Comparison of the PFAS Adsorption Capabilities of a Coconut Shell Based Granular Activated Carbon and a Bituminous Coal Based Granular Activated Carbon

This research compares the ability of two granular activated carbons (GAC) from different material sources to adsorb perfluoroalkyl substances (PFAS) in deionized water. A bottle study design was used to conduct the research, which measured the reduction in perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS). The carbons used were the bituminous coal based Calgon Filtrasorb 600 (F600) and the coconut shell based Evoqua AquaCarb 1230CX (AC1230CX). Additionally, the research focused on the rates at which the two contaminants were removed and compared them to previous research conducted with different forms of GAC. Results showed that both GACs were capable of reducing the concentration \u3e95% for both PFOS and PFOA, and that the more sustainable and cheaper Evoqua AC1230CX was able to compete with a bituminous coal based carbon. Additionally, PFOS was removed more quickly than PFOA, showing a preference to perfluoroalkane sulfonic acids (PFSA) over perfluorocarboxylic acids (PFCA) similar to that which has been observed in previous research

Socioeconomic inequalities in childhood exposure to secondhand smoke before and after smoke-free legislation in three UK countries

Background: Secondhand smoke (SHS) exposure is higher among lower socioeconomic status (SES) children. Legislation restricting smoking in public places has been associated with reduced childhood SHS exposure and increased smoke-free homes. This paper examines socioeconomic patterning in these changes.<p></p> Methods: Repeated cross-sectional survey of 10 867 schoolchildren in 304 primary schools in Scotland, Wales and Northern Ireland. Children provided saliva for cotinine assay, completing questionnaires before and 12 months after legislation.<p></p> Results: SHS exposure was highest, and private smoking restrictions least frequently reported, among lower SES children. Proportions of saliva samples containing <0.1 ng/ml (i.e. undetectable) cotinine increased from 31.0 to 41.0%. Although across the whole SES spectrum, there was no evidence of displacement of smoking into the home or increased SHS exposure, socioeconomic inequality in the likelihood of samples containing detectable levels of cotinine increased. Among children from the poorest families, 96.9% of post-legislation samples contained detectable cotinine, compared with 38.2% among the most affluent. Socioeconomic gradients at higher exposure levels remained unchanged. Among children from the poorest families, one in three samples contained > 3 ng/ml cotinine. Smoking restrictions in homes and cars increased, although socioeconomic patterning remained.<p></p> Conclusions Urgent action is needed to reduce inequalities in SHS exposure. Such action should include emphasis on reducing smoking in cars and homes

Physical and chemical signatures of a developing anticyclonic eddy in the Leeuwin Current, eastern Indian Ocean

A multidisciplinary cruise aboard the R/V Southern Surveyor was conducted in May 2006 to sample a developing anticyclonic eddy of the Leeuwin Current off Western Australia. The eddy formed from a meander of the Leeuwin Current in mid-April 2006 and remained attached to the current until mid-August. In this study, a combination of satellite data (altimeter, sea surface temperature, and chlorophyll a) and shipboard measurements (acoustic Doppler current profiler and conductivity-temperature-depth) were used to characterize the physical and chemical signatures of the eddy. The temperature-salinity properties of the mixed layer waters within the anticyclonic eddy and on the shelf were both connected to that of the Leeuwin Current, indicating the water mass in the eddy is mainly derived from the Leeuwin Current and the modified Leeuwin Current water on the shelf. Above the salinity maximum near the eddy center, there was a regionally significant concentration of nitrate (>0.9 μmol L-1), and the maximum (2 μmol L-1) was at 150 in depth, below the photic zone. Nitrification within the eddy and/or local upwelling due to the forming eddy could be responsible for this high concentration of nitrate near the eddy center which potentially makes the eddy a relatively productive feature in the Leeuwin Current

Assessing the Viability of Complex Electrical Impedance Tomography (EIT) with a Spatially Distributed Sensor Array for Imaging of River Bed Morphology: a Proof of Concept (Study)

