biomass burning emission inventories in the framework of the AMMA-IDAF program, with an evaluation of combustion aerosols

African biomass burning emission inventories for gaseous and particulate species have been constructed at a resolution of 1 km by 1km with daily coverage for the 2000–2007 period. These inventories are higher than the GFED2 inventories, which are currently widely in use. Evaluation specifically focusing on combustion aerosol has been carried out with the ORISAM-TM4 global chemistry transport model which includes a detailed aerosol module. This paper compares modeled results with measurements of surface BC concentrations and scattering coefficients from the AMMA Enhanced Observations period, aerosol optical depths and single scattering albedo from AERONET sunphotometers, LIDAR vertical distributions of extinction coefficients as well as satellite data. Aerosol seasonal and interannual evolutions over the 2004–2007 period observed at regional scale and more specifically at the Djougou (Benin) and Banizoumbou (Niger) AMMA/IDAF sites are well reproduced by our global model, indicating that our biomass burning emission inventory appears reasonable

Photosynthesis-dependent isoprene emission from leaf to planet in a global carbon-chemistry-climate model

Peer reviewe

Net greenhouse gas balance of fibre wood plantation on peat in Indonesia

Tropical peatlands cycle and store large amounts of carbon in their soil and biomass1,2,3,4,5. Climate and land-use change alters greenhouse gas (GHG) fluxes of tropical peatlands, but the magnitude of these changes remains highly uncertain6,7,8,9,10,11,12,13,14,15,16,17,18,19. Here we measure net ecosystem exchanges of carbon dioxide, methane and soil nitrous oxide fluxes between October 2016 and May 2022 from Acacia crassicarpa plantation, degraded forest and intact forest within the same peat landscape, representing land-cover-change trajectories in Sumatra, Indonesia. This allows us to present a full plantation rotation GHG flux balance in a fibre wood plantation on peatland. We find that the Acacia plantation has lower GHG emissions than the degraded site with a similar average groundwater level (GWL), despite more intensive land use. The GHG emissions from the Acacia plantation over a full plantation rotation (35.2 ± 4.7 tCO2-eq ha−1 year−1, average ± standard deviation) were around two times higher than those from the intact forest (20.3 ± 3.7 tCO2-eq ha−1 year−1), but only half of the current Intergovernmental Panel on Climate Change (IPCC) Tier 1 emission factor (EF)20 for this land use. Our results can help to reduce the uncertainty in GHG emissions estimates, provide an estimate of the impact of land-use change on tropical peat and develop science-based peatland management practices as nature-based climate solutions

Impact of NO emissions from soils on tropospheric ozone formation in the framework of the AMMA program.

(octobre 2007

Efficiency of the Nam Theun 2 hydraulic structures on water aeration and methane degassing

Release of hypolimnetic water from man-made reservoirs can be a problem for downstream rivers. These effects can be significant mainly during the first years after the reservoir impoundment, especially in thermally stratified reservoirs favouring the release of anoxic methane-rich water. In tropical areas, higher temperatures decrease the oxygen solubility and enhance chemical processes responsible for the rise of reduced compounds. The Nam Theun 2 Reservoir was first filled in 2008. It experienced hypolimnetic deoxygenation and significant methane concentrations during the first 2 years. Dedicated structures to oxygenate water and degas methane were designed during the study phase. The overall aerating and degassing effects of these hydraulics structures varied from very good to moderate. Results depend on the continuous water quality improvement with time as well as on the limited range of upstream oxygen and methane concentrations tested. The hollow jet valve and the concrete tooth shaped structure were very efficient together with downstream natural turbulence in aerating/degassing compared to the staggered baffle blocks. Contrary to other structures, the efficiency of the baffle blocks structure is reduced with high discharges. The aeration weir showed a moderate efficiency in supplying oxygen to the water due to the high upstream oxygen saturations (close to 100%). However, it was very efficient for methane degassing even at low concentrations. Hydraulics structures of the Nam Theun 2 project are an efficient, reliable and low maintenance way to improve oxygen content and to degas methane

Evolution of the physico-chemical water quality in the Nam Theun 2 Reservoir and downstream rivers for the first 5 years after impoundment

The physical (temperature, conductivity and turbidity) and chemical water quality (O2, pH, conductivity, nutrients, major anions and cations) characteristics have been monitored in the Nam Theun 2 system (hydroelectric reservoir and rivers downstream) for the first 5 years after impoundment. The results emphasize that the impoundment of the reservoir induced a substantial modification of the water quality in the whole aquatic system which is partially controlled by the hydrodynamics in the reservoir. During the warm seasons, the reservoir water column is thermally stratified with a warm oxic epilimnion and a colder anoxic hypolimnion. During the cold dry season or during floods, the reservoir water column over-turns which enhances oxygen penetration down to the bottom waters and contributes to a global improvement of the water quality. Downstream of the reservoir, the oxygen level was always above the minimum requirement for aquatic life due to the specific design of the water intakes at the Nakai Dam and upstream of the Power House which both favour the withdrawal of a large proportion of oxygenated epilimnic waters. Over the five years, the water quality in the reservoir itself globally improved. However, the diversion of the Nam Theun River into the Xe Bang Fai watershed via the reservoir has impacted the Xe Bang Fai River in terms of temperature, conductivity and total suspended solids