Experimental analysis of waste tyres as a sustainable source of energy

© The Authors, published by EDP Sciences, 2019. Nowadays, the stability of energy supply that additionally should be sustainable is one of the most important global issues. Thus, many new potential energy sources are being investigated. Since automobile industry is growing, a huge amount of waste tyres (WT) occur each year. Pyrolysis of scrap tyres can be considered as a sustainable way to recover significant amounts of energy as well as the valuable materials. Potential of waste tyres in the energy sector is studied in this work. Proximate, ultimate and thermogravimetric (TG) analysis of mechanically grounded WT sample was done. Waste tyres feature high heating value combined with carbon content as high as 87.90 % (on dry ash-free basis). Additionally, TG analysis allows to choose optimal operating temperature for pyrolysis process which is between 350 and 500°C. However, the sulphur content is also relatively high - around 2 wt.% - and it is the most important challenge for utilizing this waste in a thermochemical way.The paper was financial supported by Department of Air Conditioning, Heating, Gas Engineering and Air Protection; Wroclaw University of Science and Technology (No. 0401/0055/18)

Experimental investigation of waste tyres pyrolysis gas desulfurization through absorption in alkanolamines solutions

Copyright © 2022 The Authors. Pyrolysis of waste tyres produces harmful hydrogen sulfide and other mercaptan compounds as by-products. The current study is concerned with the purification of hydrogen-rich pyrolysis gas from hydrogen sulfide gas that is present in a great amount (up to 5.1% mol at 420 °C), and mercaptans that are also problematic impurities. The method proposed is absorption by alkanolamines which is one of the most economical methods applied in natural gas sweetening. However, it has not been adopted in waste tyre pyrolysis gas purification yet. Two organic absorbents were tested, diethanolamine (DEA), N-methyldiethanolamine (MDEA) as well as theirs blends, at various concentrations. The application of 30 wt% DEA in water reduced H2S emission by 98%. In turn, 40 wt% MDEA aqueous solutions reduced H2S emission by 97%. The best results were produced when 30 wt% DEA was mixed with 40 wt% of MDEA (1:1 vol ratio) which allowed a removal of 99% of H2S from the pyrolysis gas. Moreover, the maximum H2S emission was 7 ppm, and a level below 5 ppm was kept for 99% of experiments duration. Finally, the application of this mixture also reduced significantly the concentrations of other sulfur-containing compounds such as methyl mercaptan and carbonyl sulfide (a minimum of 98%), ethyl mercaptan (∼90%), and carbon disulphide (by more than 99%). Thus, aqueous solvent mixture of 30 wt% DEA with 40 wt% of MDEA (1:1 v/v) can be recommended as a potential desulfurization method for waste tyres pyrolysis gas.Department of Air Conditioning, Heating, Gas Engineering and Air Protection; Wroclaw University of Science and Technology (No. 8211204601 - N_RRB_PODST_BAD_ EXP_BAM)

Products’ composition of food waste low-temperature slow pyrolysis

Food waste generation is one of the most crucial problems of our constantly developing world. There are several common methods of its treatment, however each one has its own advantages and disadvantages. Pyrolysis attracting attention in this field since a long time, because it allows to utilize this valuable resource with energy and material recovery. Moreover, the environmental impact of the process is relatively low. In this paper, products of low temperature household waste pyrolysis underwent a detailed chemical analysis. Liquid and solid residues was examined. Composition and concentration of particular compounds and elements indicates presence of long chain alkane, alkene and carboxylic acid molecules together with small amounts of aromatics within the bio-oil samples. The presence of heavy metals in residues was detected, too. Since the products are usually described as non-toxic, the idea of waste’ low-temperature thermal treating in household was analyzed. In general, examined residues from the process are safe for the environment, thus pyrolysis can be considered as a legitimate mechanism to treat kitchen waste combined with energy recovery for homes

Municipal waste management systems for domestic use

© 2017 The Authors. Every year, the average citizen of a developed country produces about half a tonne of waste, thus waste management is an essential industry. Old waste management systems based on the collection of mixed/ sorted waste and transporting it a long way to disposal sites has a significant negative impact on the environment and humans. This paper will review the available waste management systems for house- holds. Biological methods (such as composting or anaerobic digestion) and physicochemical methods (such as burning or pyrolysis) of waste utilization will be considered from the householder’s point of view. The most important features of each system will be discussed and compared. Municipal waste management systems for domestic use could eliminate or significantly reduce the stage of waste collection and transportation. Additionally, they should not require special infrastructure and at the same time should allow garbage to be changed into safe products or energy sources with no harmful emissions. The aim of the work is to identify the best available waste disposal systems for domestic use.This reported work was conducted as part of the“Design Optimisation of the HERU Waste Treatment System”project that wasfunded by Manik Ventures Limited Project ID: 10300

Syngas Quality as a Key Factor in the Design of an Energy-Efficient Pyrolysis Plant for Scrap Tyres

