The Development of Sense of Agency

Agency, a behavioral and psychological concept, is an individual’s sense of what they can do and what they think they can do. It is imperative to understand how a sense of agency in youths can be fostered and transformed into constructive action. This study builds on previous research to better identify predictors of agency, focusing on social and political involvement and opportunity structure. Additionally, it analyzes and proposes the use of a new measure of agency, the Community Leadership (CL) scale. Eighty-five teens (ages 13 to 18) were administered surveys. Involvement was found to be significantly related to agency. It was also related to opportunity structure, but opportunity structure was not significantly related to agency. Opportunity structure seems to partly influence the relationship between involvement and agency. When compared to previously validated measures of agency, the CL scale proved to be a shorter and psychometrically sound alternative measure

Extended calibration of thin-foil manganin gage in ALOX material

The purpose of this program was to extend an existing manganin gage calibration curve, correlating stress as a function of change in gage resistance/gage resistance ({Delta}R/R), and obtain gage repeatability data from stripped manganin thin-foiled gages manufactured by the Measurements Group Inc., Micro-Measurements division. The experiments extended the existing calibration curve range from the current 0.5 GPa to 6.1 GPa by examining impact stresses of 0.1 GPa in the lower range, and 8.0 and 10.0 GPa in the higher range. The manganin gages were embedded in ALOX (42% by volume alumina in EPON 828 epoxy) material. A light gas-gun was used at Sandia National Laboratories Explosive Components Facility (ECF) to drive an impactor material, ALOX or Tungsten, into the ALOX target containing two gages in a centered arrangement. Tilt and velocity of the impactor were measured along with the gage outputs. A total of 11 tests were conducted using the same ALOX target material that was used when obtaining the original calibration curve. Two initial tests were completed using Polymethyl Methacrylate (PMMA) as the impactor and target at an impact pressure of 3.3 GPa for comparison of gage output with analysis and literature values. The installed gage, stripped of its backing, has a nominal thickness of 5 microns. The thin gage and high speed instrumentation allowed higher output resolution measurements than can be obtained with 76 microns manganin wire used previously. The areas of investigation that will be presented include: (1) experimental setup, (2) comparison with existing calibration curve, and (3) discussions of the extended calibration data

How the toughness in metallic glasses depends on topological and chemical heterogeneity

To gain insight into the large toughness variability observed between metallic glasses (MGs), we examine the origin of fracture toughness through bending experiments and molecular dynamics (MD) simulations for two binary MGs: Pd_(82)Si_(18) and Cu_(46)Zr_(54). The bending experiments show that Pd_(82)Si_(18) is considerably tougher than Cu_(46)Zr_(54), and the higher toughness of Pd_(82)Si_(18) is attributed to an ability to deform plastically in the absence of crack nucleation through cavitation. The MD simulations study the initial stages of cavitation in both materials and extract the critical factors controlling cavitation. We find that for the tougher Pd_(82)Si_(18), cavitation is governed by chemical inhomogeneity in addition to topological structures. In contrast, no such chemical correlations are observed in the more brittle Cu_(46)Zr_(54), where topological low coordination number polyhedra are still observed around the critical cavity. As such, chemical inhomogeneity leads to more difficult cavitation initiation in Pd_(82)Si_(18) than in Cu_(46)Zr_(54), leading to a higher toughness. The absence of chemical separation during cavitation initiation in Cu_(46)Zr_(54) decreases the energy barrier for a cavitation event, leading to lower toughness

How the toughness in metallic glasses depends on topological and chemical heterogeneity

To gain insight into the large toughness variability observed between metallic glasses (MGs), we examine the origin of fracture toughness through bending experiments and molecular dynamics (MD) simulations for two binary MGs: Pd_(82)Si_(18) and Cu_(46)Zr_(54). The bending experiments show that Pd_(82)Si_(18) is considerably tougher than Cu_(46)Zr_(54), and the higher toughness of Pd_(82)Si_(18) is attributed to an ability to deform plastically in the absence of crack nucleation through cavitation. The MD simulations study the initial stages of cavitation in both materials and extract the critical factors controlling cavitation. We find that for the tougher Pd_(82)Si_(18), cavitation is governed by chemical inhomogeneity in addition to topological structures. In contrast, no such chemical correlations are observed in the more brittle Cu_(46)Zr_(54), where topological low coordination number polyhedra are still observed around the critical cavity. As such, chemical inhomogeneity leads to more difficult cavitation initiation in Pd_(82)Si_(18) than in Cu_(46)Zr_(54), leading to a higher toughness. The absence of chemical separation during cavitation initiation in Cu_(46)Zr_(54) decreases the energy barrier for a cavitation event, leading to lower toughness