This report was produced as part of a NERC funded ‘Connect A’ project to establish a new collaborative partnership between the University of Worcester (UW) and Q-par Angus Ltd. The project aim was to assess the potential of using complex Electrical Impedance Tomography (EIT) to image river bed morphology. An assessment of the viability of sensors inserted vertically into the channel margins to provide real-time or near real-time monitoring of bed morphology is reported. Funding has enabled UW to carry out a literature review of the use of EIT and existing methods used for river bed surveys, and outline the requirements of potential end-users. Q-par Angus has led technical developments and assessed the viability of EIT for this purpose. EIT is one of a suite of tomographic imaging techniques and has already been used as an imaging tool for medical analysis, industrial processing and geophysical site survey work. The method uses electrodes placed on the margins or boundary of the entity being imaged, and a current is applied to some and measured on the remaining ones. Tomographic reconstruction uses algorithms to estimate the distribution of conductivity within the object and produce an image of this distribution from impedance measurements. The advantages of the use of EIT lie with the inherent simplicity, low cost and portability of the hardware, the high speed of data acquisition for real-time or near real-time monitoring, robust sensors, and the object being monitored is done so in a non-invasive manner. The need for sophisticated image reconstruction algorithms, and providing images with adequate spatial resolution are key challenges. A literature review of the use of EIT suggests that to date, despite its many other applications, to the best of our knowledge only one study has utilised EIT for river survey work (Sambuelli et al 2002). The Sambuelli (2002) study supported the notion that EIT may provide an innovative way of describing river bed morphology in a cost effective way. However this study used an invasive sensor array, and therefore the potential for using EIT in a non-invasive way in a river environment is still to be tested. A review of existing methods to monitor river bed morphology indicates that a plethora of techniques have been applied by a range of disciplines including fluvial geomorphology, ecology and engineering. However, none provide non-invasive, low costs assessments in real-time or near real-time. Therefore, EIT has the potential to meet the requirements of end users that no existing technique can accomplish. Work led by Q-par Angus Ltd. has assessed the technical requirements of the proposed approach, including probe design and deployment, sensor array parameters, data acquisition, image reconstruction and test procedure. Consequently, the success of this collaboration, literature review, identification of the proposed approach and potential applications of this technique have encouraged the authors to seek further funding to test, develop and market this approach through the development of a new environmental sensor

Modular input-parallel-output-series DC/DC converter control with fault detection and redundancy

Large offshore wind farms will require an extensive sub-sea power network to provide internal interconnection. Present solutions are based around conventional medium-voltage AC architectures. This paper proposes an alternative DC collection network based around modular DC/DC converters with input-parallel-output-series (IPOS) connection. Small-signal analysis of the converter is presented, to assist in control scheme development for the converter input and output stages. A Lyapunov controller is embedded within the conventional output voltage sharing control loop. A master-slave control scheme is proposed to ensure power sharing under a range of operating conditions, and provides fault-tolerant operation since the status of 'master' can be reallocated in the event that the present 'master' module fails

User trust in intelligent systems: A journey over time

Trust is a significant factor in user adoption of new systems. However, although trust is a dynamic attitude of the user towards the system and changes over time, trust in intelligent systems is typically captured as a single quantitative measure at the conclusion of a task. This paper challenges this approach. We report a case study that employed a combination of repeated quantitative and qualitative measures to examine how trust in an intelligent system evolved over time and whether this varied depending on whether the system offered explanations. We discovered different patterns in participants' trust journeys. When provided with explanations, participants' trust levels initially increased, before returning to their original level. Without explanations, participants' trust reduced over time. The qualitative data showed that perceived system ability was more important in determining trust amongst with explanation participants and perceived transparency was a greater influence on the trust of participants who did not receive explanations. The findings provide a deeper understanding of the development of user trust in intelligent systems and indicate the value of the approach adopted

Fault blocking converters for HVDC transmission : a transient behaviour comparison

A thorough comparison of the transient behaviours of two state-of-the-art converters suitable for HVDC transmission is presented. The Alternate Arm and Mixed-Cell Modular Multilevel Converter topologies both have DC fault blocking capability and are selected for the comparison. Converter performance is evaluated and compared under various transient conditions including charging sequence, unbalanced operation, and DC fault recovery. The study is conducted using high-fidelity converter simulation models, integrating detailed controllers that reflect real-scale projects. The main findings of the study assist in the selection of the most suitable converter, given specific performance specifications such as capacitor voltage ripple, cell capacitor requirements, and response during transient operation

Space-Time Clustering and Correlations of Major Earthquakes

Earthquake occurrence in nature is thought to result from correlated elastic stresses, leading to clustering in space and time. We show that occurrence of major earthquakes in California correlates with time intervals when fluctuations in small earthquakes are suppressed relative to the long term average. We estimate a probability of less than 1% that this coincidence is due to random clustering.Comment: 5 pages, 3 figures. Submitted to PR