In 2016 4.94 million tonnes of tyres were produced. Each tyre eventually become waste and pyrolysis has been considered an effective way of utilizing scrap tyres for several decades. However, pyrolysis has failed many times because the process has a great energy demand and the quality of products is unstable or insufficient for commercial use. Usually plants are focused on the production of pyrolytic oil or char and the gaseous phase is only a by-product. In this paper the importance of composition and quality of pyrolytic gas is emphasized. The main chemical properties make this gas a valuable biofuel that may satisfy energy requirements of the whole process (except for the start-up phase). Available data from literature concerning composition and other features of the pyrolytic gas from scrap tyres obtained at temperatures up to 1000 °C are compared with experimental results. The quality of evolved gases is discussed in the context of the Industrial Emissions Directive (IED), too. Finally, an analysis of the mass balances obtained allows a decision about the business profile and profitability

Experimental investigation of waste tyres pyrolysis gas desulfurization through absorption in alkanolamines solutions

Copyright © 2022 The Authors. Pyrolysis of waste tyres produces harmful hydrogen sulfide and other mercaptan compounds as by-products. The current study is concerned with the purification of hydrogen-rich pyrolysis gas from hydrogen sulfide gas that is present in a great amount (up to 5.1% mol at 420 °C), and mercaptans that are also problematic impurities. The method proposed is absorption by alkanolamines which is one of the most economical methods applied in natural gas sweetening. However, it has not been adopted in waste tyre pyrolysis gas purification yet. Two organic absorbents were tested, diethanolamine (DEA), N-methyldiethanolamine (MDEA) as well as theirs blends, at various concentrations. The application of 30 wt% DEA in water reduced H2S emission by 98%. In turn, 40 wt% MDEA aqueous solutions reduced H2S emission by 97%. The best results were produced when 30 wt% DEA was mixed with 40 wt% of MDEA (1:1 vol ratio) which allowed a removal of 99% of H2S from the pyrolysis gas. Moreover, the maximum H2S emission was 7 ppm, and a level below 5 ppm was kept for 99% of experiments duration. Finally, the application of this mixture also reduced significantly the concentrations of other sulfur-containing compounds such as methyl mercaptan and carbonyl sulfide (a minimum of 98%), ethyl mercaptan (∼90%), and carbon disulphide (by more than 99%). Thus, aqueous solvent mixture of 30 wt% DEA with 40 wt% of MDEA (1:1 v/v) can be recommended as a potential desulfurization method for waste tyres pyrolysis gas.Department of Air Conditioning, Heating, Gas Engineering and Air Protection; Wroclaw University of Science and Technology (No. 8211204601 - N_RRB_PODST_BAD_ EXP_BAM)

Assessment of Heat Hazard during the Polymerization of Selected Light-Sensitive Dental Materials

Introduction. Polymerization of light-cured dental materials used for restoration of hard tooth tissue may lead to an increase in temperature that may have negative consequence for pulp vitality. Aim. The aim of this study was to determine maximum temperatures reached during the polymerization of selected dental materials, as well as the time that is needed for samples of sizes similar to those used in clinical practice to reach these temperatures. Materials and Methods. The study involved four composite restorative materials, one lining material and a dentine bonding agent. The polymerization was conducted with the use of a diode light-curing unit. The measurements of the external surface temperature of the samples were carried out using the Thermovision®550 thermal camera. Results. The examined materials significantly differed in terms of the maximum temperatures values they reached, as well as the time required for reaching the temperatures. A statistically significant positive correlation of the maximum temperature and the sample weight was observed. Conclusions. In clinical practice, it is crucial to bear in mind the risk of thermal damage involved in the application of light-cured materials. It can be reduced by using thin increments of composite materials

Waste tyre pyrolysis – impact of the process and its products on the environment

Department of Air Conditioning, Heating, Gas Engineering and Air Protection; Wroclaw University of Science and Technolog

Experimental investigation on the chemical characterisation of pyrolytic products of discarded food at temperatures up to 300ºC

Discarded food generation is one of the most crucial problems of constantly growing modern society. There are several conventional treatment methods of this type of material, however, each one has its own advantages and disadvantages. Pyrolysis, a thermal degradation process, has recently been attracting an increased attention in this field. Pyrolysis allows the utilization of resources to recover the energy within materials with relatively low environmental impact. In this paper results of food pyrolysis products analysis are shown. Liquid and solid residue were tested for the content of various compounds and elements. Composition and concentration of particular compounds and elements indicates a strong presence of long chain alkane and alkene, as well as carboxylic acid molecules within the bio-oil samples. The presence of heavy metals in residues was detected, too. The idea of low-temperature thermal treating in household was critically analyzed. In general, the composition of products from lowtemperature slow pyrolysis is safe for the environment. The obtained bio-oils and ash are nontoxic, therefore food residues can be utilized through pyrolysis. The most important advantage of proposed solution is no need of pretreatment of chamber load, and possibility of simple energy recovery for home.HER