ALEGRA -- code validation: Experiments and simulations

In this study, the authors are providing an experimental test bed for validating features of the ALEGRA code over a broad range of strain rates with overlapping diagnostics that encompass the multiple responses. A unique feature of the Arbitrary Lagrangian Eulerian Grid for Research Applications (ALEGRA) code is that it allows simultaneous computational treatment, within one code, of a wide range of strain-rates varying from hydrodynamic to structural conditions. This range encompasses strain rates characteristic of shock-wave propagation (10{sup 7}/s) and those characteristic of structural response (10{sup 2}/s). Most previous code validation experimental studies, however, have been restricted to simulating or investigating a single strain-rate regime. What is new and different in this investigation is that the authors have performed well-instrumented experiments which capture features relevant to both hydrodynamic and structural response in a single experiment. Aluminum was chosen for use in this study because it is a well characterized material--its EOS and constitutive material properties are well defined over a wide range of loading rates. The current experiments span strain rate regimes of over 10{sup 7}/s to less than 10{sup 2}/s in a single experiment. The input conditions are extremely well defined. Velocity interferometers are used to record the high strain-rate response, while low strain rate data were collected using strain gauges

Rapid Environmental Change over the Past Decade Revealed by Isotopic Analysis of the California Mussel in the Northeast Pacific

The anthropogenic input of fossil fuel carbon into the atmosphere results in increased carbon dioxide (CO2) into the oceans, a process that lowers seawater pH, decreases alkalinity and can inhibit the production of shell material. Corrosive water has recently been documented in the northeast Pacific, along with a rapid decline in seawater pH over the past decade. A lack of instrumentation prior to the 1990s means that we have no indication whether these carbon cycle changes have precedence or are a response to recent anthropogenic CO2 inputs. We analyzed stable carbon and oxygen isotopes (δ13C, δ18O) of decade-old California mussel shells (Mytilus californianus) in the context of an instrumental seawater record of the same length. We further compared modern shells to shells from 1000 to 1340 years BP and from the 1960s to the present and show declines in the δ13C of modern shells that have no historical precedent. Our finding of decline in another shelled mollusk (limpet) and our extensive environmental data show that these δ13C declines are unexplained by changes to the coastal food web, upwelling regime, or local circulation. Our observed decline in shell δ13C parallels other signs of rapid changes to the nearshore carbon cycle in the Pacific, including a decline in pH that is an order of magnitude greater than predicted by an equilibrium response to rising atmospheric CO2, the presence of low pH water throughout the region, and a record of a similarly steep decline in δ13C in algae in the Gulf of Alaska. These unprecedented changes and the lack of a clear causal variable underscores the need for better quantifying carbon dynamics in nearshore environments

Temporal and spatial variability in stable isotope ratios of SPM link to local hydrography and longer term SPM averages suggest heavy dependence of mussels on nearshore production

Temporal changes in hydrography affect suspended particulate matter (SPM) composition and distribution in coastal systems, potentially influencing the diets of suspension feeders. Temporal variation in SPM and in the diet of the mussel Perna perna, were investigated using stable isotope analysis. The δ13C and δ15 N ratios of SPM, mussels and macroalgae were determined monthly, with SPM samples collected along a 10 km onshore–offshore transect, over 14 months at Kenton-on-Sea, on the south coast of South Africa. Clear nearshore (0 km) to offshore (10 km) carbon depletion gradients were seen in SPM during all months and extended for 50 km offshore on one occasion. Carbon enrichment of coastal SPM in winter (June–August 2004 and May 2005) indicated temporal changes in the nearshore detrital pool, presumably reflecting changes in macroalgal detritus, linked to local changes in coastal hydrography and algal seasonality. Nitrogen patterns were less clear, with SPM enrichment seen between July and October 2004 from 0 to 10 km. Nearshore SPM demonstrated cyclical patterns in carbon over 24-h periods that correlated closely with tidal cycles and mussel carbon signatures, sampled monthly, demonstrated fluctuations that could not be correlated to seasonal or monthly changes in SPM. Macroalgae showed extreme variability in isotopic signatures, with no discernable patterns. IsoSource mixing models indicated over 50% reliance of mussel tissue on nearshore carbon, highlighting the importance of nearshore SPM in mussel diet. Overall, carbon variation in SPM at both large and small temporal scales can be related to hydrographic processes, but is masked in mussels by long-term isotope integration

Effects of canopy-mediated abrasion and water flow on the early colonisation of turf-forming algae

Algal canopies form predictable associations with the benthic understorey, and canopy-mediated processes may maintain these associations. Three canopy-mediated processes that are inherently linked are water flow through a canopy, abrasion of the substrate by the canopy, and light penetration. These processes were experimentally reduced to test the hypotheses that turf-forming algae would be: (1) positively affected by reduced abrasion by kelp canopies; (2) positively affected by reduced water flow; and (3) negatively affected by shading (reduced light). Biomass of turf-forming algae was greater when abrasion was reduced, but less when light was reduced. In contrast to predictions, reduced water flow had a negative effect on the percentage cover and biomass of turf-forming algae, rejecting the second hypothesis. It seems, however, that this negative effect was caused by an increase in shading associated with reduced canopy movement, not a reduction of water flow per se. None of the factors accounted for all of the change seen in understorey algae, indicating that it is important to study the interactive effects of physical processes.Bayden D. Russel

Characteristics of the Mesophotic Megabenthic Assemblages of the Vercelli Seamount (North Tyrrhenian Sea)

The biodiversity of the megabenthic assemblages of the mesophotic zone of a Tyrrhenian seamount (Vercelli Seamount) is described using Remotely Operated Vehicle (ROV) video imaging from 100 m depth to the top of the mount around 61 m depth. This pinnacle hosts a rich coralligenous community characterized by three different assemblages: (i) the top shows a dense covering of the kelp Laminaria rodriguezii; (ii) the southern side biocoenosis is mainly dominated by the octocorals Paramuricea clavata and Eunicella cavolinii; while (iii) the northern side of the seamount assemblage is colonized by active filter-feeding organisms such as sponges (sometimes covering 100% of the surface) with numerous colonies of the ascidian Diazona violacea, and the polychaete Sabella pavonina. This study highlights, also for a Mediterranean seamount, the potential role of an isolated rocky peak penetrating the euphotic zone, to work as an aggregating structure, hosting abundant benthic communities dominated by suspension feeders, whose distribution may vary in accordance to the geomorphology of the area and the different local hydrodynamic conditions

Multiple Processes Regulate Long-Term Population Dynamics of Sea Urchins on Mediterranean Rocky Reefs

We annually monitored the abundance and size structure of herbivorous sea urchin populations (Paracentrotus lividus and Arbacia lixula) inside and outside a marine reserve in the Northwestern Mediterranean on two distinct habitats (boulders and vertical walls) over a period of 20 years, with the aim of analyzing changes at different temporal scales in relation to biotic and abiotic drivers. P. lividus exhibited significant variability in density over time on boulder bottoms but not on vertical walls, and temporal trends were not significantly different between the protection levels. Differences in densities were caused primarily by variance in recruitment, which was less pronounced inside the MPA and was correlated with adult density, indicating density-dependent recruitment under high predation pressure, as well as some positive feedback mechanisms that may facilitate higher urchin abundances despite higher predator abundance. Populations within the reserve were less variable in abundance and did not exhibit the hyper-abundances observed outside the reserve, suggesting that predation effects maybe more subtle than simply lowering the numbers of urchins in reserves. A. lixula densities were an order of magnitude lower than P. lividus densities and varied within sites and over time on boulder bottoms but did not differ between protection levels. In December 2008, an exceptionally violent storm reduced sea urchin densities drastically (by 50% to 80%) on boulder substrates, resulting in the lowest values observed over the entire study period, which remained at that level for at least two years (up to the present). Our results also showed great variability in the biological and physical processes acting at different temporal scales. This study highlights the need for appropriate temporal scales for studies to fully understand ecosystem functioning, the concepts of which are fundamental to successful conservation and management